Search Results - "Silva, Telma F S"
-
1
Cobalt complexes bearing scorpionate ligands: synthesis, characterization, cytotoxicity and DNA cleavage
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2012)“…A number of novel, water-stable redox-active cobalt complexes of the C-functionalized tripodal ligands tris(pyrazolyl)methane XC(pz)(3) (X = HOCH(2),…”
Get more information
Journal Article -
2
Recent Advances in Copper Catalyzed Alcohol Oxidation in Homogeneous Medium
Published in Molecules (Basel, Switzerland) (09-02-2020)“…The development of sustainable processes and products through innovative catalytic materials and procedures that allow a better use of resources is undoubtedly…”
Get full text
Journal Article -
3
Novel Methinic Functionalized and Dendritic C-Scorpionates
Published in Molecules (Basel, Switzerland) (23-11-2018)“…The study of chelating ligands is undoubtedly one of the most significant fields of research in chemistry. The present work is directed to the synthesis of new…”
Get full text
Journal Article -
4
Half-Sandwich Scorpionate Vanadium, Iron and Copper Complexes: Synthesis and Application in the Catalytic Peroxidative Oxidation of Cyclohexane under Mild Conditions
Published in Advanced synthesis & catalysis (25-03-2008)“…The new half‐sandwich scorpionate complexes [hydridotris(1‐pyrazolyl)methane]vanadium trichloride, ([VCl3{HC(pz)3}] 1 (pz=pyrazolyl),…”
Get full text
Journal Article -
5
Novel Scorpionate and Pyrazole Dioxovanadium Complexes, Catalysts for Carboxylation and Peroxidative Oxidation of Alkanes
Published in Advanced synthesis & catalysis (04-01-2010)“…The dioxovanadium(V) complexes [VO2(3,5‐Me2Hpz)3][BF4] (1) (pz=pyrazolyl), [VO2{SO3C(pz)3}] (2), [VO2{HB(3,5‐Me2pz)3}] (3) and [VO2{HC(pz)3}][BF4] (4), bearing…”
Get full text
Journal Article -
6
Cobalt Complexes with Pyrazole Ligands as Catalyst Precursors for the Peroxidative Oxidation of Cyclohexane: X-ray Absorption Spectroscopy Studies and Biological Applications
Published in Chemistry, an Asian journal (01-04-2014)“…[CoCl(μ‐Cl)(HpzPh)3]2 (1) and [CoCl2(HpzPh)4] (2) were obtained by reaction of CoCl2 with HC(pzPh)3 and HpzPh, respectively (HpzPh=3‐phenylpyrazole). The…”
Get full text
Journal Article -
7
Cobalt and Zinc Compounds Bearing 1,10-Phenanthroline-5,6-dione or 1,3,5-Triaza-7-phosphaadamantane Derivatives - Synthesis, Characterization, Cytotoxicity, and Cell Selectivity Studies
Published in European journal of inorganic chemistry (01-07-2013)“…The compounds [mPTA][CoCl4] (1, mPTA = N‐methyl‐1,3,5‐triaza‐7‐phosphaadamantane cation), [CoCl(H2O)(DION)2][BF4] (2, DION = 1,10‐phenanthroline‐5,6‐dione),…”
Get full text
Journal Article -
8
Pyrazole or tris(pyrazolyl)ethanol oxo-vanadium(IV) complexes as homogeneous or supported catalysts for oxidation of cyclohexane under mild conditions
Published in Journal of molecular catalysis. A, Chemical (01-02-2013)“…[Display omitted] ► New oxo-vanadium(IV) complexes with pyrazole or tris(pyrazolyl)ethanol ligands. ► Immobilization of those V complexes on a…”
Get full text
Journal Article -
9
Insights into the mechanisms underlying the antiproliferative potential of a Co(II) coordination compound bearing 1,10-phenanthroline-5,6-dione: DNA and protein interaction studies
Published in Journal of biological inorganic chemistry (01-08-2014)“…The very high antiproliferative activity of [Co(Cl)(H 2 O)(phendione) 2 ][BF 4 ] (phendione is 1,10-phenanthroline-5,6-dione) against three human tumor cell…”
Get full text
Journal Article -
10
Scorpionate complexes of vanadium(III or IV) as catalyst precursors for solvent-free cyclohexane oxidation with dioxygen
Published in Pure and applied chemistry (01-07-2009)“…The V-scorpionate vanadium complexes [VCl {HC(pz) }] (pz = pyrazolyl) and [VCl {SO C(pz) }] catalyze cyclohexane oxidation with dioxygen, to cyclohexanol (the…”
Get full text
Journal Article -
11
Ruthenium(II) Arene Complexes Bearing Tris(pyrazolyl)methanesulfonate Capping Ligands. Electrochemistry, Spectroscopic, and X-ray Structural Characterization
Published in Organometallics (28-11-2011)“…Novel [Ru(L)(Tpms)]Cl and [Ru(L)(TpmsPh)]Cl complexes (L = p-cymene, benzene, or hexamethylbenzene, Tpms = tris(pyrazolyl)methanesulfonate, TpmsPh =…”
Get full text
Journal Article -
12
Cu(II) complexes bearing the 2,2,2-tris(1-pyrazolyl)ethanol or 2,2,2-tris(1-pyrazolyl)ethyl methanesulfonate scorpionates. X-Ray structural characterization and application in the mild catalytic peroxidative oxidation of cyclohexane
Published in Dalton transactions : an international journal of inorganic chemistry (14-11-2009)“…Reactions between CuCl2 and the functionalized scorpionate 2,2,2-tris(1-pyrazolyl)ethanol HOCH2C(pz)3 1 (pz = pyrazolyl) or 2,2,2-tris(1-pyrazolyl)ethyl…”
Get more information
Journal Article -
13
Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanol ligands: Application in the peroxidative oxidation of cyclohexane under mild conditions
Published in Journal of organometallic chemistry (15-03-2011)“…The reactions of FeCl 2.2H 2O and 2,2,2-tris(1-pyrazolyl)ethanol HOCH 2C(pz) 3 ( 1) (pz = pyrazolyl) afford [Fe{HOCH 2C(pz) 3} 2][FeCl 4]Cl ( 2), [Fe{HOCH…”
Get full text
Journal Article -
14
Enhancing alkane oxidation using Co-doped SnO2 nanoparticles as catalysts
Published in Catalysis communications (01-06-2017)“…A novel eco-friendly KA oil synthesis at room temperature (up to 25% yield) via solvent-free cyclohexane oxidation using Sn1−xCoxO2−δ (x=0, 0.01 or 0.05)…”
Get full text
Journal Article -
15
Trends in properties of para-substituted 3-(phenylhydrazo)pentane-2,4-diones
Published in Journal of physical organic chemistry (01-09-2011)“…Trends between the Hammett's σp and related normal , inductive σI, resonance σR, negative and positive polar conjugation and Taft's σp° substituent constants…”
Get full text
Journal Article -
16
Synthesis and coordination chemistry of a new N4-polydentate class of pyridyl-functionalized scorpionate ligands: complexes of Fe(II), Zn(II), Ni(II), V(IV), Pd(II) and use for heterobimetallic systems
Published in Inorganic chemistry (06-09-2010)“…The new potentially N(4)-multidentate pyridyl-functionalized scorpionates 4-((tris-2,2,2-(pyrazol-1-yl)ethoxy)methyl)pyridine (TpmPy, (1)) and…”
Get full text
Journal Article -
17
Synthesis, characterization, electrochemical behavior and in vitro protein tyrosine kinase inhibitory activity of the cymene-halogenobenzohydroxamato [Ru(η6-cymene)(bha)Cl] complexes
Published in Journal of organometallic chemistry (15-04-2013)“…The ruthenium(II)–cymene complexes [Ru(η6-cymene)(bha)Cl] with substituted halogenobenzohydroxamato (bha) ligands (substituents = 4-F, 4-Cl, 4-Br, 2,4-F2,…”
Get full text
Journal Article -
18
-
19
Synthesis and Coordination Chemistry of a New N4-Polydentate Class of Pyridyl-Functionalized Scorpionate Ligands: Complexes of FeII, ZnII, NiII, VIV, PdII and Use for Heterobimetallic Systems
Published in Inorganic chemistry (06-09-2010)“…The new potentially N4-multidentate pyridyl-functionalized scorpionates 4-((tris-2,2,2-(pyrazol-1-yl)ethoxy)methyl)pyridine (TpmPy, (1)) and…”
Get full text
Journal Article -
20
Biological characterization of the antiproliferative potential of Co(II) and Sn(IV) coordination compounds in human cancer cell lines: a comparative proteomic approach
Published in Drug metabolism and drug interactions (2013)“…The discovery of cisplatin's antitumor activity led to a great interest in the potential application of coordination compounds as chemotherapeutic agents. It…”
Get more information
Journal Article