Search Results - "Skulan, Andrew J"

Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes by Solomon, Edward I, Brunold, Thomas C, Davis, Mindy I, Kemsley, Jyllian N, Lee, Sang-Kyu, Lehnert, Nicolai, Neese, Frank, Skulan, Andrew J, Yang, Yi-Shan, Zhou, Jing

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Dielectrophoretic Manipulation of Particles and Cells Using Insulating Ridges in Faceted Prism Microchannels by Barrett, Louise M, Skulan, Andrew J, Singh, Anup K, Cummings, Eric B, Fiechtner, Gregory J

“…This paper presents a novel device for the dielectrophoretic manipulation of particles and cells. A two-level isotropic etch of a glass substrate was used to…”
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Nature of the Peroxo Intermediate of the W48F/D84E Ribonucleotide Reductase Variant:  Implications for O2 Activation by Binuclear Non-Heme Iron Enzymes by Skulan, Andrew J, Brunold, Thomas C, Baldwin, Jeffrey, Saleh, Lana, Bollinger, J. Martin, Solomon, Edward I

“…Analysis of the spectroscopic signatures of the R2-W48F/D84E biferric peroxo intermediate identifies a cis μ-1,2 peroxo coordination geometry. DFT geometry…”
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Electronic and Spectroscopic Studies of the Non-Heme Reduced Binuclear Iron Sites of Two Ribonucleotide Reductase Variants:  Comparison to Reduced Methane Monooxygenase and Contributions to O2 Reactivity by Wei, Pin-pin, Skulan, Andrew J, Mitić, Natasa, Yang, Yi-Shan, Saleh, Lana, Bollinger, J. Martin, Solomon, Edward I

“…Circular dichroism (CD), magnetic circular dichroism (MCD), and variable-temperature variable-field (VTVH) MCD have been used to probe the biferrous active…”
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Spectroscopic and Computational Studies of the de Novo Designed Protein DF2t:  Correlation to the Biferrous Active Site of Ribonucleotide Reductase and Factors That Affect O2 Reactivity by Wei, Pin-pin, Skulan, Andrew J, Wade, Herschel, DeGrado, William F, Solomon, Edward I

“…DF2t, a de novo designed protein that mimicks the active-site structure of many non-heme biferrous enzymes, has been studied using a combination of circular…”
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BAC-MP4 Predictions of Thermochemistry for Gas-Phase Antimony Compounds in the Sb−H−C−O−Cl System by Skulan, Andrew J, Nielsen, Ida M. B, Melius, Carl F, Allendorf, Mark D

“…Calibrated by both experimental data and high-level coupled-cluster calculations, the BAC-MP4 methodology was applied to 51 SbL n (L = H, CH3, C2H5, Cl, and…”
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BAC-MP4 Predictions of Thermochemistry for Gas-Phase Indium Compounds in the In−H−C−O−Cl System by Skulan, Andrew J, Nielsen, Ida M. B, Melius, Carl F, Allendorf, Mark D

“…The BAC-MP4 methodology has been used to calculate the heats of formation and associated thermodynamic parameters for a family of 51 different one-, two-, and…”
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Fabrication and Analysis of Spatially Uniform Field Electrokinetic Flow Devices:  Theory and Experiment by Skulan, Andrew J, Barrett, Louise M, Singh, Anup K, Cummings, Eric B, Fiechtner, Gregory J

“…A uniform-field design approach can improve the performance of microanalytical, chip-based devices for a number of applications, including separations and…”
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Spectroscopic Study of [Fe2O2(5-Et3-TPA)2]3+:  Nature of the Fe2O2 Diamond Core and Its Possible Relevance to High-Valent Binuclear Non-Heme Enzyme Intermediates by Skulan, Andrew J, Hanson, Melissa A, Hsu, Hua-fen, Que, Lawrence, Solomon, Edward I

“…The spectroscopic properties and electronic structure of an Fe2(III,IV) bis-μ-oxo complex, [Fe2O2(5-Et3-TPA)2](ClO4)3 where 5-Et3-TPA =…”
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Nature of the Peroxo Intermediate of the W48F/D84E Ribonucleotide Reductase Variant:  Implications for O 2 Activation by Binuclear Non-Heme Iron Enzymes by Skulan, Andrew J., Brunold, Thomas C., Baldwin, Jeffrey, Saleh, Lana, Bollinger, J. Martin, Solomon, Edward I.

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Spectroscopic and Computational Studies of the de Novo Designed Protein DF2t:  Correlation to the Biferrous Active Site of Ribonucleotide Reductase and Factors That Affect O 2 Reactivity by Wei, Pin-pin, Skulan, Andrew J., Wade, Herschel, DeGrado, William F., Solomon, Edward I.

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Electronic and Spectroscopic Studies of the Non-Heme Reduced Binuclear Iron Sites of Two Ribonucleotide Reductase Variants:  Comparison to Reduced Methane Monooxygenase and Contributions to O 2 Reactivity by Wei, Pin-pin, Skulan, Andrew J., Mitić, Natasa, Yang, Yi-Shan, Saleh, Lana, Bollinger, J. Martin, Solomon, Edward I.

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EPR Spectroscopy of [Fe2O2(5-Et3-TPA)2]3+:  Electronic Origin of the Unique Spin-Hamiltonian Parameters of the Fe2III,IVO2 Diamond Core by SKULAN, Andrew J., HANSON, Melissa A., HSU, Hua-fen, DONG, Yanhong, QUE, Lawrence, SOLOMON, Edward I.

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EPR Spectroscopy of [Fe2O2(5-Et3-TPA)2]3+:  Electronic Origin of the Unique Spin-Hamiltonian Parameters of the Fe2 III,IVO2 Diamond Core by Skulan, Andrew J, Hanson, Melissa A, Hsu, Hua-fen, Dong, Yanhong, Que, Lawrence, Solomon, Edward I

“…The electronic origins of the magnetic signatures of [Fe2O2(5-Et3-TPA)2](ClO4)3, where 5-Et3-TPA = tris(5-ethyl-2-pyridylmethyl)amine, were investigated by…”
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EPR Spectroscopy of [Fe 2 O 2 (5-Et 3 -TPA) 2 ] 3+ :  Electronic Origin of the Unique Spin-Hamiltonian Parameters of the Fe 2 III,IV O 2 Diamond Core by Skulan, Andrew J., Hanson, Melissa A., Hsu, Hua-fen, Dong, Yanhong, Que, Lawrence, Solomon, Edward I.

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Spectroscopic Study of [Fe 2 O 2 (5-Et 3 -TPA) 2 ] 3+ :  Nature of the Fe 2 O 2 Diamond Core and Its Possible Relevance to High-Valent Binuclear Non-Heme Enzyme Intermediates by Skulan, Andrew J., Hanson, Melissa A., Hsu, Hua-fen, Que, Lawrence, Solomon, Edward I.

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EPR spectroscopy of [Fe2O2(5-Et3-TPA)2]3+: electronic origin of the unique spin-Hamiltonian parameters of the Fe2(III,IV)O2 diamond core by Skulan, Andrew J, Hanson, Melissa A, Hsu, Hua-fen, Dong, Yanhong, Que, Jr, Lawrence, Solomon, Edward I

“…The electronic origins of the magnetic signatures of [Fe(2)O(2)(5-Et(3)-TPA)(2)](ClO(4))(3), where 5-Et(3)-TPA = tris(5-ethyl-2-pyridylmethyl)amine, were…”
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Circular dichroism and magnetic circular dichroism studies of the reduced binuclear non-heme iron sites of D84E and D84E/W48F ribonucleotide reductase mutants. Comparison to reduced methane monooxygenase and contributions to O2 reactivity by Wei, Pin-pin, Skulan, Andrew J., Mitic, Natasa, Yang, Yi-Shan, Solomon, Edward I., Bollinger, J.Martin, Saleh, Lana

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Electronic structure of the oxygen activating intermediates of ribonucleotide reductase: the peroxo intermediate and a model complex of the high-valent intermediate, X by Skulan, Andrew J., Brunold, Thomas C., Hanson, Melissa A., Solomon, Edward I., Baldwin, Jeffrey, Bollinger, J.Martin, Hsu, Hua-fen, Que, Lawrence

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Particle mixing and concentration through competing electrokinetic and hydrodynamic flows by Skulan, A.J., Barrett, L.M., Fiechtner, G.J., Singh, A.K., Cummings, E.B., Simmons, B.A.

“…We have developed a novel, low voltage particle concentration and separation paradigm that exploits the interplay between electrokinetic, dielectrophoretic,…”
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