Equilibrium phase diagram of the water-sucrose-NaCl system

Equilibrium phase diagram of the water-sucrose-NaCl system

The solid-liquid equilibrium phase relationships in the ternary system water-NaCl-sucrose have been established with the aid of DSC measurements in the water-rich region and literature data. The phase coexistence conditions are represented in a plane projection of the three-dimensional phase diagram...

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Bibliographic Details
Published in:Thermochimica acta Vol. 255; pp. 49 - 61
Main Authors: Shalaev, E.Yu, Franks, F.
Format: Journal Article
Language:English
Published: Amsterdam Elsevier B.V 01-05-1995
Elsevier Science
Subjects:
Chemistry
DSC
Exact sciences and technology
General and physical chemistry
Hydrate
Liquid-solid equilibria
Phase diagram
Phase equilibria
SLE
Stoichiometry
Ternary system
Stoichiometry
Hydrate
Ternary system
DSC
Phase diagram
SLE
Differential scanning calorimetry
Chemical equilibrium
Sucrose
Liquid solid equilibrium
Aqueous solution
Experimental study
Sodium Chlorides
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Summary:The solid-liquid equilibrium phase relationships in the ternary system water-NaCl-sucrose have been established with the aid of DSC measurements in the water-rich region and literature data. The phase coexistence conditions are represented in a plane projection of the three-dimensional phase diagram. The existence of the following stoichiometric hydrates has been taken into account: NaCl·2H 2O, C 12H 22O 11·2.5H 2O, C 12H 22O 11·3.5H 2O and NaCl·C 12H 22O 11·2H 2O. The coordinates of the binary and ternary eutectic and peritectic points are established with varying degrees of confidence.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(94)02180-V