Actinide molecular ion formation in collision/reaction cell of triple quadrupole ICP-MS/MS and its application to quantitative actinide analysis

Actinide molecular ion formation in collision/reaction cell of triple quadrupole ICP-MS/MS and its application to quantitative actinide analysis

A study for the quantitative actinide analysis by using a triple quadrupole ICP-MS/MS, Agilent 8900, was carried out. We confirmed the formation percentages of ionic species of each actinide in several kinds of collision/reaction cell modes. It was found that the dominant ions in oxygen gas mode wer...

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Bibliographic Details
Published in:Journal of radioanalytical and nuclear chemistry Vol. 318; no. 1; pp. 221 - 225
Main Authors: Suzuki, T., Yamamura, T., Abe, C., Konashi, K., Shikamori, Y.
Format: Journal Article
Language:English
Published: Cham Springer International Publishing 01-10-2018
Springer
Springer Nature B.V
Subjects:
Actinides
Atomic properties
Chemistry
Chemistry and Materials Science
Diagnostic Radiology
Flow velocity
Gas flow
Hadrons
Heavy Ions
Inorganic Chemistry
Molecular ions
Nuclear Chemistry
Nuclear Physics
Oxygen
Physical Chemistry
Quadrupoles
Americium
Uranium
Plutonium
Curium
Oxygen reaction
Neptunium
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Summary:A study for the quantitative actinide analysis by using a triple quadrupole ICP-MS/MS, Agilent 8900, was carried out. We confirmed the formation percentages of ionic species of each actinide in several kinds of collision/reaction cell modes. It was found that the dominant ions in oxygen gas mode were oxide ions, and the ratio of monoxide ion/dioxide ion increases with atomic number in the case of same oxygen gas flow rate. The percentages of actinide ion and oxide ions depend on the oxygen gas flow rate, and the number of oxygen attached on actinides increases with the oxygen gas flow rate.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-018-6095-7