Search Results - "Sims, Howard E."
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Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions
Published in The journal of physical chemistry. B (17-11-2016)“…A multiscale modeling approach has been developed for the extended time scale long-term radiolysis of aqueous systems. The approach uses a combination of…”
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Radiation chemical processes in the water layer on the surface of PuO2
Published in Frontiers in nuclear engineering (17-04-2024)“…It is generally accepted that radiolysis of water on the surface of PuO 2 by alpha particles is the source of H 2 which can cause pressurisation in sealed…”
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Plutonium and Americium Alpha Radiolysis of Nitric Acid Solutions
Published in The journal of physical chemistry. B (02-02-2017)“…The yield of HNO2, as a function of absorbed dose and HNO3 concentration, from the α-radiolysis of aerated HNO3 solutions containing plutonium or americium has…”
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Molecular Hydrogen Yields from the α‑Self-Radiolysis of Nitric Acid Solutions Containing Plutonium or Americium
Published in The journal of physical chemistry. B (08-03-2018)“…The yield of molecular hydrogen, as a function of nitric acid concentration, from the α-radiolysis of aerated nitric acid and its mixtures with sulfuric acid…”
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5
Hydrogen yields from water on the surface of plutonium dioxide
Published in Journal of nuclear materials (01-06-2013)“…► Hydrogen evolution due to water radiolysis on samples of Sellafield PuO2. ► Sharp increase in hydrogen evolution above 75% relative humidity. ► Hydrogen…”
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Modeling the critical hydrogen concentration in the AECL test reactor
Published in Radiation physics and chemistry (Oxford, England : 1993) (01-01-2013)“…Hydrogen is added to a pressurized water reactor (PWR) to suppress radiolysis and maintain reducing conditions. The minimum hydrogen concentration needed to…”
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A model of chemistry and thermal hydraulics in PWR fuel crud deposits
Published in Journal of nuclear materials (01-07-2006)“…A model is described for simulating thermal hydraulic and chemical conditions within fuel crud deposits. Heat transfer takes place by wick boiling in which…”
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Modelling Np(IV) Solvent Extraction between 30% Tri-Butyl Phosphate and Nitric Acid in the Presence of Simple Hydroxamic Acids
Published in Solvent extraction and ion exchange (31-01-2011)“…Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions from a tri-butyl phosphate phase into nitric acid. A…”
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Extraction of Neptunium (IV) Ions into 30% Tri-Butyl Phosphate from Nitric Acid
Published in Solvent extraction and ion exchange (01-12-2009)“…The distribution of Np(IV) between 0.08-4.5 M HNO 3(aq,eqm) and ∼30% tributyl phosphate has been modelled, accounting for the formation of 1:1 and 1:2 nitrate…”
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Lithium reduction of a MOX pellet
Published in Journal of nuclear science and technology (01-11-2002)“…The MOX pellet of approximately 10g was reduced with lithium metal in molten lithium chloride at 923K. The pellet has high density and consists of 90% of…”
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Magnesium hydroxide bulk and colloid-associated 152Eu in an alkaline environment: colloid characterisation and sorption properties in the presence and absence of carbonate
Published in Journal of environmental monitoring (01-03-2008)“…The distribution of 152Eu between magnesium hydroxide bulk, colloids and solution has been assessed under alkaline conditions, such as those in nuclear fuel…”
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Chemical Reduction of SIM MOX in Molten Lithium Chloride Using Lithium Metal Reductant
Published in Zeitschrift für Naturforschung. A, A journal of physical sciences (01-09-2007)“…A simulated spent oxide fuel in a sintered pellet form, which contained the twelve elements U, Pu, Am, Np, Cm, Ce, Nd, Sm, Ba, Zr,Mo, and Pd, was reduced with…”
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