Search Results - "Silks, Louis A.“Pete”"
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CC or CO Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst
Published in Angewandte Chemie International Edition (02-04-2012)“…The aerobic oxidation of a phenolic lignin model compound with a vanadium catalyst results in the oxidative cleavage of the CC bond between the aryl ring and…”
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The hydrodeoxygenation of bioderived furans into alkanes
Published in Nature chemistry (01-05-2013)“…The conversion of biomass into fuels and chemical feedstocks is one part of a drive to reduce the world's dependence on crude oil. For transportation fuels in…”
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Ruthenium-8-quinolinethiolate-phenylterpyridine versus ruthenium-bipyridine-phenyl-terpyridine complexes as homogeneous water and high temperature stable hydrogenation catalysts for biomass-derived substrates
Published in Polyhedron (29-03-2016)“…The complex [(4′-Ph-terpy)(quSH)Ru(H)]+ acts as a metal–ligand bifunctional ionic hydrogenation catalyst for the conversion of the biomass derivable substrates…”
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Determining the Solution State Orientation of a Ti Enolate via Stable Isotope Labeling, NMR Spectroscopy, and Modeling Studies
Published in Journal of the American Chemical Society (03-12-2003)“…Our group has used Ti-promoted aldol additions with an oxazolidineselone as the chiral auxiliary with much success. In these reactions, the Se atom in the…”
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An EPR, ESEEM, Structural NMR, and DFT Study of a Synthetic Model for the Covalently Ring-Linked Tyrosine-Histidine Structure in the Heme-Copper Oxidases
Published in Journal of the American Chemical Society (03-03-2004)“…We report CW-EPR, ESEEM, and structural NMR results, as well as DFT calculations, on model compounds relevant to the unusual cross-linked Tyr-His (YH) moiety…”
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CC or CO Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst
Published in Angewandte Chemie (02-04-2012)“…Die aerobe Oxidation einer phenolischen Lignin‐Modellverbindung mit einem Vanadiumkatalysator führt zur oxidativen Spaltung der C‐C‐Bindung zwischen dem…”
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The hydrodeoxygenation of bioderived furans into alkanes
Published in Nature chemistry (01-06-2013)Get full text
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The hydrodeoxygenation of bioderived furans into alkanes: 1
Published in Nature chemistry (01-06-2013)Get full text
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Structural Studies on the Hairpins at the 3‘ Untranslated Region of an Anthrax Toxin Gene
Published in Biochemistry (Easton) (27-05-2003)“…Three proteins, namely, protective antigen (PA), edema factor (EF), and lethal factor (LF), encoded by the pX01 plasmid of Bacillus anthracis play a major role…”
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Synthesis of 13C labeled sulfur and nitrogen mustard metabolites as mass spectrometry standards for monitoring and detecting chemical warfare agents
Published in Journal of labelled compounds & radiopharmaceuticals (30-05-2012)“…13C labeled (>M + 4) metabolites of nitrogen and sulfur‐based chemical warfare agent metabolites were prepared from readily available and 13C labeled…”
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Compensating bends in a 16‐base‐pair DNA oligomer containing a T3A3 segment: A NMR study of global DNA curvature
Published in Biopolymers (15-12-2004)“…In‐phase ligated DNA containing TnAn segments fail to exhibit the retarded polyacrylamide gel electrophoresis (PAGE) migration observed for in‐phase ligated…”
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Synthesis and incorporation of [6,7]-selenatryptophan into dihydrofolate reductase
Published in Biochemical and biophysical research communications (25-10-2002)“…Until recently, the only selenium containing amino acid which could be used to completely substitute for a wild type amino acid was selenomethionine (SeMet)…”
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Stereoselectivity in Aldol Reactions of Chiral N-Acyl Selones
Published in Journal of the American Chemical Society (19-01-2000)“…Aldol reactions have played a central role in many stereoselective constructions of carbon-carbon bonds. During the past several years the selenocarbonyl group…”
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Innentitelbild: CC or CO Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst (Angew. Chem. 14/2012)
Published in Angewandte Chemie (02-04-2012)“…Vanadiumkomplexe katalysieren C‐C‐ und C‐O‐Bindungsspaltungen in einer Lignin‐Modellverbindung mit Luft als Oxidationsmittel. In ihrer Zuschrift auf S. 3466…”
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CC or CO Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst
Published in Angewandte Chemie International Edition (02-04-2012)“…The aerobic oxidation of a phenolic lignin model compound with a vanadium catalyst results in the oxidative cleavage of the C-C bond between the aryl ring and…”
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Synthesis of 2‘β-Deoxy-[8-13C;amino,9-15N2]adenosine: Unusual Annulation Conditions To Assemble the Purine Core
Published in Journal of organic chemistry (25-06-1999)“…Synthesis of 2‘β-Deoxy-[8-13C;amino,9-15N2]adenosine has been accomplished using a five-step process which employs a novel annulation of [13C]formamide…”
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Origins of the Regioselectivity in the Lutetium Triflate Catalyzed Ketalization of Acetone with Glycerol: A DFT Study
Published in ACS catalysis (06-02-2015)“…We describe DFT computations that address the regioselective preference toward the five-membered ring product 1,3-dioxolane (solketal) over the…”
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Synthesis of stable isotope–labeled chloroquine and amodiaquine and their metabolites
Published in Journal of labelled compounds & radiopharmaceuticals (15-05-2019)“…Anti‐malaria drugs chloroquine and amodiaquine and their metabolites were synthesized to incorporate 13C and 15N starting from U‐13C–labeled benzene to give…”
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