Search Results - "Shoesmith, David"
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Characterization of film properties on the NiCrMo Alloy C-2000
Published in Electrochimica acta (01-02-2013)“…The passive and transpassive film properties grown at various potentials on a NiCrMo alloy, Alloy C-2000 (Ni23Cr16Mo1.6Cu), were investigated by…”
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2
Effect of duty cycle and applied current frequency on plasma electrolytic oxidation (PEO) coating growth behavior
Published in Surface & coatings technology (15-07-2013)“…Ceramic coatings were created on the surface of 6061 aluminum alloy using a plasma electrolytic oxidation (PEO) process employing a pulsed direct current (DC)…”
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3
Molybdenum surface enrichment and release during transpassive dissolution of Ni-based alloys
Published in Corrosion science (01-02-2019)“…[Display omitted] •Ni, Cr, Mo and Fe dissolution were monitored as a function of time in the passive and transpassive domain.•Mo surface enrichment, probably…”
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4
Influence of temperature on passive film properties on Ni–Cr–Mo Alloy C-2000
Published in Corrosion science (01-11-2013)“…•The passive films on Alloy C-2000 were investigated by AR-XPS and ToF-SIMS.•The film consists of an inner Cr2O3, outer Cr/Ni hydroxide and Mo/Cu…”
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5
Phase transformation in plasma electrolytic oxidation coatings on 6061 aluminum alloy
Published in Surface & coatings technology (25-07-2014)“…Oxide coatings were produced on a 6061 aluminum alloy using a pulsed unipolar plasma electrolytic oxidation (PEO) process. The effect of electrical parameters…”
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6
Hydrogen peroxide decomposition on simulated nuclear fuel bicarbonate/carbonate solutions
Published in Electrochimica acta (20-04-2020)“…The behavior of SIMFUEL (rare earth doped uranium dioxide containing noble metal particles) has been studied in bicarbonate/carbonate solutions (pH = 9.7)…”
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7
An electrochemical and radiolytic study of the effects of H2 on the corrosion of UO2-based materials
Published in Corrosion science (01-11-2021)“…The influence of γ-radiation in the presence of dissolved hydrogen on the corrosion of uranium dioxide has been compared to the electrochemical behavior of…”
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8
Correlation between plasma electrolytic oxidation treatment stages and coating microstructure on aluminum under unipolar pulsed DC mode
Published in Surface & coatings technology (01-05-2015)“…Alumina coatings were deposited on 6061 aluminum alloy substrates using plasma electrolytic oxidation (PEO) in an alkaline silicate electrolyte. Different…”
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Mechanisms of Film Growth on Copper in Aqueous Solutions Containing Sulphide and Chloride under Voltammetric Conditions
Published in Electrochimica acta (01-05-2014)“…•Three type of films were formed depending on water chemistry and SH− flux.•The film properties and its growth mechanism were determined.•The possibility of…”
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10
The influence of sulphide, bicarbonate and carbonate on the electrochemistry of carbon steel in slightly alkaline solutions
Published in Corrosion science (01-06-2020)“…•Sulphides (< 10−6 M) interfere with the passivity of FeIIIoxides in alkaline conditions.•Sulphides are able to chemically reduce FeIIIoxides.•Surface analysis…”
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11
An Electrochemical Study of H2O2 Oxidation and Decomposition on Simulated Nuclear Fuel (SIMFUEL)
Published in Electrochimica acta (10-08-2014)“…•We study anodic oxidation and open circuit decomposition of H2O2 on used nuclear fuel.•The effect of pH (9.5-12.5) on H2O2 redox behaviour on UO2 is…”
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12
The contribution of Cr and Mo to the passivation of Ni22Cr and Ni22Cr10Mo alloys in sulfuric acid
Published in Corrosion science (01-11-2020)“…•The role of Mo on passivation was investigated by AESEC coupled with XPS.•Mo enriched on the surface in the low potential domain and dissolved congruently in…”
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13
An improved model for the corrosion of used nuclear fuel inside a failed waste container under permanent disposal conditions
Published in Corrosion science (01-07-2014)“…[Display omitted] •The corrosion of spent nuclear fuel in a failed waste container is modelled.•Alpha-radiolysis process is simulated using a full reaction…”
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14
The cathodic behaviour of Al–Mn precipitates during atmospheric and saline aqueous corrosion of a sand-cast AM50 alloy
Published in Corrosion science (01-06-2014)“…•Site-specific analytical electron microscopy was performed on corroded AM50.•In air-exposed alloy, Al–Mn particles show enrichment in Al and O at the…”
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15
A comparison of the corrosion behaviour of copper materials in dilute nitric acid
Published in Corrosion science (01-11-2021)“…The corrosion of a number of coarse- and fine-grained copper materials has been studied in an aerated aqueous nitric acid (100 mM) solution. The materials…”
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16
Roles of Radiolytic and Externally Generated H 2 in the Corrosion of Fractured Spent Nuclear Fuel
Published in Environmental science & technology (15-11-2016)“…A 2-D model for the corrosion of spent nuclear fuel inside a failed nuclear waste container has been modified to determine the influence of various redox…”
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17
Investigating the transport mechanisms governing the oxidation of Hastelloy BC-1 by in situ ToF-SIMS
Published in Corrosion science (01-10-2019)“…•The air-formed oxide on Hastelloy BC-1 contained Cr- and Mo- rich regions in the inner and outer oxide, respectively.•Empirical evidence shows O atom…”
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18
Anodic reactions occurring on simulated spent nuclear fuel (SIMFUEL) in hydrogen peroxide solutions containing bicarbonate/carbonate – The effect of fission products
Published in Electrochimica acta (10-10-2019)“…The anodic behaviour of simulated spent nuclear fuel (SIMFUEL) was studied in NaCl solutions containing H2O2 and various concentration of HCO3−/CO32− using…”
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19
Roles of Radiolytic and Externally Generated H2 in the Corrosion of Fractured Spent Nuclear Fuel
Published in Environmental science & technology (15-11-2016)“…A 2-D model for the corrosion of spent nuclear fuel inside a failed nuclear waste container has been modified to determine the influence of various redox…”
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20
The role of aluminum distribution on the local corrosion resistance of the microstructure in a sand-cast AM50 alloy
Published in Corrosion science (01-12-2013)“…•Site-specific analytical electron microscopy was performed on corroded AM50.•Areas close to eutectic microstructure show less corrosion damage.•Eutectic Mg…”
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