Search Results - "Singer, Philip M"
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Emergence of the spin polarized domains in the kagome lattice Heisenberg antiferromagnet Zn-barlowite (Zn0.95Cu0.05)Cu3(OD)6FBr
Published in npj quantum materials (27-12-2022)“…Kagome lattice Heisenberg antiferromagnets are known to be highly sensitive to perturbations caused by the structural disorder. NMR is a local probe ideally…”
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2
Diffusive coupling in heptane-saturated kerogen isolates evidenced by NMR T1-T2 and T2-T2 maps
Published in Fuel (Guildford) (15-11-2020)“…[Display omitted] •Diffusive coupling found between inter-granular and dissolved heptane in kerogen.•T2-T2 maps show off-diagonal exchange peaks due to…”
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3
Molecular dynamics simulations of NMR relaxation and diffusion of bulk hydrocarbons and water
Published in Journal of magnetic resonance (1997) (01-04-2017)“…[Display omitted] •MD simulations of T1,2 and diffusion show good agreement with measurements.•No adjustable parameters are used in going from simulation data…”
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4
Emergence of spin singlets with inhomogeneous gaps in the kagome lattice Heisenberg antiferromagnets Zn-barlowite and herbertsmithite
Published in Nature physics (01-10-2021)“…The kagome Heisenberg antiferromagnet formed by frustrated spins arranged in a lattice of corner-sharing triangles is a prime candidate for hosting a quantum…”
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5
Critical Role of Confinement in the NMR Surface Relaxation and Diffusion of n‑Heptane in a Polymer Matrix Revealed by MD Simulations
Published in The journal of physical chemistry. B (07-05-2020)“…The mechanism behind the NMR surface-relaxation times (T 1S,2S) and the large T 1S/T 2S ratio of light hydrocarbons confined in the nanopores of kerogen…”
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6
Effect of Nanoconfinement on NMR Relaxation of Heptane in Kerogen from Molecular Simulations and Measurements
Published in The journal of physical chemistry letters (02-02-2023)“…Kerogen-rich shale reservoirs will play a key role during the energy transition, yet the effects of nanoconfinement on the NMR relaxation of hydrocarbons in…”
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7
Molecular Modes Elucidate the Nuclear Magnetic Resonance Relaxation of Viscous Fluids
Published in The journal of physical chemistry. B (22-08-2024)“…The Bloembergen, Purcell, and Pound (BPP) theory of nuclear magnetic resonance (NMR) relaxation in fluids dating back to 1948 continues to be the linchpin in…”
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8
Distinguishing the Effect of Rock Wettability from Residual Oil on Foam Generation and Propagation in Porous Media
Published in Energy & fuels (06-05-2021)“…One of the common challenges of applying foam for enhanced oil recovery is the foam instability in the presence of crude oil and nonwater-wet surfaces. In this…”
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9
Interpretation of NMR Relaxation in Bitumen and Organic Shale Using Polymer–Heptane Mixes
Published in Energy & fuels (15-02-2018)“…One of the much debated mysteries in 1H NMR relaxation measurements of bitumen and heavy crude oils is the departure from expected theoretical trends at high…”
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10
Elucidating the 1 H NMR Relaxation Mechanism in Polydisperse Polymers and Bitumen Using Measurements, MD Simulations, and Models
Published in The journal of physical chemistry. B (21-05-2020)“…The mechanism behind the H nuclear magnetic resonance (NMR) frequency dependence of and the viscosity dependence of for polydisperse polymers and bitumen…”
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11
A more accurate estimate of T2 distribution from direct analysis of NMR measurements
Published in Journal of magnetic resonance (1997) (01-03-2013)“…[Display omitted] ▸ We propose a modified inversion of the relaxation distribution from NMR data. ▸ Solution is less sensitive to regularization. ▸ Estimates…”
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12
Characterization of Single-Phase Flow Through Carbonate Rocks: Quantitative Comparison of NMR Flow Propagator Measurements with a Realistic Pore Network Model
Published in Transport in porous media (2010)“…We report here the quantitative comparisons between the measured NMR flow propagator of a carbonate rock and the flow propagator calculated with a porous…”
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13
Low magnetic fields for flow propagators in permeable rocks
Published in Journal of magnetic resonance (1997) (01-12-2006)“…Pulsed field gradient NMR flow propagators for water flow in Bentheimer sandstone are measured at low fields ( 1H resonance 2 MHz), using both unipolar and…”
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14
Diffusive coupling in heptane-saturated kerogen isolates evidenced by NMR T 1 - T 2 and T 2 - T 2 maps
Published in Fuel (Guildford) (15-11-2020)Get full text
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15
Separation of solid and liquid components in organic-rich chalks using NMR relaxation
Published in Fuel (Guildford) (01-02-2023)“…[Display omitted] •Solid components obtained from multi-Gaussian T2G decay using solid-echo.•Liquid components obtained from multi-exponential T2e decay using…”
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Characterization of kerogen and bitumen in Type II-S organic-rich chalk as a function of maturity using 2D NMR relaxation
Published in Fuel (Guildford) (01-07-2024)“…As kerogen matures over geological times, bitumen is generated inside kerogen. With further maturation, bitumen can coat the inorganic meso-macro pores, which…”
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17
Spin Excitations of a Proximate Kitaev Quantum Spin Liquid Realized in Cu2IrO3
Published in Physical review. X (13-09-2019)“…Magnetic moments arranged at the corners of a honeycomb lattice are predicted to form a novel state of matter, the Kitaev quantum spin liquid, under the…”
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18
Revisiting the 63 Cu NMR Signature of Charge Order in La 1.875 Ba 0.125 CuO 4
Published in Journal of the Physical Society of Japan (15-03-2021)Get full text
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Revisiting the 63Cu NMR Signature of Charge Order in La1.875Ba0.125CuO4
Published in Journal of the Physical Society of Japan (15-03-2021)“…We use single crystal 63Cu NMR techniques to revisit the early 63Cu NQR signature of charge order observed for La1.875Ba0.125CuO4 (Tc = 4 K) [A. W. Hunt et…”
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20
Freezing of the Lattice in the Kagome Lattice Heisenberg Antiferromagnet Zn-Barlowite ZnCu3(OD)6FBr
Published in Physical review letters (15-04-2022)“…Here, we use 79Br nuclear quadrupole resonance (NQR) to demonstrate that ultraslow lattice dynamics set in below the temperature scale set by the Cu-Cu…”
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