Search Results - "Shi, Liang"

Nickel/NHC‐Catalyzed Asymmetric C−H Alkylation of Fluoroarenes with Alkenes: Synthesis of Enantioenriched Fluorotetralins by Cai, Yuan, Ye, Xiaodong, Liu, Sheng, Shi, Shi‐Liang

“…Chiral polyfluoroarene derivatives are an important scaffold in chemistry. An unprecedented enantioselective C−H alkylation of polyfluoroarenes with alkenes is…”
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A Bulky Chiral N‑Heterocyclic Carbene Palladium Catalyst Enables Highly Enantioselective Suzuki–Miyaura Cross-Coupling Reactions for the Synthesis of Biaryl Atropisomers by Shen, Di, Xu, Youjun, Shi, Shi-Liang

“…Axially chiral biaryl scaffolds are essential structural units in chemistry. The asymmetric Pd-catalyzed Suzuki–Miyaura cross-coupling reaction has been widely…”
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Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines by Yang, Yang, Shi, Shi-Liang, Niu, Dawen, Liu, Peng, Buchwald, Stephen L.

“…Catalytic assembly of enantiopure aliphatic amines from abundant and readily available precursors has long been recognized as a paramount challenge in…”
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Fast Enantio‐ and Chemoselective Arylation of Ketones with Organoboronic Esters Enabled by Nickel/N‐Heterocyclic Carbene Catalysis by Cai, Yuan, Ruan, Lin‐Xin, Rahman, Abdul, Shi, Shi‐Liang

“…A general, efficient, highly enantio‐ and chemoselective N‐heterocyclic carbene (NHC)/Ni‐catalyzed addition of readily available and stable arylboronic esters…”
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Copper-catalysed selective hydroamination reactions of alkynes by Shi, Shi-Liang, Buchwald, Stephen L.

“…The development of selective reactions that utilize easily available and abundant precursors for the efficient synthesis of amines is a long-standing goal of…”
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Low‐Temperature Nickel‐Catalyzed C−N Cross‐Coupling via Kinetic Resolution Enabled by a Bulky and Flexible Chiral N‐Heterocyclic Carbene Ligand by Wang, Zi‐Chao, Xie, Pei‐Pei, Xu, Youjun, Hong, Xin, Shi, Shi‐Liang

“…The transition‐metal‐catalyzed C−N cross‐coupling has revolutionized the construction of amines. Despite the innovations of multiple generations of ligands to…”
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Copper‐Catalyzed Enantioselective Markovnikov Protoboration of α‐Olefins Enabled by a Buttressed N‐Heterocyclic Carbene Ligand by Cai, Yuan, Yang, Xin‐Tuo, Zhang, Shuo‐Qing, Li, Feng, Li, Yu‐Qing, Ruan, Lin‐Xin, Hong, Xin, Shi, Shi‐Liang

“…Reported is a highly enantioselective copper‐catalyzed Markovnikov protoboration of unactivated terminal alkenes. A variety of simple and abundant feedstock…”
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Van der Waals Heterostructures for High‐Performance Device Applications: Challenges and Opportunities by Liang, Shi‐Jun, Cheng, Bin, Cui, Xinyi, Miao, Feng

“…The discovery of two‐dimensional (2D) materials with unique electronic, superior optoelectronic, or intrinsic magnetic order has triggered worldwide interest…”
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Palladium-Catalyzed Intramolecular CH Difluoroalkylation: Synthesis of Substituted 3,3-Difluoro-2-oxindoles by Shi, Shi-Liang, Buchwald, Stephen L.

“…The synthesis of 3,3‐difluoro‐2‐oxindoles through a robust and efficient palladium‐catalyzed CH difluoroalkylation is described. This process generates a…”
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Nickel/NHC‐Catalyzed Enantioselective Cyclization of Pyridones and Pyrimidones with Tethered Alkenes by Shen, Di, Zhang, Wu‐Bin, Li, Zhiyang, Shi, Shi‐Liang, Xu, Youjun

“…Reported is a highly enantioselective Ni(0)‐catalyzed endo‐selective C−H annulation of 2‐ and 4‐pyridone, and 4‐pyrimidone with alkenes to provide…”
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Enantioconvergent Arylation of Racemic Secondary Alcohols to Chiral Tertiary Alcohols Enabled by Nickel/N-Heterocyclic Carbene Catalysis by Cai, Yuan, Shi, Shi-Liang

“…The direct upgrading reaction of simple and readily available achiral alcohols via C–H functionalization is an ideal strategy to prepare value-added chiral…”
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f(Q, T) gravity by Xu, Yixin, Li, Guangjie, Harko, Tiberiu, Liang, Shi-Dong

“…We propose an extension of the symmetric teleparallel gravity, in which the gravitational action L is given by an arbitrary function f of the non-metricity Q…”
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Divergent and Selective Light Alkene Cross‐Coupling by Wang, Zi‐Chao, Zhang, Jia‐Wen, Koh, Ming Joo, Shi, Shi‐Liang

“…Abstract Light olefins are abundantly manufactured in the petroleum industry and thus represent ideal starting materials for modern chemical synthesis…”
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Enantio- and Regioselective Ni-Catalyzed para-C–H Alkylation of Pyridines with Styrenes via Intermolecular Hydroarylation by Ma, Jun-Bao, Zhao, Xia, Zhang, Dongju, Shi, Shi-Liang

“…Direct asymmetric functionalization of the pyridyl C–H bond represents a longstanding challenge in organic chemistry. We herein describe the first…”
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Dynamic kinetic asymmetric arylation and alkenylation of ketones by Ruan, Lin-Xin, Sun, Bo, Liu, Jia-Ming, Shi, Shi-Liang

“…Despite the importance of enantioenriched alcohols in medicinal chemistry, total synthesis, and materials science, the efficient and selective construction of…”
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Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols by Shi, Shi-Liang, Wong, Zackary L., Buchwald, Stephen L.

“…Here, a method is described by which to generate all possible stereoisomers of certain amino alcohols—a protocol that should see use in drug discovery and…”
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Catalytic Asymmetric Total Synthesis of ent-Hyperforin by Shimizu, Yohei, Shi, Shi-Liang, Usuda, Hiroyuki, Kanai, Motomu, Shibasaki, Masakatsu

“…Key to success: The first catalytic asymmetric total synthesis of ent‐hyperforin (see picture) was accomplished by using a Diels–Alder reaction promoted by a…”
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Efficient quantum memory for single-photon polarization qubits by Wang, Yunfei, Li, Jianfeng, Zhang, Shanchao, Su, Keyu, Zhou, Yiru, Liao, Kaiyu, Du, Shengwang, Yan, Hui, Zhu, Shi-Liang

“…A quantum memory, for storing and retrieving flying photonic quantum states, is a key interface for realizing long-distance quantum communication and…”
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Nickel/N-Heterocyclic Carbene Complex-Catalyzed Enantioselective Redox-Neutral Coupling of Benzyl Alcohols and Alkynes to Allylic Alcohols by Cai, Yuan, Zhang, Jia-Wen, Li, Feng, Liu, Jia-Ming, Shi, Shi-Liang

“…The nickel-catalyzed enantioselective redox-neutral coupling of alcohols and alkynes to access chiral allylic alcohols is reported. The reaction proceeds via a…”
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Weyl type f(Q, T) gravity, and its cosmological implications by Xu, Yixin, Harko, Tiberiu, Shahidi, Shahab, Liang, Shi-Dong

“…We consider an f ( Q ,  T ) type gravity model in which the scalar non-metricity Q α μ ν of the space-time is expressed in its standard Weyl form, and it is…”
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