Search Results - "Shan, Xiang‐Huan"
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1
Ultrathin Amorphous/Crystalline Heterophase Rh and Rh Alloy Nanosheets as Tandem Catalysts for Direct Indole Synthesis
Published in Advanced materials (Weinheim) (01-03-2021)“…Heterogeneous noble‐metal‐based catalysis plays an essential role in the production of fine chemicals. Rh‐based catalysts are one of the most active candidates…”
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2
Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay
Published in Nature communications (22-02-2019)“…Base-promoted C-H cleavage without transition metals opens a practical alternative for the one based on noble metals or radical initiators. The resulting…”
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3
Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde
Published in Organic letters (06-10-2017)“…A transition-metal- and catalyst-free hydrogenation of aryl halides, promoted by bases with either aldehydes or alcohols, is described. One equivalent of…”
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Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C–H and C–O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans
Published in Organic letters (01-06-2018)“…An intermolecular addition of carbon radicals enabled by a cascade radical coupling strategy is developed. It includes an intermolecular alkyl radical addition…”
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5
CuSO4‑Catalyzed Tandem C(sp3)–H Insertion Cyclization of Toluenes with Isonitriles to Form Indoles
Published in Organic letters (17-01-2020)“…A CuSO4-catalyzed tandem benzylic C–H insertion cyclization of toluene derivatives and isonitriles is described. The naturally abundant salt CuSO4 serves as a…”
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6
Synthesis of amorphous Pd-based nanocatalysts for efficient alcoholysis of styrene oxide and electrochemical hydrogen evolution
Published in Nano research (01-04-2023)“…Amorphous nanomaterials with long-range disordered structures could possess distinct properties and promising applications, especially in catalysis, as…”
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7
Competing Dehalogenation versus Borylation of Aryl Iodides and Bromides under Transition-Metal-Free Basic Conditions
Published in Journal of organic chemistry (06-09-2019)“…In this work, selectivity-controllable base-promoted transition-metal-free borylation and dehalogenation of aryl halides are described. Under the conditions of…”
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8
Iron-Catalyzed α,β-Dehydrogenation of Carbonyl Compounds
Published in Organic letters (05-03-2021)“…An iron-catalyzed α,β-dehydrogenation of carbonyl compounds was developed. A broad spectrum of carbonyls or analogues, such as aldehyde, ketone, lactone,…”
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9
CuSO 4 -Catalyzed Tandem C(sp 3 )-H Insertion Cyclization of Toluenes with Isonitriles to Form Indoles
Published in Organic letters (17-01-2020)“…A CuSO -catalyzed tandem benzylic C-H insertion cyclization of toluene derivatives and isonitriles is described. The naturally abundant salt CuSO serves as a…”
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10
t BuOK-Promoted Cyclization of Imines with Aryl Halides
Published in Organic letters (05-06-2020)“…A transition-metal-free indole synthesis using radical coupling of 2-halotoluenes and imines via the later-stage C-N bond construction was reported for the…”
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11
Phenanthroline‑ t BuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions
Published in Organic letters (21-12-2018)“…The first example of phenanthroline- t BuOK promoted intramolecular radical C–H arylation of N-(2-iodobenzyl)indoles without involvement of transition metals…”
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12
Synthesis of amorphous Pd-based nanocatalysts for efficient alcoholysis of styrene oxide and electrochemical hydrogen evolution
Published in Nano research (13-12-2022)“…Amorphous nanomaterials with long-range disordered structures could possess distinct properties and promising applications, especially in catalysis, as…”
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13
tBuOK-Promoted Cyclization of Imines with Aryl Halides
Published in Organic letters (05-06-2020)Get full text
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14
Phenanthroline- tBuOK Promoted Intramolecular C-H Arylation of Indoles with ArI under Transition-Metal-Free Conditions
Published in Organic letters (21-12-2018)“…The first example of phenanthroline- tBuOK promoted intramolecular radical C-H arylation of N-(2-iodobenzyl)indoles without involvement of transition metals…”
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