Search Results - "Skatova, Alexandra A."

Redox‐Active Ligand‐Assisted Two‐Electron Oxidative Addition to Gallium(II) by Fedushkin, Igor L., Dodonov, Vladimir A., Skatova, Alexandra A., Sokolov, Vladimir G., Piskunov, Alexander V., Fukin, Georgii K.

“…The reaction of digallane (dpp‐bian)Ga−Ga(dpp‐bian) (2) (dpp‐bian=1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene) with allyl chloride (AllCl) proceeded by a…”
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Gallium “Shears” for C=N and C=O Bonds of Isocyanates by Dodonov, Vladimir A., Chen, Weixing, Zhao, Yanxia, Skatova, Alexandra A., Roesky, Peter W., Wu, Biao, Yang, Xiao‐Juan, Fedushkin, Igor L.

“…Digallane [L1Ga−GaL1] (1, L1=dpp‐bian=1,2‐[(2,6‐iPr2C6H3)NC]2C12H6) reacts with RN=C=O (R=Ph or Tos) by [2+4] cycloaddition of the isocyanate C=N bonds across…”
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Ytterbium and Europium Complexes of Redox-Active Ligands: Searching for Redox Isomerism by Fedushkin, Igor L, Yambulatov, Dmitriy S, Skatova, Alexandra A, Baranov, Evgeny V, Demeshko, Serhiy, Bogomyakov, Artem S, Ovcharenko, Victor I, Zueva, Ekaterina M

“…The reaction of (dpp-Bian)­EuII(dme)2 (3) (dpp-Bian is dianion of 1,2-bis­[(2,6-diisopropylphenyl)­imino]­acenaphthene; dme is 1,2-dimethoxyethane) with…”
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Mononuclear dpp-Bian Gallium Complexes: Synthesis, Crystal Structures, and Reactivity toward Alkynes and Enones by Fedushkin, Igor L, Kazarina, Olga V, Lukoyanov, Anton N, Skatova, Alexandra A, Bazyakina, Natalia L, Cherkasov, Anton V, Palamidis, Eftimios

“…Treatment of (dpp-Bian)­Ga–Ga­(dpp-Bian) (1) (dpp-Bian = 1,2-bis­[(2,6-diisopropylphenyl)­imino]­acenaphthene) with iodine gives…”
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[(dpp-bian)ZnZn(dpp-bian)]: A Zinc-Zinc-Bonded Compound Supported by Radical-Anionic Ligands by Fedushkin, Igor L., Skatova, Alexandra A., Ketkov, Sergey Y., Eremenko, Olga V., Piskunov, Alexander V., Fukin, Georgy K.

“…Radical help: The use of a spin‐labeled ligand allows a zinc–zinc‐bonded compound supported by radical‐anionic ligands to be prepared (see scheme). The radical…”
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Reduction of CO2 with Aluminum Hydrides Supported with Ar-BIAN Radical-Anions (Ar-BIAN = 1,2-Bis(arylimino)acenaphthene) by Koptseva, Tatyana S, Moskalev, Mikhail V, Skatova, Alexandra A, Rumyantcev, Roman V, Fedushkin, Igor L

“…The reactions of H2AlCl with [(dpp-Bian)­Na­(Et2O)n] and [(ArBIG-Bian)­Na­(THF)] produce respective aluminum hydrides supported by radical-anionic…”
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Reactivity of Transition Metal Gallylene Complexes Toward Substrates with Multiple Carbon–Element Bonds by Dodonov, Vladimir A., Sokolov, Vladimir G., Baranov, Evgeny V., Skatova, Alexandra A., Xu, Wenhua, Zhao, Yanxia, Yang, Xiao-Juan, Fedushkin, Igor L.

“…Reactivity of transition metal complexes containing the redox-active gallylene (dpp-bian)Ga ligand (dpp-bian =…”
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Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C by Koptseva, Tatyana S., Sokolov, Vladimir G., Ketkov, Sergey Yu, Rychagova, Elena A., Cherkasov, Anton V., Skatova, Alexandra A., Fedushkin, Igor L.

“…The reaction of dialane [LAl‐AlL] (1; L=dianion of 1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene, dpp‐bian) with carbon dioxide results in two different…”
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Cycloaddition versus Cleavage of the C=S Bond of Isothiocyanates Promoted by Digallane Compounds with Noninnocent α‐Diimine Ligands by Zhang, Wei, Dodonov, Vladimir A., Chen, Weixing, Zhao, Yanxia, Skatova, Alexandra A., Fedushkin, Igor L., Roesky, Peter W., Wu, Biao, Yang, Xiao‐Juan

“…Whereas the chemistry of single‐bond activation by compounds of the main group elements has undergone some development in recent years, the cleavage of…”
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Reactions of Iso(thio)cyanates with Dialanes: Cycloaddition, Reductive Coupling, or Cleavage of the CS or CO Bond by Dodonov, Vladimir A, Chen, Weixing, Liu, Li, Sokolov, Vladimir G, Baranov, Evgeny V, Skatova, Alexandra A, Zhao, Yanxia, Wu, Biao, Yang, Xiao-Juan, Fedushkin, Igor L

“…The dialanes [(dpp-Bian)­Al–Al­(dpp-Bian)] (1) and [(dpp-dad)­Al­(THF)–(THF)­Al­(dpp-dad)] (2) (dpp-Bian = 1,2-[(2,6-iPr2C6H3)­NC]2C12H6, dpp-dad =…”
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Synthesis and ε‑Caprolactone Polymerization Activity of Electron-Deficient Gallium and Aluminum Species Containing a Charged Redox-Active dpp-Bian Ligand by Dodonov, Vladimir A, Morozov, Alexander G, Rumyantsev, Roman V, Fukin, Georgy K, Skatova, Alexandra A, Roesky, Peter W, Fedushkin, Igor L

“…The synthesis of electron-deficient gallium- and aluminum-centered species containing a redox-active dpp-Bian ligand (dpp-Bian =…”
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Reduction of CO 2 with Aluminum Hydrides Supported with Ar-BIAN Radical-Anions (Ar-BIAN = 1,2-Bis(arylimino)acenaphthene) by Koptseva, Tatyana S, Moskalev, Mikhail V, Skatova, Alexandra A, Rumyantcev, Roman V, Fedushkin, Igor L

“…The reactions of H AlCl with [(dpp-Bian)Na(Et O) ] and [(Ar -Bian)Na(THF)] produce respective aluminum hydrides supported by radical-anionic…”
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Addition of Alkynes to a Gallium Bis-Amido Complex: Imitation of Transition-Metal-Based Catalytic Systems by Fedushkin, Igor L., Nikipelov, Alexander S., Morozov, Alexander G., Skatova, Alexandra A., Cherkasov, Anton V., Abakumov, Gleb A.

“…Acetylene, phenylacetylene, and alkylbutynoates add reversibly to (dpp‐bian)Ga–Ga(dpp‐bian) (dpp‐bian=1,2‐bis[(2,6‐diisopropylphenyl)‐imino]acenaphthene) to…”
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Digallane with Redox-Active Diimine Ligand: Dualism of Electron-Transfer Reactions by Fedushkin, Igor L, Skatova, Alexandra A, Dodonov, Vladimir A, Chudakova, Valentina A, Bazyakina, Natalia L, Piskunov, Alexander V, Demeshko, Serhiy V, Fukin, Georgy K

“…The reactivity of digallane (dpp-Bian)Ga–Ga(dpp-Bian) (1), which consists of redox-active ligand 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-Bian),…”
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Ligand “Brackets” for Ga–Ga Bond by Fedushkin, Igor L, Skatova, Alexandra A, Dodonov, Vladimir A, Yang, Xiao-Juan, Chudakova, Valentina A, Piskunov, Alexander V, Demeshko, Serhiy, Baranov, Evgeny V

“…The reactivity of digallane (dpp-Bian)­Ga–Ga­(dpp-Bian) (1) (dpp-Bian = 1,2-bis­[(2,6-diisopropylphenyl)­imino]­acenaphthene) toward acenaphthenequinone (AcQ),…”
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Four-Step Reduction of dpp-bian with Sodium Metal: Crystal Structures of the Sodium Salts of the Mono-, Di-, Tri- and Tetraanions of dpp-bian by Fedushkin, Igor L., Skatova, Alexandra A., Chudakova, Valentina A., Fukin, Georgy K.

“…One ligand, four anions! Four anionic forms of a single ligand bis[N‐(2,6‐diisopropylphenyl)imino]acenaphthene (dpp‐bian) were isolated on a preparative scale…”
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Binuclear Zinc Complexes with Radical-Anionic Diimine Ligands by Fedushkin, Igor L, Eremenko, Olga V, Skatova, Alexandra A, Piskunov, Alexander V, Fukin, Georgi K, Ketkov, Sergey Yu, Irran, Elisabeth, Schumann, Herbert

“…The reactions of (dpp-BIAN)Zn−Zn(dpp-BIAN) (1) with PhCCH and of [(dpp-BIAN)Zn(μ-I)]2 (2) with potassium hydride yield the binuclear complexes…”
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Reduction of Benzophenone and 9(10H)-Anthracenone with the Magnesium Complex [(2,6-iPr2C6H3-bian)Mg(thf)3] by Fedushkin, Igor L., Skatova, Alexandra A., Cherkasov, Vladimir K., Chudakova, Valentina A., Dechert, Sebastian, Hummert, Markus, Schumann, Herbert

“…The reduction of benzophenone with the magnesium complex [(2,6‐iPr2C6H3‐bian)Mg(thf)3] (1), containing the 1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene…”
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Monomeric Magnesium and Calcium Complexes Containing the Bidentate, Dianionic 1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene Ligand by Fedushkin, Igor L., Skatova, Alexandra A., Chudakova, Valentina A., Fukin, Georgy K., Dechert, Sebastian, Schumann, Herbert

“…The reduction of 1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene (2,6‐iPr2C6H3‐BIAN) with metallic magnesium or calcium in THF affords the monomeric…”
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Monomeric Magnesium and Calcium Complexes containing the Rigid, Dianionic 1, 2-Bis[(2, 5-di-tert-butylphenyl)imino]acenaphthene (dtb-BIAN) and 1, 2-Bis[(2-biphenyl)imino]acenaphthene (bph-BIAN) Ligands by Fedushkin, Igor L., Chudakova, Valentina A., Skatova, Alexandra A., Khvoinova, Natalie M., Kurskii, Yuri A., Glukhova, Tatyana A., Fukin, Georgy K., Dechert, Sebastian, Hummert, Markus, Schumann, Herbert

“…The new rigid bidentate nitrogen ligands 1, 2‐bis[(2, 5‐di‐tert‐butylphenyl)imino]acenaphthene (1) (dtb‐BIAN) and 1, 2‐bis[(2‐biphenyl)imino]acenaphthene (2)…”
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