Search Results - "Sigwalt, Pierre"

Carbocationic polymerization: Mechanisms and kinetics of propagation reactions by Sigwalt, Pierre, Moreau, Michel

“…Propagation rate constants k p in carbocationic polymerizations can be obtained through two general methods. The first one, used for decades, calculated k p…”
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Reactivities of carbocations and monomers in carbocationic polymerization and copolymerization by Sigwalt, Pierre, Moreau, Michel

“…In carbocationic polymerization and copolymerization, a recent publication concluded that the substituent effect on carbocation reactivity is much larger than…”
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2020 recommendations from the French Society of Rheumatology for the management of gout: Urate-lowering therapy by Pascart, Tristan, Latourte, Augustin, Flipo, René-Marc, Chalès, Gérard, Coblentz-Baumann, Laurence, Cohen-Solal, Alain, Ea, Hang-Korng, Grichy, Jacques, Letavernier, Emmanuel, Lioté, Frédéric, Ottaviani, Sébastien, Sigwalt, Pierre, Vandecandelaere, Guy, Richette, Pascal, Bardin, Thomas

“…•These first French recommendations aim at improving urate-lowering therapy (ULT) prescription as ULT, although being the only treatment able make gout…”
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Can Propagation Reaction in Carbocationic Polymerization and Copolymerization of Styrene be Diffusion Controlled ? by Sigwalt, Pierre, Moreau, Michel

“…The reactivity ratios r1 and r2 in copolymerizations of styrene and parasubstituted styrenes, for which r1 = 1/r2, are in contradiction with diffusion control…”
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2020 Recommendations from the French Society of Rheumatology for the management of gout: Management of acute flares by Latourte, Augustin, Pascart, Tristan, Flipo, René-Marc, Chalès, Gérard, Coblentz-Baumann, Laurence, Cohen-Solal, Alain, Ea, Hang-Korng, Grichy, Jacques, Letavernier, Emmanuel, Lioté, Frédéric, Ottaviani, Sébastien, Sigwalt, Pierre, Vandecandelaere, Guy, Richette, Pascal, Bardin, Thomas

“…•Gout is one of the most common forms of inflammatory arthritis, which remains poorly treated in France and worldwide.•These first French recommendations aim…”
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New developments in cationic polymerization of cyclosiloxanes by SIGWALT, P

“…Some publications have shown the analogies or the differences in the behavior of cyclosiloxanes of various sizes (particularly D sub 3 and D sub 4 ) when they…”
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Recent results in proton-initiated and non proton-initiated cationic polymerizations by SIGWALT, P

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Recommandations 2020 de la Société française de rhumatologie pour la prise en charge de la goutte : traitement des crises de goutte by Latourte, Augustin, Pascart, Tristan, Flipo, René-Marc, Chalès, Gérard, Coblentz-Baumann, Laurence, Cohen-Solal, Alain, Ea, Hang-Korng, Grichy, Jacques, Letavernier, Emmanuel, Lioté, Frédéric, Ottaviani, Sébastien, Sigwalt, Pierre, Vandecandelaere, Guy, Richette, Pascal, Bardin, Thomas

“…•La goutte est un des rhumatismes inflammatoires les plus fréquents, mais reste mal soignée en France et dans le monde.•Ces premières recommandations visent à…”
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Recommandations de la Société française de rhumatologie pour la prise en charge de la goutte : le traitement hypo-uricémiant by Pascart, Tristan, Latourte, Augustin, Chalès, Gérard, Coblentz-Baumann, Laurence, Cohen-Solal, Alain, Ea, Hang-Korng, Flipo, René-Marc, Grichy, Jacques, Letavernier, Emmanuel, Lioté, Frédéric, Ottaviani, Sébastien, Sigwalt, Pierre, Vandecandelaere, Guy, Richette, Pascal, Bardin, Thomas

“…•Ces premières recommandations françaises visent à améliorer la prise en charge de la goutte en France car la mise en œuvre du traitement hypouricémiant reste…”
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Recent Evidence for the Association of Initiator with Counter Ion in Cationic Polymerization by Sigwalt, Pierre, Sauvet, Georges

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The effect of light on the cationic polymerisation of isobutene by TiCl4 some comments on two papers by Kennedy and Diem by Gandini, Alessandro, Cheradame, Herv, Sigwalt, Pierre

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About propagation rate constants in carbocationic polymerizations by Sigwalt, Pierre, Moreau, Michel, Polton, Alain

“…Published carbocationic propagation rate constants vary between 2 103 and 5 109 L·mol−1·s−1, e.g. for kp± with styrene in CH2Cl2. The low values were deduced…”
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Structural Studies of the Optically Active and Racemic Poly(propylene sulfides) by Sakakihara, Hideko, Takahashi, Yasuhiro, Tadokoro, Hiroyuki, Sigwalt, Pierre, Spassky, Nicolas

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Mechanism of hexamethylcyclotrisiloxane polymerization in the presence of siloxanediols by Bischoff, Rémy, Sigwalt, Pierre

“…Polymerization of hexamethylcyclotrisiloxane (D3 ) in CH2Cl2 at 30°C, initiated by triflic acid (TfOH) was studied in the presence of siloxanediols (HD2OH or…”
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Mechanism of octamethylcyclotetrasiloxane polymerization in the presence of siloxanediols by Bischoff, Rémy, Sigwalt, Pierre

“…Polycondensation of tetramethyldisiloxanediol (HD 2OH) by triflic acid (TfOH) in the presence of octamethylcyclotetrasiloxane (D4) has been studied at 30°C in…”
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Synthesis of cyclic and multicyclic polyisoprenes by Boutillier, Jean-Marc, Lepoittevin, Bénédicte, Favier †, Jean-Claude, Masure, Michèle, Hémery, Patrick, Sigwalt, Pierre

“…Cyclic polyisoprenes have been synthesized by reaction of α,ω-dilithiopolyisoprenes with dichlorodimethylsilane or 1,2-bis(isopropenyl-4-phenyl) ethane (BIPE)…”
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Stereoelection and Stereoselection in the Ring-Opening Polymerization of Epoxides and Episulfides by Sigwalt, Pierre

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Influence of ring size on monomer reactivities in cationic polymerization of cyclodimethylsiloxanes : Comparison of D5, D6 and D7 by MOREAU, M, MASURE, M, SIGWALT, P

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Influence of ring size on monomer reactivities in cationic polymerization of cyclodimethylsiloxanes: Comparison of D 5, D 6 and D 7 by Moreau, Michel, Masure, Michèle, Sigwalt, Pierre

“…Earlier data had shown that monomer reactivities and polymerization rates of cyclodimethylsiloxanes D x ([Si(CH 3) 2O] x) increased in the order D 4 < D 5 < D…”
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Various types of aggregates in mono- or bifunctional polyisoprenyllithium in hydrocarbons by Boutillier, Jean-Marc, Favier, Jean-Claude, Hémery, Patrick, Sigwalt, Pierre

“…The addition of tert-butyllithium on 1,2-bis(isopropenyl-4 phenyl)ethane in pure hexane leads to the quantitative synthesis of a dilithium compound as shown…”
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