Search Results - "Smaliy, Radomyr"
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New concepts in multidentate ligand chemistry: effects of multidentarity on catalytic and spectroscopic properties of ferrocenyl polyphosphines
Published in Chemical Society reviews (01-01-2007)“…This tutorial review devoted to ligand chemistry deals with the design and properties of ferrocenyl polyphosphines, an original class of multidentate ligands…”
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Diastereoselective Synthesis of Dialkylated Bis(phosphino)ferrocenes: Their Use in Promoting Silver‐Mediated Nucleophilic Fluorination of Chloroquinolines
Published in European journal of inorganic chemistry (10-01-2017)“…The diastereoselective synthesis of dialkylated ferrocenyl bis(phosphane)s bearing aryl, alkyl, and hetero‐ or polycyclic substituents on the phosphino groups…”
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Conformational Control of Metallocene Backbone by Cyclopentadienyl Ring Substitution: A New Concept in Polyphosphane Ligands Evidenced by “Through-Space” Nuclear Spin−Spin Coupling. Application in Heteroaromatics Arylation by Direct C−H Activation
Published in Organometallics (08-06-2009)“…The present study deals with the conformational control of the metallocene backbone within ferrocenyl polyphosphane ligands and their performance in the highly…”
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p-Nitrophenyl ester of (diphenylphosphoryl)acetic acid as a reagent for the synthesis of 2-(phosphorylmethyl)benzimidazole
Published in Z͡h︡urnal orhanichnoï ta farmat͡s︡evtychnoï khimiï (18-09-2020)“…Aim. To expand the synthetic potential of the activated esters of diphenylphosphorylacetic acid for the synthesis of phosphorylated benzimidazoles. Results and…”
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Structure-based Design of Novel Hepatitis B Virus Capsid Assembly Modulators
Published in Bioorganic & medicinal chemistry letters (01-09-2023)“…[Display omitted] •Capsid Assembly Modulators are promising agents for curing chronic HBV infection.•Target-based in silico screening study leads to the…”
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Diastereoselective Synthesis of Dialkylated Bis(phosphino)ferrocenes: Their Use in Promoting Silver‐Mediated Nucleophilic Fluorination of Chloroquinolines
Published in European journal of inorganic chemistry (2017)“…The diastereoselective synthesis of dialkylated ferrocenyl bis(phosphane)s bearing aryl, alkyl, and hetero‐ or polycyclic substituents on the phosphino groups…”
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3,4-Bis-phosphanyl-1H-pyrrole derivatives via direct electrophilic phosphanylation of 1-tert-butyl-1H-pyrrole
Published in Tetrahedron letters (23-03-2016)“…[Display omitted] •Preparation of 1-(tert-butyl)-3,4-bis(dibromophosphanyl)-1H-pyrrole is described.•This compound was used in the synthesis of new…”
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Application of chlorotrimethylsilane in Pictet–Spengler reaction
Published in Monatshefte für Chemie (01-11-2012)“…Chlorotrimethylsilane has been found to be an efficient condensing agent in the Pictet–Spengler reaction, affording an extremely straightforward synthetic…”
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Ferrocenyl (P,N)-diphosphines incorporating pyrrolyl, imidazolyl or benzazaphospholyl moieties: Synthesis, coordination to group 10 metals and performances in palladium-catalyzed arylation reactions
Published in Journal of organometallic chemistry (01-07-2013)“…Three novel symmetrical ferrocenyl diphosphines with tertiary phosphorus atoms holding respectively nitrogen-containing heterocyclic derivatives of pyrrole,…”
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Synthesis of CF3-bearing pyrrolidines by hydrogenation of trifluoroacetylated pyrrole derivatives
Published in Journal of fluorine chemistry (01-12-2015)“…Hydrogenation of trifluoroacylated pyrroles was investigated. •An approach to CF3-bearing pyrrolidines was developed.•The CF3-bearing pyrroles were found to be…”
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Hexaphosphine: A Multifaceted Ligand for Transition Metal Coordination
Published in European journal of inorganic chemistry (01-03-2012)“…We report the synthesis and characterization of the first ferrocenyl polyphosphane incorporating six phosphorus donor atoms. In this unique ligand, the…”
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Functionalized Tri- and Tetraphosphine Ligands as a General Approach for Controlled Implantation of Phosphorus Donors with a High Local Density in Immobilized Molecular Catalysts
Published in ChemPlusChem (Weinheim, Germany) (01-01-2015)“…Supported phosphine ligands are auxiliaries of topical academic and industrial interest in catalysis promoted by transition metals. However, both controlled…”
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Intramolecular Cyclization of N ‐Arylphosphinimidic Isocyanates – Novel Approach to a 4a,8a‐Dihydro‐1,3,2λ 5 ‐benzodiazaphosphinin‐4(3 H )‐one System
Published in European journal of inorganic chemistry (01-07-2008)“…A previously unknown type of 1,3,2λ 5 ‐benzodiazaphosphinin‐4(3 H )‐ones was obtained by intramolecular heterocyclization of novel N ‐arylphosphinimidic…”
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Intramolecular Cyclization of N-Arylphosphinimidic Isocyanates - Novel Approach to a 4a,8a-Dihydro-1,3,2λ5-benzodiazaphosphinin-4(3H)-one System
Published in European Journal of Inorganic Chemistry (01-07-2008)“…A previously unknown type of 1,3,2λ5‐benzodiazaphosphinin‐4(3H)‐ones was obtained by intramolecular heterocyclization of novel N‐arylphosphinimidic…”
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