Ultraviolet Light-Induced Surface Changes of Tungsten Oxide in Air: Combined Scanning Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy Analysis

Scanning transmission electron microscopy (STEM) and X-ray photoelectron spectroscopy analyses were combined to clarify the ultraviolet light-induced surface changes of WO in air. Identical-location STEM (IL-STEM) analysis showed that the WO particle surface was covered with an amorphous thin film a...

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Bibliographic Details
Published in:Nanomaterials (Basel, Switzerland) Vol. 14; no. 18; p. 1486
Main Authors: Nakagawa, Yuki, Shiratsuchi, Yasuhiro, Shibayama, Tamaki, Takeguchi, Masaki
Format: Journal Article
Language:English
Published: Switzerland MDPI AG 13-09-2024
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Summary:Scanning transmission electron microscopy (STEM) and X-ray photoelectron spectroscopy analyses were combined to clarify the ultraviolet light-induced surface changes of WO in air. Identical-location STEM (IL-STEM) analysis showed that the WO particle surface was covered with an amorphous thin film after ultraviolet irradiation in air. X-ray photoelectron spectroscopy analysis showed that hydrocarbon decomposition and the formation of carboxyl/hydroxyl species occurred. These results suggested that the amorphous thin films consisted of photocatalytic oxidative species of hydrocarbon. The IL-STEM analysis could detect small light-induced changes. This technique will be useful for the microscopic characterization of photocatalysis or photoinduced hydrophilic conversion.
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ISSN:2079-4991
2079-4991
DOI:10.3390/nano14181486