Search Results - "Skitaltseva, Elena V."
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Base-Catalyzed Stereoselective Vinylation of Ketones with Arylacetylenes: A New C(sp3)C(sp2) Bond-Forming Reaction
Published in Chemistry : a European journal (26-07-2010)“…Alkylaryl‐ and alkylheteroarylketones, including those with condensed aromatic moieties, are readily vinylated with arylacetylenes (KOH/DMSO, 100 °C, 1 h) to…”
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Journal Article -
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15-[( Z)-Phenylmethylidene]-7,14-dioxadispiro[5.1.5.2]pentadecanes: stereoselective one-pot assembly from cyclohexanones and phenylacetylene in a KOH/DMSO suspension
Published in Tetrahedron letters (20-07-2011)“…Cyclohexanones react with phenylacetylene in a KOH/DMSO suspension (80 °C, 1 h) to give unexpectedly phenylmethylidene dispirocyclic ketals, 15-[(…”
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Unexpected diastereoselective one-pot assembly of hexahydroazulenones from 2-alkylcyclohexanones and arylacetylenes in KOH/DMSO suspension
Published in Tetrahedron letters (17-08-2011)“…2-Alkylcyclohexanones react with arylacetylenes (KOH/DMSO, 100°C, 1h) to afford unexpectedly hexahydroazulenones in 34–50% yields and ca. 100%…”
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Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples
Published in Mendeleev communications (01-03-2012)“…1-Ethynylcyclohexanol and 1-ethynylcycloheptanol are O-vinylated with acetylene in KOH/DMSO superbase system (90°C, autoclave, initial acetylene pressure of 14…”
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Synthesis of Functionalized 3,4-Dihydropyrans via Rearrangement of the Products of a One-Pot Diastereoselective Assembly of Ketones and Acetylene
Published in European Journal of Organic Chemistry (01-12-2010)“…The products of the one‐pot assembly of ketones and acetylene, 7‐methylene‐6,8‐dioxabicyclo[3.2.1]octanes, congeners of an insect pheromone frontalin, undergo…”
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Book Review Journal Article -
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Synthesis of 1-vinylpyrrole-2-carbonitriles
Published in Tetrahedron letters (07-01-2009)“…A new highly synthetically potent series of bifunctional pyrroles, 1-vinylpyrrole-2-carbonitriles, were synthesized from readily available…”
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One‐Pot Assembly of 7‐Methylene‐6,8‐dioxabicyclo[3.2.1]octanes, Congeners of Frontalin, from Ketones and Acetylene
Published in European Journal of Organic Chemistry (01-10-2009)“…A facile, consecutive, self‐consisting assembly of two molecules of ketones with two molecules of acetylene to afford…”
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Book Review Journal Article