Search Results - "Silverio, Daniel L."

Catalytic enantioselective addition of organoboron reagents to fluoroketones controlled by electrostatic interactions by Lee, KyungA, Silverio, Daniel L., Torker, Sebastian, Robbins, Daniel W., Haeffner, Fredrik, van der Mei, Farid W., Hoveyda, Amir H.

“…Organofluorine compounds are central to modern chemistry, and broadly applicable transformations that generate them efficiently and enantioselectively are in…”
Get full text

Simple organic molecules as catalysts for enantioselective synthesis of amines and alcohols by Silverio, Daniel L., Torker, Sebastian, Pilyugina, Tatiana, Vieira, Erika M., Snapper, Marc L., Haeffner, Fredrik, Hoveyda, Amir H.

“…A set of small organic molecules catalyse reactions of unsaturated organoboron reagents with imines and carbonyls to produce amines and alcohols in high…”
Get full text

N-Substituted tertiary and O-substituted quaternary carbon stereogenic centers by site-, diastereo- and enantioselective vinylogous Mannich reactions by Silverio, Daniel L., Fu, Peng, Carswell, Emma L., Snapper, Marc L., Hoveyda, Amir H.

“…[Display omitted] A readily accessible small-molecule phosphine, derived from commercially available starting materials such as an enantiomerically pure amino…”
Get full text

Three-Dimensional Structure Determination of Surface Sites by Berruyer, Pierrick, Lelli, Moreno, Conley, Matthew P, Silverio, Daniel L, Widdifield, Cory M, Siddiqi, Georges, Gajan, David, Lesage, Anne, Copéret, Christophe, Emsley, Lyndon

“…The spatial arrangement of atoms is directly linked to chemical function. A fundamental challenge in surface chemistry and catalysis relates to the…”
Get full text

Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective [gamma]-Additions of Allylboron Moieties to Aldimines by vanderMei, Farid W, Miyamoto, Hiroshi, Silverio, Daniel L, Hoveyda, Amir H

“…Catalytic allylboron additions to aldimines are presented for which small amounts of Zn(OMe)2 serve as the co-catalyst to accelerate allyl exchange and…”
Get full text

Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters by Robbins, Daniel W., Lee, KyungA, Silverio, Daniel L., Volkov, Alexey, Torker, Sebastian, Hoveyda, Amir H.

“…A set of broadly applicable methods for efficient catalytic additions of easy‐to‐handle allyl‐B(pin) (pin=pinacolato) compounds to ketones and acyclic…”
Get full text

To the Literature and Beyond: Teaching Advanced Organic Chemistry at a Primarily Undergraduate Institution by Silverio, Daniel L., Mistretta, Matthew J., Buzzolani, Scott P.

“…Offering an advanced organic chemistry course at a primarily undergraduate institution poses a challenge of condensing graduate organic synthesis into one…”
Get full text

Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective γ-Additions of Allylboron Moieties to Aldimines by van der Mei, Farid W., Miyamoto, Hiroshi, Silverio, Daniel L., Hoveyda, Amir H.

“…Catalytic allylboron additions to aldimines are presented for which small amounts of Zn(OMe)2 serve as the co‐catalyst to accelerate allyl exchange and…”
Get full text

Tailored Polarizing Hybrid Solids with Nitroxide Radicals Localized in Mesostructured Silica Walls by Silverio, Daniel L., Kalkeren, Henri A., Ong, Ta‐Chung, Baudin, Mathieu, Yulikov, Maxim, Veyre, Laurent, Berruyer, Pierrick, Chaudhari, Sachin, Gajan, David, Baudouin, David, Cavaillès, Matthieu, Vuichoud, Basile, Bornet, Aurélien, Jeschke, Gunnar, Bodenhausen, Geoffrey, Lesage, Anne, Emsley, Lyndon, Jannin, Sami, Thieuleux, Chloé, Copéret, Christophe

“…Hyperpolarization by dynamic nuclear polarization relies on the microwave irradiation of paramagnetic radicals dispersed in molecular glasses to enhance the…”
Get full text

Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective γ-Additions of Allylboron Moieties to Aldimines by van der Mei, Farid W., Miyamoto, Hiroshi, Silverio, Daniel L., Hoveyda, Amir H.

“…Catalytic allylboron additions to aldimines are presented for which small amounts of Zn(OMe)2 serve as the co‐catalyst to accelerate allyl exchange and…”
Get full text

Synthesis and properties of liquid phenyliodine dicarboxylates by Callovi, Christina, War, Su Wint, Semczuk, Calvin N., Fisher, Madison, Rodriguez, Matthew Lucero, Plaut, Joshua, Joshi, Ivana, Hyatt, I. F. Dempsey, Silverio, Daniel L.

Get full text

Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and [alpha]-Ketoesters by Robbins, Daniel W, Lee, KyungA, Silverio, Daniel L, Volkov, Alexey, Torker, Sebastian, Hoveyda, Amir H

“…A set of broadly applicable methods for efficient catalytic additions of easy-to-handle allyl-B(pin) (pin=pinacolato) compounds to ketones and acyclic…”
Get full text

Ligand exchange of aryl iodine dicarboxylates to form reagents with differing solubilities by Seecharan, Vanie, Armand, Lyse, Noorollah, Jennifer, Singh, Nirvanie, Zhang, Andrew, Freddo, Kevin P., Spatola, Nicholas, Prasad, Sailesh, Chaudhry, Azka, War, Su Wint, Hyatt, I. F. Dempsey, Silverio, Daniel L.

Get full text

Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters by Robbins, Daniel W., Lee, KyungA, Silverio, Daniel L., Volkov, Alexey, Torker, Sebastian, Hoveyda, Amir H.

“…A set of broadly applicable methods for efficient catalytic additions of easy‐to‐handle allyl‐B(pin) (pin=pinacolato) compounds to ketones and acyclic…”
Get full text

Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and [alpha]-Ketoesters by Robbins, Daniel W, Lee, KyungA, Silverio, Daniel L, Volkov, Alexey, Torker, Sebastian, Hoveyda, Amir H

“…A set of broadly applicable methods for efficient catalytic additions of easy-to-handle allyl-B(pin) (pin=pinacolato) compounds to ketones and acyclic…”
Get full text

Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective [gamma]-Additions of Allylboron Moieties to Aldimines by vanderMei, Farid W, Miyamoto, Hiroshi, Silverio, Daniel L, Hoveyda, Amir H

“…Catalytic allylboron additions to aldimines are presented for which small amounts of Zn(OMe)2 serve as the co-catalyst to accelerate allyl exchange and…”
Get full text

Development of amino acid-derived ligands for enantioselective synthesis of amines and alcohols by Silverio, Daniel L

“…Chapter One: Development of Simple Organic Molecules as Catalysts for Enantioselective Allyl Additions to N-Phosphinoylaldimines and Isatins. A new catalytic…”
Get full text