Search Results - "Sirsch, Peter"

A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound by Dettenrieder, Nicole, Schädle, Christoph, Maichle-Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner

“…The three-coordinate complex Me2Ga[B(NArCH)2] (Ar = C6H3 iPr2-2,6) is accessible via a tandem Lewis acid–base metathesis protocol employing (THF)2Li[B(NArCH)2]…”
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Homoleptic Rare-Earth Metal(III) Tetramethylaluminates: Structural Chemistry, Reactivity, and Performance in Isoprene Polymerization by Zimmermann, Melanie, Frøystein, Nils Åge, Fischbach, Andreas, Sirsch, Peter, Dietrich, H. Martin, Törnroos, Karl W., Herdtweck, Eberhardt, Anwander, Reiner

“…The complexes [Ln(AlMe4)3] (Ln=Y, La, Ce, Pr, Nd, Sm, Ho, Lu) have been synthesized by an amide elimination route and the structures of [Lu{(μ‐Me)2AlMe2}3],…”
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The first metal complexes of bis(diisopropylamino)carbene: synthesis, structure and ligand properties by Denk, Karin, Sirsch, Peter, Herrmann, Wolfgang A

“…The synthesis of rhodium(I) and iridium(I) complexes of the bis(diisopropylamino)carbene is described for the first time. The formamidinium chloride and the…”
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Gallatabenzene Ligands Emerging from Open Lutetocene and Yttrocene Methyl Complexes by Lebon, Jakob, Beauvois, Maxime, Maichle-Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner

“…Utilizing ternary mixtures [LnMe3]n/K(2,4-dtbp)/GaMe3 (Ln = Lu, Y; 2,4-dtbp = 2,4-di-tert-butyl-pentadienyl), a series of metallacycles is accessible via…”
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Well-Defined Molecular Magnesium Hydride Clusters: Relationship between Size and Hydrogen-Elimination Temperature by Intemann, Julia, Spielmann, Jan, Sirsch, Peter, Harder, Sjoerd

“…A new tetranuclear magnesium hydride cluster, [{NN‐(MgH)2}2], which was based on a NN‐coupled bis‐β‐diketiminate ligand (NN2−), was obtained from the reaction…”
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Comparison of Hydrogen Elimination from Molecular Zinc and Magnesium Hydride Clusters by Intemann, Julia, Sirsch, Peter, Harder, Sjoerd

“…In analogy to the previously reported tetranuclear magnesium hydride cluster with a bridged dianionic bis‐β‐diketiminate ligand, a related zinc hydride cluster…”
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A Terminal Yttrium Phosphinidene by Rieser, Theresa E., Wetzel, Philipp, Maichle-Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner

“…Terminal, nondirectional ionic “multiple” bond interactions between group 15 elements and rare-earth metals (Ln) have remained a challenging target until…”
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Yttrium Calix[4]arene Complexes. Silylation and Silylamine Elimination Reactions on Model Oxo Surfaces by Anwander, Reiner, Eppinger, Jörg, Nagl, Iris, Scherer, Wolfgang, Tafipolsky, Maxim, Sirsch, Peter

“…The synthesis and the spectroscopic and structural characterization of lower-rim-silylated and rare-earth-metalated calix[4]arenes are presented…”
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Schlenk's Legacy—Methyllithium Put under Close Scrutiny by Lebon, Jakob, Mortis, Alexandros, Maichle‐Mössmer, Cäcilia, Manßen, Manfred, Sirsch, Peter, Anwander, Reiner

“…Commercially available stock solutions of organolithium reagents are well‐implemented tools in organic and organometallic chemistry. However, such solutions…”
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Gallium Methylene by Bonath, Martin, Maichle‐Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner

“…Despite the eminent importance of metal alkylidene species for organic synthesis and industrial catalytic processes, molecular homoleptic metal methylene…”
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Open-Shell Early Lanthanide Terminal Imides by Rieser, Theresa E, Thim-Spöring, Renita, Schädle, Dorothea, Sirsch, Peter, Litlabø, Rannveig, Törnroos, Karl W, Maichle-Mössmer, Cäcilia, Anwander, Reiner

“…Group 3- and 4f-element organometallic chemistry and reactivity are decisively driven by the rare-earth-metal/lanthanide (Ln) ion size and associated…”
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Molecular Ln(III)−H−E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb) by Widemann, Max, Aicher, Frederik S. W., Bonath, Martin, Eichele, Klaus, Maichle‐Mössmer, Cäcilia, Schubert, Hartmut, Sirsch, Peter, Anwander, Reiner, Wesemann, Lars

“…Following the alkane‐elimination route, the reaction between tetravalent aryl tintrihydride Ar*SnH3 and trivalent rare‐earth‐metallocene alkyls…”
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Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions by Maudrich, Jakob‐Jonathan, Widemann, Max, Diab, Fatima, Kern, Ralf H., Sirsch, Peter, Sindlinger, Christian P., Schubert, Hartmut, Wesemann, Lars

“…Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar*GeH2]−…”
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Cyclic Distannene or Bis(stannylene) with a Ferrocenyl Backbone: Synthesis, Structure, and Coordination Chemistry by Henoch, Jessica, Auch, Armin, Diab, Fatima, Eichele, Klaus, Schubert, Hartmut, Sirsch, Peter, Block, Theresa, Pöttgen, Rainer, Wesemann, Lars

“…1,1′-Dilithioferrocene was reacted with 2 equiv of isopropyl (Ar*) or methyl (Ar′) substituted terphenyl tin­(II) chloride. Reaction product 1, carrying the…”
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Complexation of N-heterocyclic silylenes to Pd(0): formation of highly labile homoleptic complexes Pd[tBu)]4 and Pd[tBu)]3 by Herrmann, Wolfgang A., Härter, Peter, Gstöttmayr, Christian W.K., Bielert, Frank, Seeboth, Nicolas, Sirsch, Peter

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Hydride–Hydride Bonding Interactions in the Hydrogen Storage Materials AlH 3 , MgH 2 , and NaAlH 4 by Sirsch, Peter, Che, Franklin N., Titah, James T., McGrady, G. Sean

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Schlenks Vermächtnis – Methyllithium unter der Lupe by Lebon, Jakob, Mortis, Alexandros, Maichle‐Mössmer, Cäcilia, Manßen, Manfred, Sirsch, Peter, Anwander, Reiner

“…Kommerziell erhältliche Stammlösungen von Organolithiumverbindungen sind vielfach eingesetzte Reagenzien in der Organischen und Metallorganischen Chemie…”
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Hydride-Hydride Bonding Interactions in the Hydrogen Storage Materials AlH3, MgH2, and NaAlH4 by Sirsch, Peter, Che, Franklin N., Titah, James T., McGrady, G. Sean

“…Force of attraction: The structures and electron distribution of the hydrogen storage materials AlH3, MgH2, and NaAlH4 were explored in detail. Topological…”
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C–H Bond Activation and Isoprene Polymerization by Lutetium Alkylaluminate/gallate Complexes Bearing a Peripheral Boryl and a Bulky Hydrotris(pyrazolyl)borate Ligand by Bonath, Martin, Hollfelder, Christoph O., Schädle, Dorothea, Maichle‐Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner

“…The bimetallic lutetium alkylaluminate complex [(TptBu,Me)Lu(Me)(AlMe3{B(NDippCH)2})] {TptBu,Me = hydrotris(3‐Me‐5‐tBu‐pyrazolyl)borate} formed readily upon…”
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Nature of the Bonding in Metal-Silane σ-Complexes by McGrady, G. Sean, Sirsch, Peter, Chatterton, Nicholas P, Ostermann, Andreas, Gatti, Carlo, Altmannshofer, Sandra, Herz, Verena, Eickerling, Georg, Scherer, Wolfgang

“…The nature of metal silane σ-bond interaction has been investigated in several key systems by a range of experimental and computational techniques. The…”
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