Search Results - "Shang, Yuan"
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Atomically Precise Preorganization of Open Metal Sites on Gold Nanoclusters with High Catalytic Performance
Published in Angewandte Chemie International Edition (01-03-2021)“…Gold nanoclusters with surface open sites are crucial for practical applications in catalysis. We have developed a surface geometric mismatch strategy by using…”
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2
Formation of an Alkynyl‐Protected Ag112 Silver Nanocluster as Promoted by Chloride Released In Situ from CH2Cl2
Published in Angewandte Chemie International Edition (23-03-2020)“…By directly reducing alkynyl–silver precursors, we successfully obtained a large alkynyl‐protected silver nanocluster, (C7H17ClN)3[Ag112Cl6(C≡CAr)51], which is…”
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3
Ligand Engineering toward the Trade‐Off between Stability and Activity in Cluster Catalysis
Published in Angewandte Chemie International Edition (07-03-2022)“…We report the structures, stability and catalysis properties of two Ag21 nanoclusters, namely [Ag21(H2BTCA)3(O2PPh2)6]SbF6 (1) and…”
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4
Ultrastable Anti‐Acid “Shield” in Layered Silver Coordination Polymers
Published in Angewandte Chemie International Edition (02-11-2022)“…Surface passivation technology provides noble‐metal materials with limited chemical stability, especially under highly acidic condition. To design effective…”
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5
Structure Determination of Alkynyl‐Protected Gold Nanocluster Au22(tBuC≡C)18 and Its Thermochromic Luminescence
Published in Angewandte Chemie International Edition (03-02-2020)“…An alkynyl‐protected gold nanocluster, Au22(tBuC≡C)18 (1), has been synthesized and its structure has been determined by single‐crystal X‐ray diffraction. The…”
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6
Robust Gold Nanocluster Protected with Amidinates for Electrocatalytic CO2 Reduction
Published in Angewandte Chemie International Edition (21-06-2021)“…The first all‐amidinate‐protected gold nanocluster [Au28(Ph−form)12](OTf)2 (Ph‐form=N,N′‐diphenylformamidinate) (Au28) has been synthesized and structurally…”
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7
Chiral Superatomic Nanoclusters Ag47 Induced by the Ligation of Amino Acids
Published in Angewandte Chemie International Edition (10-05-2021)“…Silver nanoclusters containing Ag0 atoms protected by amino acids were synthesized and characterized. Chiral superatomic silver nanoclusters…”
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8
A Chiral Gold Nanocluster Au20 Protected by Tetradentate Phosphine Ligands
Published in Angewandte Chemie International Edition (10-03-2014)“…The chirality of a gold nanocluster can be generated from either an intrinsically chiral inorganic core or an achiral inorganic core in a chiral environment…”
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9
A Near-Infrared-Emissive Alkynyl-Protected Au24 Nanocluster
Published in Angewandte Chemie International Edition (10-08-2015)“…An alkynyl‐protected gold nanocluster [Au24(CCPh)14(PPh3)4](SbF6)2 has been prepared by a direct reduction method. Single‐crystal X‐ray diffraction reveals…”
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10
Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties
Published in Nature communications (06-09-2019)“…Surface organic ligands are critical in determining the formation and properties of atomically precise metal nanoclusters. In contrast to the conventionally…”
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11
Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters
Published in Nature communications (19-04-2022)“…Copper hydrides are important hydrogenation catalysts, but their poor stability hinders the practical applications. Ligand engineering is an effective strategy…”
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12
Phase Transition in Postsynaptic Densities Underlies Formation of Synaptic Complexes and Synaptic Plasticity
Published in Cell (25-08-2016)“…Postsynaptic densities (PSDs) are membrane semi-enclosed, submicron protein-enriched cellular compartments beneath postsynaptic membranes, which constantly…”
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13
An All‐Alkynyl Protected 74‐Nuclei Silver(I)–Copper(I)‐Oxo Nanocluster: Oxo‐Induced Hierarchical Bimetal Aggregation and Anisotropic Surface Ligand Orientation
Published in Angewandte Chemie International Edition (26-08-2019)“…The hardness of oxo ions (O2−) means that coinage‐metal (Cu, Ag, Au) clusters supported by oxo ions (O2−) are rare. Herein, a novel μ4‐oxo supported…”
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14
Enriching Structural Diversity of Alkynyl‐Protected Gold Nanoclusters with Chlorides
Published in Angewandte Chemie International Edition (15-03-2021)“…The synthesis and isolation of alkynyl/chloride‐protected gold nanoclusters is described. Silica gel column chromatography is effective in isolating gold…”
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15
Au57Ag53(C≡CPh)40Br12: A Large Nanocluster with C1 Symmetry
Published in Angewandte Chemie International Edition (14-05-2018)“…The controlled synthesis and structure determination of a bimetallic nanocluster Au57Ag53(C≡CPh)40Br12 (Au57Ag53) is presented. The metal core has a four‐shell…”
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16
Experimental study of CO2 capture enhanced by coal fly ash-synthesized NH2-MCM-41 coupled with high gravity technology
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-11-2020)“…•Synthesis of NH2-MCM-41 from solid waste coal fly ash to prepare nanofluids.•Nanofluids coupled with high gravity technology intensify CO2 absorption…”
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17
Alkynyl-Protected Au23 Nanocluster: A 12-Electron System
Published in Angewandte Chemie International Edition (11-05-2015)“…A 23‐gold‐atom nanocluster was prepared by NaBH4‐mediated reduction of a solution of PhCCAu and Ph3PAuSbF6 in CH2Cl2. The cluster composition was determined…”
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18
Nitrogen Donor Protection for Atomically Precise Metal Nanoclusters
Published in Chemistry : a European journal (27-04-2022)“…Surface organic ligands are critical in dictating the structures and properties of atomically precise metal nanoclusters. In contrast to the conventionally…”
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19
Chiral Superatomic Nanoclusters Ag 47 Induced by the Ligation of Amino Acids
Published in Angewandte Chemie International Edition (10-05-2021)“…Silver nanoclusters containing Ag atoms protected by amino acids were synthesized and characterized. Chiral superatomic silver nanoclusters [Ag L (C≡C Bu) ]BF…”
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20
Yellow River's Contribution to the Building of Yangtze Delta During the Last 500 Years ‐ Evidence From Detrital Zircon U‐Pb Geochronology
Published in Geophysical research letters (28-07-2021)“…The Yangtze Delta (YD), as one of the world mega deltas, its formation process has long been the subject of research. Previous study has proposed a remote…”
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