Search Results - "Smits, Jan M. M."
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Enforcing Corporate Social Responsibility Codes Under Private Law: On the Disciplining Power of Legal Doctrine
Published in Indiana journal of global legal studies (01-01-2017)“…A central question in the debate on corporate social responsibility is to what extent CSR codes can be enforced among private parties. This contribution argues…”
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Formal Synthesis of Solanoeclepin A: Enantioselective Allene Diboration and Intramolecular [2+2] Photocycloaddition for the Construction of the Tricyclic Core
Published in Chemistry : a European journal (22-01-2016)“…An enantioselective synthesis of an intermediate in the Tanino total synthesis of solanoeclepin A has been developed. The key step was an intramolecular [2+2]…”
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Ligand effects of NHC-iridium catalysts for signal amplification by reversible exchange (SABRE)
Published in Chemical communications (Cambridge, England) (28-08-2013)“…SABRE hyperpolarizes substrates by polarization transfer from para-hydrogen in a metal complex. We have measured the signal enhancement of pyridine and its…”
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4
Rhodium-Mediated Stereoselective Polymerization of “Carbenes”
Published in Journal of the American Chemical Society (02-08-2006)“…Unprecedented rhodium-catalyzed stereoselective polymerization of “carbenes” from ethyl diazoacetate (EDA) to give high molecular mass poly(ethyl…”
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Strong Induced-Fit Binding of Viologen and Pyridine Derivatives in Adjustable Porphyrin Cavities
Published in Chemistry : a European journal (01-09-2014)“…The synthesis and binding properties of new porphyrin cage compounds consisting of a rigid diphenylglycoluril part, which is connected via flexible…”
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Rh-Mediated Carbene Polymerization: from Multistep Catalyst Activation to Alcohol-Mediated Chain-Transfer
Published in ACS catalysis (03-02-2012)“…Rh-mediated polymerization of carbenes gives access to new highly substituted and stereoregular polymers. While this reaction is of interest for the synthesis…”
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1. Solvent, Linker, and Anion Effects on the Formation, Connectivity, and Topology of Cu(I)/PPh3/N-Donor Ligand Coordination Polymers
Published in Crystal growth & design (05-10-2011)“…The effect of linker, anion, and solvent on the formation, topology, and connectivity of coordination polymers was investigated for polymers resulting from…”
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Processive Rotaxane Systems. Studies on the Mechanism and Control of the Threading Process
Published in Journal of the American Chemical Society (02-05-2007)“…The threading behavior of a zinc analogue of a previously reported processive manganese porphyrin catalyst onto a series of polymers of different lengths is…”
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Ligand Oxidation of a Deprotonated Bis(picolyl)amine IrI(cod) Complex
Published in Chemistry : a European journal (08-12-2008)“…Innocent until proven guilty: The bis(2‐picolyl)amine (bpa) and related poly(picolyl)amine ligands might not be as innocent as they seem. A double…”
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10
Thermodynamics and kinetics of guest-induced switching between "basket handle" porphyrin isomers
Published in Molecules (Basel, Switzerland) (23-04-2014)“…The synthesis and switching properties of two "basket handle" porphyrin isomers is described. The cis-oriented meso-phenyl groups of these porphyrins are…”
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11
Squaring cooperative binding circles
Published in Proceedings of the National Academy of Sciences - PNAS (30-06-2009)“…The cooperative binding effects of viologens and pyridines to a synthetic bivalent porphyrin receptor are used as a model system to study how the magnitudes of…”
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12
Ir III and Ru II Complexes Containing Triazole‐Pyridine Ligands: Luminescence Enhancement upon Substitution with β‐Cyclodextrin
Published in Chemistry : a European journal (07-12-2009)“…Novel 2‐(1‐substituted‐1 H ‐1,2,3‐triazol‐4‐yl)pyridine (pytl) ligands have been prepared by “click chemistry” and used in the preparation of heteroleptic…”
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Enantioselective Approach to the Right-Hand Substructure of Solanoeclepin A
Published in European journal of organic chemistry (01-12-2016)“…An enantioselective synthesis of the right‐hand substructure of solanoeclepin A has been developed. The key step was an intramolecular [2+2] photocycloaddition…”
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14
Cationic Heteroleptic Cyclometalated IridiumIII Complexes Containing Phenyl-Triazole and Triazole-Pyridine Clicked Ligands
Published in Molecules (Basel, Switzerland) (23-03-2010)“…Novel heteroleptic iridium complexes containing the 1-substituted-4-phenyl-1H-1,2,3-triazole (phtl) cyclometalating ligand have been synthesized. The 3+2…”
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Cationic heteroleptic cyclometalated iridium(III) complexes containing phenyl-triazole and triazole-pyridine clicked ligands
Published in Molecules (Basel, Switzerland) (23-03-2010)“…Novel heteroleptic iridium complexes containing the 1-substituted-4-phenyl-1H-1,2,3-triazole (phtl) cyclometalating ligand have been synthesized. The 3+2…”
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16
Dioxygen Activation by a Mononuclear IrII-Ethene Complex
Published in Angewandte Chemie International Edition (17-06-2002)“…Oxidation induces oxygenation: The first IrII–ethene complex ever (2) was obtained by one‐electron oxidation of the corresponding IrI–ethene complex 1. Whereas…”
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Ligand Design in Rh(diene)-Mediated “Carbene” Polymerization; Efficient Synthesis of High-Mass, Highly Stereoregular, and Fully Functionalized Carbon-Chain Polymers
Published in Organometallics (28-06-2010)“…Stereoselective polymerization of “carbenes” from diazo esters mediated by [(L-prolinate)RhI(Me2cod)] allows the formation of highly syndiotactic, fully…”
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18
European legal education, or: how to prepare students for global citizenship?
Published in Law teacher (01-07-2011)“…Legal education is gradually moving away from the teaching of national law towards a more European, transnational, or even "global" way of teaching. This paper…”
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Reaction of the Diimine Pyridine Ligand with Aluminum Alkyls: An Unexpectedly Complex Reaction
Published in Organometallics (13-02-2006)“…The diimine pyridine ligand 2,6-{2,6- i Pr2C6H3NCMe}2C5H3N (1) was reacted with a series of aluminum alkyls (Me3Al, Et3Al, i Bu3Al, i Bu2AlH, Et2AlCl)…”
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20
IrII(ethene): Metal or Carbon Radical?
Published in Journal of the American Chemical Society (16-02-2005)“…One-electron oxidation of [(Me n tpa)IrI(ethene)]+ complexes (Me3tpa = N,N,N-tri(6-methyl-2-pyridylmethyl)amine; Me2tpa =…”
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