Search Results - "Shinagawa, Tatsuya"
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Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion
Published in Scientific reports (08-09-2015)“…Microkinetic analyses of aqueous electrochemistry involving gaseous H 2 or O 2 , i.e., hydrogen evolution reaction (HER), hydrogen oxidation reaction (HOR),…”
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2
Towards Versatile and Sustainable Hydrogen Production through Electrocatalytic Water Splitting: Electrolyte Engineering
Published in ChemSusChem (10-04-2017)“…Recent advances in power generation from renewable resources necessitate conversion of electricity to chemicals and fuels in an efficient manner…”
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3
Microkinetic assessment of electrocatalytic oxygen evolution reaction over iridium oxide in unbuffered conditions
Published in Journal of catalysis (01-11-2020)“…[Display omitted] •Microkinetic analysis of oxygen evolution reaction (OER) over IrOx was performed.•Rate-determining steps at acidic or alkaline pH involve…”
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4
Water Electrolysis in Saturated Phosphate Buffer at Neutral pH
Published in ChemSusChem (20-11-2020)“…Hydrogen production from renewable energy and ubiquitous water has a potential to achieve sustainability, although current water electrolyzers cannot compete…”
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5
Delivering the Full Potential of Oxygen Evolving Electrocatalyst by Conditioning Electrolytes at Near‐Neutral pH
Published in ChemSusChem (22-03-2021)“…This study reports on the impact of identity and compositions of buffer ions on oxygen evolution reaction (OER) performance at a wide range of pH levels using…”
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6
Gas Crossover Regulation by Porosity‐Controlled Glass Sheet Achieves Pure Hydrogen Production by Buffered Water Electrolysis at Neutral pH
Published in ChemSusChem (08-02-2022)“…Near‐neutral pH water electrolysis driven by renewable electricity can reduce the costs of clean hydrogen generation, but its low efficiency and gas crossover…”
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7
Temperature Dependence of Electrocatalytic and Photocatalytic Oxygen Evolution Reaction Rates Using NiFe Oxide
Published in ACS catalysis (04-03-2016)“…The present work compares the oxygen evolution reaction (OER) in electrocatalysis and photocatalysis in aqueous solutions using nanostructured NiFeO x as…”
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Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate
Published in ACS catalysis (02-02-2018)“…The electrocatalytic CO2 reduction reaction (eCO2RR) has been gaining increasing attention owing to its potential to contribute to sustainability in our…”
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9
Boosting the Performance of the Nickel Anode in the Oxygen Evolution Reaction by Simple Electrochemical Activation
Published in Angewandte Chemie International Edition (24-04-2017)“…The development of cost‐effective and active water‐splitting electrocatalysts that work at mild pH is an essential step towards the realization of sustainable…”
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Low temperature catalytic reverse water gas shift reaction assisted by an electric field
Published in Catalysis today (01-09-2014)“…•Catalytic reverse water gas shift reaction in an electric field was investigated.•Pt/10mol%La-ZrO2 catalyst showed high catalytic activity in an electric…”
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Journal Article Conference Proceeding -
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Volcano Trend in Electrocatalytic CO2 Reduction Activity over Atomically Dispersed Metal Sites on Nitrogen-Doped Carbon
Published in ACS catalysis (01-11-2019)“…The development of catalysts for electrochemical reduction of carbon dioxide (eCO2RR) with high activity and selectivity remains a grand challenge to render…”
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12
Electrolyte Engineering towards Efficient Water Splitting at Mild pH
Published in ChemSusChem (09-11-2017)“…The development of processes for the conversion of H2O and CO2 driven by electricity generated by renewable means is essential to achieving sustainable energy…”
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13
Determination and perturbation of the electronic potentials of solid catalysts for innovative catalysis
Published in Chemical science (Cambridge) (08-12-2020)“…Concerns about energy and the environment are motivating a reexamination of catalytic processes, aiming to achieve more efficient and improved catalysis…”
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14
Microfabricated electrodes unravel the role of interfaces in multicomponent copper-based CO2 reduction catalysts
Published in Nature communications (16-04-2018)“…The emergence of synergistic effects in multicomponent catalysts can result in breakthrough advances in the electrochemical reduction of carbon dioxide…”
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15
High Current Density Oxygen Evolution in Carbonate Buffered Solution Achieved by Active Site Densification and Electrolyte Engineering
Published in ChemSusChem (09-01-2023)“…High current density reaching 1 A cm−2 for efficient oxygen evolution reaction (OER) was demonstrated by interactively optimizing electrolyte and electrode at…”
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Cover Feature: Water Electrolysis in Saturated Phosphate Buffer at Neutral pH (ChemSusChem 22/2020)
Published in ChemSusChem (20-11-2020)“…The Cover Feature shows large mass‐transport flux made possible by the highly concentrated buffer solution at elevated temperatures for water splitting. The…”
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Journal Article -
17
Origin of the Selective Electroreduction of Carbon Dioxide to Formate by Chalcogen Modified Copper
Published in The journal of physical chemistry letters (20-12-2018)“…The electrochemical reduction of atmospheric CO2 by renewable electricity opens new routes to synthesize fuels and chemicals, but more selective and efficient…”
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Author Correction: Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion
Published in Scientific reports (20-04-2020)“…A correction has been published and is appended to both the HTML and PDF versions of this paper. The error has not been fixed in the paper…”
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Journal Article -
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Low temperature hydrogen production by catalytic steam reforming of methane in an electric field
Published in International journal of hydrogen energy (07-03-2013)“…Catalytic steam reforming of methane in an electric field (electroreforming) at low temperatures such as 423 K was investigated. Pt catalysts supported on…”
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An Oxygen‐Insensitive Hydrogen Evolution Catalyst Coated by a Molybdenum‐Based Layer for Overall Water Splitting
Published in Angewandte Chemie International Edition (15-05-2017)“…For overall water‐splitting systems, it is essential to establish O2‐insensitive cathodes that allow cogeneration of H2 and O2. An acid‐tolerant…”
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