Search Results - "Shipman, Michael"
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Recent progress towards the electrosynthesis of ammonia from sustainable resources
Published in Catalysis today (15-05-2017)“…[Display omitted] •Recent progress towards electrosynthetic devices for the production of ammonia are reviewed.•The key remaining challenges in the field are…”
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Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Published in Nature reviews. Chemistry (11-01-2017)“…Sunlight is by far the most plentiful renewable energy resource, providing Earth with enough power to meet all of humanity's needs several hundred times over…”
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A re-evaluation of Sn(II) phthalocyanine as a catalyst for the electrosynthesis of ammonia
Published in Electrochimica acta (20-12-2017)“…The electrosynthesis of ammonia from nitrogen and water is a topic of considerable interest in the quest for sustainable and decentralized NH3 production…”
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Selective aldehyde reductions in neutral water catalysed by encapsulation in a supramolecular cage
Published in Chemical science (Cambridge) (15-04-2021)“…The enhancement of reactivity inside supramolecular coordination cages has many analogies to the mode of action of enzymes, and continues to inspire the design…”
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Generation and Ring Opening of Aziridines in Telescoped Continuous Flow Processes
Published in Organic letters (17-07-2015)“…A simple method for the preparation of a variety of N-sulfonyl aziridines (10 examples) from 1,2-amino alcohols under continuous flow conditions is described…”
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Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects
Published in Crystal growth & design (05-04-2017)“…The employment of three structurally related Schiff bases H2 L1, H2 L2, and H3 L3 with zinc and lanthanide salts under various reaction conditions, gave four…”
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Synthesis and structure of oxetane containing tripeptide motifs
Published in Chemical communications (Cambridge, England) (14-08-2014)“…A new class of peptidomimetic is reported in which one of the amide C=O bonds of the peptide backbone is replaced by an oxetane ring. They are synthesised by…”
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Halogenated Boron Subphthalocyanines as Light Harvesting Electron Acceptors in Organic Photovoltaics
Published in Advanced energy materials (01-05-2011)“…By tuning the frontier orbital energies through selective halogenation of the periphery of the organic framework, new light harvesting electron acceptors based…”
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Phyllostictine A: total synthesis, structural verification and determination of substructure responsible for plant growth inhibition
Published in Chemical communications (Cambridge, England) (2018)“…The first total synthesis of phyllostictine A (PA) is reported, which confirms the structure of this fungal metabolite and its (6S,7R,8S)-stereochemistry. Both…”
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Towards a better understanding of the electrosynthesis of 2,5-dicarboxy-2,5-dihydrofurans: structure, mechanism and influence over stereochemistry
Published in Royal Society open science (01-07-2019)“…2,5-Dicarboxy-2,5-dihydrofurans are key constituents of a number of natural products and have roles as intermediates in the formation of other such compounds…”
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Synthesis of Optically Active Arylaziridines by Regio- and Stereospecific Lithiation of N-Bus-Phenylaziridine
Published in Organic letters (15-01-2009)“…α,α-Disubstituted aziridines can be produced in good yields by selective lithiation of N-tert-butylsulfonyl-2-phenylaziridine (n-BuLi/TMEDA, Et2O) at the…”
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Tetrahydroxanthones by Sequential Pd-Catalyzed C−O and C−C Bond Construction and Use in the Identification of the “Antiausterity” Pharmacophore of the Kigamicins
Published in Organic letters (04-03-2011)“…Readily available C-acylated cycloalkanones undergo efficient Pd catalyzed ring closure/cross-coupling providing 7-substituted tetrahydroxanthones in a single…”
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Stereocontrolled synthesis of a d-amicetose functionalised tetrahydroxanthone related to kigamicin A
Published in Tetrahedron letters (27-11-2013)“…A glycosylated tetrahydroxanthone mimicking the ABC subunit of kigamicin A is synthesised in five steps by a sequence that exploits a Pd catalysed C–O bond…”
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Synthesis and Functionalization of 3-Alkylidene-1,2-diazetidines Using Transition Metal Catalysis
Published in Organic letters (01-04-2011)“…An efficient two-step synthesis of a wide range of 3-methylene-1,2-diazetidines has been developed through application of a Cu(I)-catalyzed 4-exo ring closure…”
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Control of Pyramidal Inversion Rates by Redox Switching
Published in Journal of the American Chemical Society (08-11-2006)“…The dynamics of pyramidal nitrogen inversion can be controlled by reversible redox switching in trans-2,3-diphenylaziridines bearing a suitable…”
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Solid-Phase, Multicomponent Reactions of Methyleneaziridines: Synthesis of 1,3-Disubstituted Propanones
Published in Organic letters (27-10-2005)“…Polymer-supported methyleneaziridines undergo ring opening by Grignard reagents under copper catalysis to yield metalloenamines which are alkylated in situ to…”
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Generation and electrophilic substitution reactions of 3-lithio-2-methyleneaziridines
Published in Tetrahedron (04-09-2006)“…2-Methyleneaziridinyl anions can be produced by selective deprotonation of the parent aziridine at C-3 using sec-BuLi/TMEDA. Subsequent reaction with a wide…”
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Multicomponent Reactions Involving 2-Methyleneaziridines: Rapid Synthesis of 1,3-Disubstituted Propanones
Published in Journal of organic chemistry (08-02-2002)“…Ring opening of 1-alkyl-2-methyleneaziridines 1 or 2 is accomplished with organocopper reagents (R2CuLi or RMgX/CuI) in the presence of boron trifluoride…”
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Asymmetric synthesis of 2-substituted piperidines using a multi-component coupling reaction: rapid assembly of (S)-coniine from (S)-1-(1-phenylethyl)-2-methyleneaziridine
Published in Chemical communications (Cambridge, England) (21-09-2001)“…(S)-Coniine is made using a reaction which assembles the piperidine ring by the sequential formation of four new chemical bonds and installs the C-2…”
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Synthesis of a trihydroxylated azepane from d-arabinose by way of an intramolecular alkene nitrone cycloaddition
Published in Tetrahedron: asymmetry (01-01-2005)“…[Display omitted] The synthesis of 1,6-imino-1,5,6-trideoxy- l- xylo-hexitol, a trihydroxylated azepane, from d-arabinose was achieved by way of an…”
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