Search Results - "Shemyakina, Olesya A"
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Cs2CO3-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones
Published in Beilstein journal of organic chemistry (12-04-2022)“…The reaction of bromopropargylic alcohols with phenols in the presence of Cs 2 CO 3 /DMF affords α-phenoxy-α’-hydroxyketones (1:1 adducts) and…”
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Expedient Access to Functionalized Furan/3(2H)-furanone Ensembles via Microwave-Assisted Domino Reactions
Published in Synthetic communications (02-12-2015)“…A one-pot linkage between furan and 3(2H)-furanone rings has been effected via the microwave-assisted Et 3 N-catalyzed domino condensation of the furan and…”
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Synthesis of α‐Acyloxy‐α′‐hydroxy Ketones via Cyclic Carbonate Intermediates Generated from Tertiary Bromopropargylic Alcohols and Cs2CO3
Published in European journal of organic chemistry (14-11-2019)“…A facile approach towards α‐acyloxy‐α′‐hydroxy ketones by reaction of readily available tertiary bromopropargylic alcohols and carboxylic acids in system…”
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Organic Superbases in Annulation with Propargylic Alcohols: Straightforward Synthesis of the Functionalized Oxazolopyrrolohexahydropyrimidine and Oxazolohexahydropyrimidoazepine Scaffolds
Published in European journal of organic chemistry (01-11-2016)“…The popular organic superbases 1,5‐diazabicyclo[4.3.0]non‐5‐ene (DBN) and 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) underwent annulation with electron‐deficient…”
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A Domino Reaction of α,β-Acetylenic γ-Hydroxy Nitriles with Arenecarboxylic Acids: An Unexpected Facile Shortcut to 4-Cyano-3(2H)-furanones
Published in Organic letters (16-07-2010)“…An unexpected facile domino reaction of α,β-acetylenic γ-hydroxy nitriles with arenecarboxylic acids (Et3N, MeCN, 20−25 °C, 48 h) affords…”
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hemo- and regioselective modification of adenosine with tertiary cyanopropargylic alcohols
Published in Tetrahedron letters (24-10-2012)“…Adenosine reacts with tertiary cyanopropargylic alcohols under mild conditions (K2CO3, DMF, 20-25 degree C, 4-30 h) with 100% chemo- and regioselectivity by…”
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Tandem regio- and stereospecific cyclization of ethyl isonicotinate with cyanoacetylenic alcohols to provide novel polycondensed heterocyclic systems
Published in Tetrahedron letters (22-02-2012)“…Ethyl isonicotinate reacts with tertiary cyanoacetylenic alcohols under exceptionally mild conditions (room temperature, without catalyst or solvent) to afford…”
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Peculiarities of the tandem reaction between cyanoacetylenic alcohols and aminobenzoic acids: Synthesis of 5,5-dialkyl-2-(3-aminophenyl)-4-oxo-4,5-dihydrofuran-3-carbonitriles
Published in ARKIVOC (26-08-2012)Get full text
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Chemo-, regio- and stereospecific addition of adenine and 8-azaadenine to α,β-acetylenic γ-hydroxy nitriles: a short-cut to novel acyclic adenosine analogues
Published in Tetrahedron (27-02-2010)“…Adenine (9 H-purin-6-amine) adds readily to available α,β-acetylenic γ-hydroxy nitriles under mild conditions (molar ratio 1:1, K 2CO 3, DMF, rt, 10 min) to…”
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Chemo- and regioselective modification of D,L-phenylalanine with α-cyanoacetylenic alcohols in water
Published in ARKIVOC (01-06-2011)Get full text
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Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of 13C13C spin-spin coupling constants
Published in Magnetic resonance in chemistry (01-09-2007)“…Configurational assignment and conformational analysis of a series of iminodihydrofurans obtained from cyanoacetylenic alcohols were performed on the basis of…”
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Synthesis of α‐Acyloxy‐α′‐hydroxy Ketones via Cyclic Carbonate Intermediates Generated from Tertiary Bromopropargylic Alcohols and Cs 2 CO 3
Published in European journal of organic chemistry (14-11-2019)“…A facile approach towards α‐acyloxy‐α′‐hydroxy ketones by reaction of readily available tertiary bromopropargylic alcohols and carboxylic acids in system Cs 2…”
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Cs 2 CO 3 -Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones
Published in Beilstein journal of organic chemistry (12-04-2022)“…The reaction of bromopropargylic alcohols with phenols in the presence of Cs CO /DMF affords α-phenoxy-α'-hydroxyketones (1:1 adducts) and α,α-diphenoxyketones…”
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Cs2CO3-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones
Published in Beilstein journal of organic chemistry (01-01-2022)“…The reaction of bromopropargylic alcohols with phenols in the presence of CS2CO3/DMF affords a-phenoxy-a'-hydroxyketones (1:1 adducts) and a.a-diphenoxyketones…”
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Catalyst-free three-component synthesis of hydroxyalkyltriazolylmethylidene barbiturates
Published in Mendeleev communications (01-11-2019)“…[Display omitted] 5-[(5-Hydroxyalkyl-1H-1,2,3-triazol-4-yl)methylidene]barbiturates were eco-friendly synthesized in up to 89% yields by one-pot…”
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One-pot tandem synthesis of fluorescent 5-naphthyl-3(2H)-furanones
Published in Tetrahedron (06-05-2013)“…Fluorescent 3(2H)-furanones, 4-cyano-2,2-dialkyl-5-(1- or 2-)naphthyl-3(2H)-furanones, have been synthesized in 69–81% yield by a one-pot procedure, via the…”
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DBU as a scaffold for the synthesis of [1,3]oxazolo[2’,3’ : 2,3]pyrimido-[1,2-a]azepines: annulation with aromatic cyanopropargylic alcohols
Published in Mendeleev communications (01-03-2018)“…[Display omitted] Organic superbase DBU, 1,8-diazabicyclo[5.4.0]undec-7-ene, readily annulated with aromatic cyanopropargylic alcohols nder mild conditions…”
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Сhemo- and regioselective modification of adenosine with tertiary cyanopropargylic alcohols
Published in Tetrahedron letters (24-10-2012)“…Adenosine reacts with tertiary cyanopropargylic alcohols under mild conditions (K2CO3, DMF, 20–25°C, 4–30h) with 100% chemo- and regioselectivity by the way of…”
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Regio- and stereoselective modification of cytosine with cyanopropargylic alcohols
Published in Mendeleev communications (01-01-2017)“…[Display omitted] Cyanopropargylic alcohols (4-hydroxyalk-2-ynenitriles) add cytosine at the triple bond under mild conditions (3–5 mol% K2CO3, DMF, 20–25°C,…”
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