Search Results - "Shchegolikhina, Olga I."
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Synthesis and photophysical properties of a new BODIPY-based siloxane dye
Published in Tetrahedron letters (02-03-2016)“…[Display omitted] A fluorescent dye comprising four BODIPY derivatives conjugated to a cyclotetrasiloxane core was synthesized by consecutive hydrosilylation…”
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Organoboron Derivatives of Stereoregular Phenylcyclosilsesquioxanes
Published in Chemistry : a European journal (04-09-2020)“…This study presents the synthesis of organoboron derivatives of stereoregular 4‐, 6‐, and 12‐unit phenylcyclosilsesquioxanes. All compounds obtained were…”
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Cross-Linked Luminescent Polymers Based on β-Diketone-Modified Polysiloxanes and Organoeuropiumsiloxanes
Published in Polymers (23-06-2022)“…Nowadays, luminescent materials attract wide attention due to their valuable characteristics and broad area of potential application. Luminescent…”
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A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
Published in Polymers (18-12-2021)“…A versatile equilibrium method for synthesizing ladder-like polyphenylsilsesquioxanes (L-PPSQs) with various molecular weights (from 4 to 500 kDa) in liquid…”
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Star-Shaped Polydimethylsiloxanes with Organocyclotetrasilsesquioxane Branching-Out Centers: Synthesis and Properties
Published in Polymers (12-01-2022)“…New non-crystallizable low-dispersity star-shaped polydimethylsiloxanes (PDMS) containing stereoregular -tetra(organo)(dimethylsiloxy)cyclotetrasiloxanes…”
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Modulation of the photophysical properties of multi-BODIPY-siloxane conjugates by varying the number of fluorophores
Published in Dyes and pigments (01-07-2022)“…A series of multifluorophore compounds with two, four, six and eight BODIPY residues linked to a siloxane core via a flexible spacer was synthesized. An…”
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Tetrachromophoric Derivatives of Dibenzoylmethanatoboron Difluoride Based on Stereoregular Cyclotetrasiloxanes: Synthesis and Properties
Published in The journal of physical chemistry. B (06-07-2023)“…A series of new tetrachromophoric systems based on stereoregular tetracyclosiloxanes and dibenzoylmethanatoboron difluoride derivatives have been synthesized…”
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Polyhedral phenylnickelsodiumsiloxanolate transformation in the presence of aromatic nitrogen-containing ligands
Published in Inorganica Chimica Acta (01-03-2021)“…[Display omitted] •Two new polyhedral phenylmetallasiloxane complexes , (1) and (2) formed in the process of recrystallization of polyhedral…”
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Synthesis and Properties of Stereoregular Cyclic Polysilanols: cis-[PhSi(O)OH]4, cis-[PhSi(O)OH]6, and Tris-cis-tris-trans-[PhSi(O)OH]12
Published in Inorganic chemistry (16-12-2002)“…New stereoregular cyclic polysilanols of the general formula [PhSi(O)OH]n (n = 6 and 12) have been selectively obtained in high yields by the reaction of…”
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Alkali-Metal-Directed Hydrolytic Condensation of Trifunctional Phenylalkoxysilanes
Published in European journal of inorganic chemistry (01-03-2004)“…The alkali‐metal‐directed hydrolysis of phenyltrialkoxysilanes, PhSi(OR)3 (R = Me, Et, nBu), was performed under various reaction conditions. The alkali metal…”
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Sol−Gel Immobilization of Lactate Oxidase from Organic Solvent: Toward the Advanced Lactate Biosensor
Published in Analytical chemistry (Washington) (01-03-2010)“…We report on the novel protocol for enzyme immobilization into gel of siloxanes using water−organic mixtures with the high content of organic solvent as a…”
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New all-cis-tetra(p-tolyl)cyclotetrasiloxanetetraol and its functionalization
Published in Mendeleev communications (01-07-2018)“…[Display omitted] New all-cis-tetra(p-tolyl)cyclotetrasiloxanetetraol and its derivatives with Si(CH=CH2)Me and Si(H)Me2 groups have been prepared and…”
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Cyclotetrasiloxanetetrols with methyl groups at silicon: isomers all-cis- and cis-trans-cis-[MeSi(O)OH](4)
Published in Inorganic chemistry (18-01-2010)“…1,3,5,7-Tetramethyl-1,3,5,7-tetrahydroxycyclotetrasiloxane has been synthesized in good yield from tetrapotassium tetramethylcyclotetrasiloxanolate. Methods…”
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Molecule-Based Magnets: Ferro- and Antiferromagnetic Interactions in Copper(II)−Polyorganosiloxanolate Clusters
Published in Inorganic chemistry (17-07-1996)“…The magnetic behavior of the clusters [(PhSiO2)6Cu6(O2SiPh)6]·6EtOH (1), Na4[(PhSiO2)12Cu4]·8 n BuOH (2), and K4[(C2H3SiO2)12Cu4]·6 n BuOH (3) has been…”
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Cyclotetrasiloxanetetrols with Methyl Groups at Silicon: Isomers all-cis- and cis-trans-cis-[MeSi(O)OH]4
Published in Inorganic chemistry (18-01-2010)“…1,3,5,7-Tetramethyl-1,3,5,7-tetrahydroxycyclotetrasiloxane has been synthesized in good yield from tetrapotassium tetramethylcyclotetrasiloxanolate. Methods…”
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Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties
Published in Journal of polymer science. Part A, Polymer chemistry (01-06-2019)“…ABSTRACT Six new star‐shaped polydimethylsiloxane (PDMS) with various cyclic siloxane cores were synthesized by the “grafting onto” method. The polymers…”
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Copper/sodium-directed hydrolytic condensation of methyltriethoxysilane: Self-assembly of polyhedral Cu/Na-methylsiloxane. Synthesis and properties of new stereoregular macrocyclosiloxane
Published in Journal of organometallic chemistry (01-05-2008)“…A new crystalline copper/sodium-methylsiloxane {Na 4[(MeSi(O)O) 12Cu 4]} · L ( 1) was obtained in a good yield by a hydrolytic condensation of…”
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Tris-cis-tris-trans-dodeca[organo(dimethylorganosiloxy)]cyclododecasiloxanes {RSi(O)[OSiMe2R′]}12. Self-Ordering Features
Published in Inorganic chemistry (17-10-2011)“…The molecular order and thermotropic transitions of tris-cis-tris-trans-dodeca- [organo(dimethylorganosiloxy)]cyclododecasiloxanes {RSi(O)[OSiMe2R′]}12 (R =…”
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Towards Stepwise Cluster Assembly: A Decacopper(II) Complex Obtained by Controlled Expansion of a Metallasiloxane Cage
Published in Angewandte Chemie International Edition (02-12-2002)“…A decacopper(II) cluster. Clusters (shown in blue) can be expanded and their magnetic properties tuned by the addition of suitable metal‐complex ligands (shown…”
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20
New Cyclosiloxanolate Cluster Complexes of Transition Metals
Published in Journal of cluster science (01-03-2007)“…New cyclosiloxanolate transition metal cluster complex derivatives were prepared. PhSiO2K reacted with NiX2 (X2 = Cl2 or acac) to give…”
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