Search Results - "Singh, Thishana"
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Iridium-catalyzed enantioconvergent hydrogenation of trisubstituted olefins
Published in Nature communications (18-01-2022)“…Asymmetric hydrogenation of olefins constitutes a practical and efficient method to introduce chirality into prochiral substrates. However, the absolute…”
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Microwave-mediated synthesis of surface-active ionic liquid-capped ZnS quantum dots: morphological studies and their applicability for fluorometric sensing of ascorbic acid
Published in Applied physics. A, Materials science & processing (01-10-2020)“…In this paper, we have synthesized surface active ionic liquid (SAIL)-capped zinc sulfide (ZnS) quantum dots (QDs) with an average size of approximately…”
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Asymmetric Synthesis and Applications of Chiral Organoselenium Compounds: A Review
Published in Molecules (Basel, Switzerland) (01-08-2024)“…The synthesis and application of organoselenium compounds have developed rapidly, and chiral organoselenium compounds have become an important intermediate in…”
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Emergency care drugs' chemical stability after eight weeks' deployment in the prehospital setting
Published in African Journal of Emergency Medicine (01-03-2024)“…Temperature conditions vary in emergency service vehicles, which may pose a risk to the integrity of the drugs on board, possibly rendering them ineffective…”
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Experimental and Theoretical Mechanistic Investigation of the Iridium-Catalyzed Dehydrogenative Decarbonylation of Primary Alcohols
Published in Journal of the American Chemical Society (21-01-2015)“…The mechanism for the iridium–BINAP catalyzed dehydrogenative decarbonylation of primary alcohols with the liberation of molecular hydrogen and carbon monoxide…”
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Biological Activity of Late Transition Metal‐Based Compounds: From Computational and Theoretical Studies to Laboratory Exploration and Beyond
Published in Bioinorganic chemistry and applications (01-01-2024)“…The use of metal compounds such as cisplatin and its derivatives as therapeutic and diagnostic agents against various diseases is well established. Although…”
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Facile synthesis of N-doped graphene encapsulated Ni@N/C catalyst and its catalysis for highly selective semi-hydrogenation of alkynes
Published in Green chemical engineering (01-12-2022)“…Although precious transition metals such as palladium, platinum, and iridium are widely used in hydrogenation reactions, the earth-abundant transition…”
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A Review on Interactions between Amino Acids and Surfactants as Well as Their Impact on Corrosion Inhibition
Published in ACS omega (27-12-2022)“…Amino acid–surfactant interactions are central to numerous studies because of their increased effectiveness in chemical, biological, household and industrial…”
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Green Synthesis, Experimental and Theoretical Studies to Discover Novel Binders of Exosomal Tetraspanin CD81 Protein
Published in ACS omega (28-07-2020)“…A new class of benzothiazole-appended quinoline derivatives (6–8) was synthesized via one-pot TPGS micellar-mediated acid-catalyzed nucleophilic addition,…”
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Stereoselective synthesis towards unnatural proline based amino acids
Published in ARKIVOC (07-02-2016)Get full text
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A DFT study of polyaniline/ZnO nanocomposite as a photocatalyst for the reduction of methylene blue dye
Published in Journal of molecular liquids (01-11-2019)“…Water pollution is a major environmental concern since many water sources are being contaminated with pollutants that are not easily degraded. Photocatalysis…”
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Selenium-Directed ortho-C–H Borylation by Iridium Catalysis
Published in Journal of organic chemistry (18-09-2020)“…An iridium-catalyzed selenium-directed ortho-C–H borylation of benzyl selenide derivatives was successfully developed. This is the first example where selenium…”
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Behaviour of 1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimdazolium thiocyanate and 1-butyl-1-methypyrrolidium chloride in dimethyl sulfoxide: Experimental, NCI and QTAIM analysis
Published in Journal of molecular liquids (01-12-2024)“…•Investigation of binary DMSO-IL solvation behaviour.•Calculations of volumetric and acoustic properties.•DFT calculations, NCI and QTAIM analysis to examine…”
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Deep eutectic solvents as reusable catalysts and promoter for the greener syntheses of small molecules: Recent advances
Published in Journal of molecular liquids (01-02-2023)“…Cutting-edge applications of DES as a reusable catalyst in the green synthesis of assorted potentially biologically active molecules. [Display omitted] •This…”
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A DFT study of the chemical reactivity properties, spectroscopy and bioactivity scores of bioactive flavonols
Published in Computational and theoretical chemistry (01-04-2022)“…[Display omitted] •Theoretical investigation of 15 natural flavonol aglycones.•QM was used to determine the chemical reactivity properties.•Electronic…”
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Commercial Copper‐Catalyzed Aerobic Oxidative Synthesis of Quinazolinones from 2‐Aminobenzamide and Methanol
Published in European journal of organic chemistry (14-05-2020)“…The focus of this study was the development of a new synthetic method for quinazolinones based on the principles of Green Chemistry. Quinazolinones were…”
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Microwave-assisted commercial copper-catalyzed aerobic oxidative synthesis of AChE quinazolinone inhibitors under solvent free conditions
Published in RSC advances (18-09-2023)“…A facile and green one-pot synthesis of AChE quinazolinone inhibitors was developed using microwave irradiation under solvent free conditions. Quinazolinones…”
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An Enantioselective Approach to the Preparation of Chiral Sulfones by Ir-Catalyzed Asymmetric Hydrogenation
Published in Journal of the American Chemical Society (26-11-2014)“…Several chiral sulfonyl compounds were prepared using the iridium catalyzed asymmetric hydrogenation reaction. Vinylic, allylic and homoallylic sulfone…”
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Stereodivergent Synthesis of Trisubstituted Enamides: Direct Access to Both Pure Geometrical Isomers
Published in Journal of organic chemistry (01-11-2019)“…A stereodivergent strategy has been developed to access either (E)- or (Z)-isomers of trisubstituted enamides. Starting from an extensive range of ketones, it…”
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