Search Results - "Simpkins, Blake S"

Mode-Specific Chemistry through Vibrational Strong Coupling (or A Wish Come True) by Simpkins, Blake S, Dunkelberger, Adam D, Owrutsky, Jeffrey C

“…Vibrational strong coupling offers newfound potential to affect chemical processes and represents a wholly new approach to catalysis. While this presents…”
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Two-dimensional infrared spectroscopy of vibrational polaritons by Xiang, Bo, Ribeiro, Raphael F., Dunkelberger, Adam D., Wang, Jiaxi, Li, Yingmin, Simpkins, Blake S., Owrutsky, Jeffrey C., Yuen-Zhou, Joel, Xiong, Wei

“…We report experimental 2D infrared (2D IR) spectra of coherent light–matter excitations—molecular vibrational polaritons. The application of advanced 2D IR…”
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Negligible Effect of Vibrational Polaritons on Chemical Reaction Rates via the Density of States Pathway by Vurgaftman, Igor, Simpkins, Blake S, Dunkelberger, Adam D, Owrutsky, Jeffrey C

“…We show that the polariton density of states in planar optical cavities strongly coupled to vibrational excitations remains much lower than the density of…”
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Excited-state vibration-polariton transitions and dynamics in nitroprusside by Grafton, Andrea B., Dunkelberger, Adam D., Simpkins, Blake S., Triana, Johan F., Hernández, Federico J., Herrera, Felipe, Owrutsky, Jeffrey C.

“…Strong cavity coupling to molecular vibrations creates vibration-polaritons capable of modifying chemical reaction kinetics, product branching ratios, and…”
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Ultrafast Transmission Modulation and Recovery via Vibrational Strong Coupling by Dunkelberger, Adam D, Davidson, Roderick B, Ahn, Wonmi, Simpkins, Blake S, Owrutsky, Jeffrey C

“…Strong coupling between vibrational modes and cavity optical modes leads to the formation of vibration–cavity polaritons, separated by the vacuum Rabi…”
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Enabling remote quantum emission in 2D semiconductors via porous metallic networks by Fonseca, Jose J., Yeats, Andrew L., Blue, Brandon, Zalalutdinov, Maxim K., Brintlinger, Todd, Simpkins, Blake S., Ratchford, Daniel C., Culbertson, James C., Grim, Joel Q., Carter, Samuel G., Ishigami, Masa, Stroud, Rhonda M., Cress, Cory D., Robinson, Jeremy T.

“…Here we report how two-dimensional crystal (2DC) overlayers influence the recrystallization of relatively thick metal films and the subsequent synergetic…”
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Potential of TiN/GaN Heterostructures for Hot Carrier Generation and Collection by Simpkins, Blake S, Maximenko, Sergey I, Baturina, Olga

“…Herein, we find that TiN sputter-deposited on GaN displayed the desired optical properties for plasmonic applications. While this is a positive result…”
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Modification of ground-state chemical reactivity via light-matter coherence in infrared cavities by Ahn, Wonmi, Triana, Johan F, Recabal, Felipe, Herrera, Felipe, Simpkins, Blake S

“…Reaction-rate modifications for chemical processes due to strong coupling between reactant molecular vibrations and the cavity vacuum have been reported;…”
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Saturable Absorption in Solution-Phase and Cavity-Coupled Tungsten Hexacarbonyl by Dunkelberger, Adam D, Grafton, Andrea B, Vurgaftman, Igor, Soykal, Öney O, Reinecke, Thomas L, Davidson, Roderick B, Simpkins, Blake S, Owrutsky, Jeffrey C

“…Saturable absorption, in which optical absorption decreases as the incident intensity increases, is commonly utilized in the visible and near-infrared for…”
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Control, Modulation, and Analytical Descriptions of Vibrational Strong Coupling by Simpkins, Blake S., Dunkelberger, Adam D., Vurgaftman, Igor

“…Here, we review the design of optical cavities, transient and modulated responses, and theoretical models relevant to vibrational strong coupling (VSC). While…”
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Vibration-Cavity Polariton Chemistry and Dynamics by Dunkelberger, Adam D, Simpkins, Blake S, Vurgaftman, Igor, Owrutsky, Jeffrey C

“…Molecular polaritons result from light-matter coupling between optical resonances and molecular electronic or vibrational transitions. When the coupling is…”
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Impact of Cavity Length Non-uniformity on Reaction Rate Extraction in Strong Coupling Experiments by Michon, Michael A., Simpkins, Blake S.

“…Reports of altered chemical phenomena under vibrational strong coupling, including reaction rates, product distributions, intermolecular forces, and…”
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Theory for Nonlinear Spectroscopy of Vibrational Polaritons by F. Ribeiro, Raphael, Dunkelberger, Adam D, Xiang, Bo, Xiong, Wei, Simpkins, Blake S, Owrutsky, Jeffrey C, Yuen-Zhou, Joel

“…Molecular polaritons have gained considerable attention due to their potential to control nanoscale molecular processes by harnessing electromagnetic…”
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3-D near-field imaging of guided modes in nanophotonic waveguides by Ziegler, Jed I., Pruessner, Marcel W., Simpkins, Blake S., Kozak, Dmitry A., Park, Doewon, Fatemi, Fredrik K., Stievater, Todd H.

“…Highly evanescent waveguides with a subwavelength core thickness present a promising lab-on-chip solution for generating nanovolume trapping sites using…”
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Comment on “Isolating Polaritonic 2D-IR Transmission Spectra” by Simpkins, Blake S., Yang, Zimo, Dunkelberger, Adam D., Vurgaftman, Igor, Owrutsky, Jeffrey C., Xiong, Wei

“…This Viewpoint responds to the analysis of 2D IR spectra of vibration cavity polaritons in the study reported in The Journal of Physical Chemistry Letters…”
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Hyperuniform disordered metal-insulator-metal gap plasmon metasurface near perfect light absorber by Kim, Wonkyu, Simpkins, Blake S., Guo, Hong, Hendrickson, Joshua R., Guo, Junpeng

“…In this work, we first introduce hyperuniform disordered patterns to a metal-insulator-metal gap plasmon metasurface and demonstrate enhanced wideband light…”
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Vibrational Strong Coupling Controlled by Spatial Distribution of Molecules within the Optical Cavity by Ahn, Wonmi, Vurgaftman, Igor, Dunkelberger, Adam D., Owrutsky, Jeffrey C., Simpkins, Blake S.

“…Similar to excitonic materials interacting with optical cavity fields, vibrational absorbers coupled to resonantly matched optical modes can exhibit new…”
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Spectroelectrochemical measurement and modulation of exciton-polaritons by Ahn, Wonmi, Simpkins, Blake S.

“…Quantum emitters strongly coupled to optical cavity modes create new hybrid states called polaritons, resulting in a vacuum Rabi splitting (Ω). Strikingly, the…”
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Synthesis, plasmonic properties, and CWA simulant decontamination activity of first row early transition metal nitride powders and nanomaterials by Purdy, Andrew P., Baturina, Olga A., Simpkins, Blake S., Giles, Spencer, Brintlinger, Todd, Wynne, James

“…The complexes MCl 3 (THF) 3 (M = Ti, V, Cr) were used as precursors to form early transition metal nitrides, and solid solutions of these isomorphous complexes…”
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Magnetic moment degradation of nanowires in biological media: real-time monitoring with SQUID magnetometry by Raphael, Marc P, Christodoulides, Joseph A, Qadri, Syed N, Simpkins, Blake S, Byers, Jeff M

“…Magnetic nanoparticles are used throughout biology for applications from targeted drug and gene delivery to the labeling of cells. These nanoparticles…”
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