Search Results - "Smith, Diane K."

The Effect of Glassy Carbon Surface Oxides in Non-Aqueous Voltammetry: The Case of Quinones in Acetonitrile by Staley, Rachel Patricia-Andrea, Newell, Christina M., Pullman, David P., Smith, Diane K.

“…Glassy carbon (GC) electrodes are well-known to contain oxygenated functional groups such as phenols, carbonyls, and carboxylic acids on their surface. The…”
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Click chemistry-facilitated comprehensive identification of proteins adducted by antimicrobial 5-nitroimidazoles for discovery of alternative drug targets against giardiasis by Lauwaet, Tineke, Miyamoto, Yukiko, Ihara, Sozaburo, Le, Christine, Kalisiak, Jarosław, Korthals, Keith A, Ghassemian, Majid, Smith, Diane K, Sharpless, K Barry, Fokin, Valery V, Eckmann, Lars

“…Giardiasis and other protozoan infections are major worldwide causes of morbidity and mortality, yet development of new antimicrobial agents with improved…”
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How Do Proximal Hydroxy or Methoxy Groups on the Bidentate Ligand Affect [(2,2′;6′,2"-Terpyridine)Ru(N,N)X] Water-Oxidation Catalysts? Synthesis, Characterization, and Reactivity at Acidic and Near-Neutral pH by Marelius, David C., Bhagan, Salome, Charboneau, David J., Schroeder, Kristine M., Kamdar, Jayneil M., McGettigan, Amanda R., Freeman, Benjamin J., Moore, Curtis E., Rheingold, Arnold L., Cooksy, Andrew L., Smith, Diane K., Paul, Jared J., Papish, Elizabeth T., Grotjahn, Douglas B.

“…Water‐oxidation catalysts (WOCs) can potentially be improved by installing pendant electron‐donor groups that may also be proton donors or acceptors. We have…”
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Use of a Wedge Scheme to Describe Intermolecular Proton-Coupled Electron Transfer through the H‑bond Complex Formed Between a Phenylenediamine-Based Urea and 1,8-Naphthyridine by Tamashiro, Bryan T, Cedano, Mario R, Pham, An T, Smith, Diane K

“…Recently we introduced the “wedge scheme” as a convenient means to include H-bonded intermediates in an overall proton-coupled electron transfer (PCET)…”
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Exploring the Role of H‐Bonding in Organic Electrochemistry – From Supramolecular Applications to Mechanistic Investigations by Smith, Diane K.

“…H‐bonds can exert a substantial impact on the course of organic electrode reactions due to their ability to stabilize charged intermediates and products formed…”
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Electrochemically Controlled Hydrogen Bonding. Electrolyte Effects in an Oxidation-Based Arylurea−Amide System by Woods, Jessica E, Ge, Yu, Smith, Diane K

“…Oxidation of a dimethylaminophenyl-substituted urea leads to a > 2000-fold increase in binding strength between the urea and a diamide guest in 0.1 M…”
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Electrochemically Controlled Hydrogen Bonding. Nitrobenzenes as Simple Redox-Dependent Receptors for Arylureas by Bu, Jingjing, Lilienthal, Ninette D, Woods, Jessica E, Nohrden, Cora E, Hoang, KimPhuong T, Truong, Daniel, Smith, Diane K

“…Reduction of nitrobenzene derivatives in the presence of arylureas in aprotic solvents results in large positive shifts in potential of the nitrobenzene0/-…”
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A Light-Promoted Innate Trifluoromethylation of Pyridones and Related N‑Heteroarenes by Dang-Nguyen, Ashley, Legaspi, Kristine C., McCarty, Connor T., Smith, Diane K., Gustafson, Jeffrey

“…We report a practical, light-mediated perfluoroalkylation using Langlois’ reagent (sodium trifluoromethylsulfinate) that proceeds in the absence of any…”
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Orlistat, a lipase inhibitor, for weight maintenance after conventional dieting: a 1-y study by Hill, J.O, Hauptman, J, Anderson, J.W, Fujioka, K, O'Neil, P.M, Smith, D.K, Zavoral, J.H, Aronne, L.J

“…Background: Long-term maintenance of weight loss remains a therapeutic challenge in obesity treatment. Objective: This multicenter, double-blind,…”
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Sulfonate Group Improves the Solubility and Electrocatalytic Performance of Ru‐Based bda‐ and pda‐Type Water Oxidation Catalysts under Neutral Conditions by Kerkhof, Jake T., Breyer, Colton J., Smith, Diane K., Mao, Yuezhi, Grotjahn, Douglas B.

“…Four ruthenium water oxidation catalysts that bear carboxylate and sulfonate groups in the active site have been synthesized and analyzed for their catalytic…”
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Redox-Responsive Dimerization in a Ferrocene-Ureidopyrimidone Supramolecular Assembly by Cedano, Mario R, Smith, Diane K

“…Ureidopyrimidones (UPy’s) are well-known to dimerize via 4 strong H-bonds in noncompetitive solvents. Although UPy dimers have been widely studied, there are…”
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Redox-Responsive H‑Bonding: Amplifying the Effect of Electron Transfer Using Proton-Coupled Electron Transfer by Choi, Hyejeong, Baek, Kiyeol, Toenjes, Sean T, Gustafson, Jeffrey L, Smith, Diane K

“…A new strategy to create highly redox-responsive H-bond dimers based on proton-coupled electron transfer is proposed that capitalizes on the importance of…”
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An Active‐Site Sulfonate Group Creates a Fast Water Oxidation Electrocatalyst That Exhibits High Activity in Acid by Nash, Aaron G., Breyer, Colton J., Vincenzini, Brett D., Elliott, Gregory I., Niklas, Jens, Poluektov, Oleg G., Rheingold, Arnold L., Smith, Diane K., Musaev, Djamaladdin G., Grotjahn, Douglas B.

“…The storage of solar energy in chemical bonds will depend on pH‐universal catalysts that are not only impervious to acid, but actually thrive in it. Whereas…”
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Nanosheets of Co-(Ni and Fe) Layered Double Hydroxides for Electrocatalytic Water Oxidation Reaction by Valdez, Ricardo, Grotjahn, Douglas B., Smith, Diane K., Quintana, Juan M., Olivas, Amelia

“…The discovery of new nanomaterials as catalysts to produce hydrogen through artificial photosynthesis approach has become essential in the development of…”
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Kinetic Stabilization of Quinone Dianions via Hydrogen Bonding by Water in Aprotic Solvents by Staley, Rachel Patricia-Andrea, Lopez, Eric M., Clare, Laurie A., Smith, Diane K.

“…It is well-established that very weak acids such as water and alcohols strongly H-bond to quinone dianions, Q2–, in aprotic solvents. This results in…”
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Increasing Ligand Denticity and Stability for a Water Oxidation Electrocatalyst using P(V) as Connecting Element by Saeedifard, Farzaneh, Breyer, Colton J., Chi Cao, Thomas, Kamdar, Jayneil M., Kerkhof, Jake, Smith, Diane K., Cooksy, Andrew L., Rheingold, Arnold L., Moore, Curtis E., Gu, Jing, Grotjahn, Douglas B.

“…Carboxylate complexes have risen to prominence in the field of water oxidation catalysis. Here for the first time we use the higher valence of phosphinates…”
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Voltammetry of Quinones in Unbuffered Aqueous Solution:  Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones by Quan, May, Sanchez, Daniel, Wasylkiw, Mark F, Smith, Diane K

“…Cyclic voltammetry studies are reported for two representative quinones, benzoquinone and 2-anthraquinonesulfonate, in buffered and unbuffered aqueous solution…”
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The Role of H‑Bonding in Nonconcerted Proton-Coupled Electron Transfer: Explaining the Voltammetry of Phenylenediamines in the Presence of Weak Bases in Acetonitrile by Clare, Laurie A, Pham, Tammy D, Rafou, Lily A, Buenaventura, Ayla G, Scott, Tiffany R, Mikhaylova, Veronika, Smith, Diane K

“…The kinetics of many proton-coupled electron transfer (PCET) reactions cannot be adequately described by stepwise proton and electron transfer. Concerted…”
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Voltammetry of nitrobenzene with cysteine and other acids in DMSO. Implications for the biological reactivity of reduced nitroaromatics with thiols by Andres, Theresa, Eckmann, Lars, Smith, Diane K.

“…A cyclic voltammetric investigation of nitrobenzene in DMSO in the presence of various acids including boc- and methylester-protected cysteine is reported. It…”
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Electrochemically-Controlled Hydrogen Bonding. Selective Recognition of Urea and Amide Derivatives by Simple Redox-Dependent Receptors by Ge, Yu, Lilienthal, Ronald R, Smith, Diane K

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