Search Results - "Sieck, Carolin"
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Reductive Coupling of Diynes at Rhodium Gives Fluorescent Rhodacyclopentadienes or Phosphorescent Rhodium 2,2'-Biphenyl Complexes
Published in Chemistry : a European journal (18-07-2016)“…Reactions of [Rh(κ2‐O,O‐acac)(PMe3)2] (acac=acetylacetonato) and α,ω‐bis(arylbutadiynyl)alkanes afford two isomeric types of MC4 metallacycles with very…”
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Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters
Published in Chemistry : a European journal (25-07-2016)“…N‐heterocyclic carbenes (NHCs) and cyclic (alkyl)(amino)carbenes (CAACs) are of great interest, as their electronic and steric properties provide a unique…”
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3
Ultrafast photophysics of para -substituted 2,5-bis(arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing
Published in Chemical science (Cambridge) (15-08-2024)“…2,5-Bis(phenylethynyl) rhodacyclopentadienes (RCPDs), as a type of Rh(iii) complex, exhibit unusually intense fluorescence and slow intersystem crossing (ISC)…”
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Convenient synthetic access to fluorescent rhodacyclopentadienes via ligand exchange reactions
Published in Journal of organometallic chemistry (01-10-2017)“…We have previously reported the formation of fluorescent 2,5-bis(arylethynyl)rhodacyclopentadienes from the reaction of [Rh(κ2-O,O-acac)(PMe3)2]…”
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