Search Results - "Sha, Fanrui"
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Metal–Organic Framework Nodes as a Supporting Platform for Tailoring the Activity of Metal Catalysts
Published in ACS catalysis (02-10-2020)“…Catalysis is a ubiquitous element of the modern economy, representing a cornerstone of many sectors including energy, materials, and pharmaceuticals. Within…”
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Recyclable Enzymatic Hydrolysis with Metal–Organic Framework Stabilized Humicola insolens Cutinase (HiC) for Potential PET Upcycling
Published in Chem & Bio Engineering (24-10-2024)Get full text
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3
Stabilization of an enzyme cytochrome c in a metal-organic framework against denaturing organic solvents
Published in iScience (25-06-2021)“…Enzymes are promising catalysts with high selectivity and activity under mild reaction conditions. However, their practical application has largely been…”
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Design, synthesis and applications of functional zirconium-based metal-organic frameworks
Published in Science China. Chemistry (01-12-2023)“…Zirconium-based metal-organic frameworks (Zr-MOFs) have been explored for applications including but not limited to water adsorption, gas storage and…”
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Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation
Published in Journal of the American Chemical Society (01-02-2023)“…Efficient separation of xenon (Xe) and krypton (Kr) mixtures through vacuum swing adsorption (VSA) is considered the most attractive route to reduce energy…”
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Insights into the Enhanced Catalytic Activity of Cytochrome c When Encapsulated in a Metal–Organic Framework
Published in Journal of the American Chemical Society (28-10-2020)“…The encapsulation of enzymes within porous materials has shown great promise, not only in protecting the enzymes from denaturation under nonbiological…”
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Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal–Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold
Published in Journal of the American Chemical Society (02-02-2022)“…Water vapor sorption by metal–organic frameworks (MOFs) has gathered significant interest because of its prominent potential in many applications such as…”
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Leveraging Isothermal Titration Calorimetry to Obtain Thermodynamic Insights into the Binding Behavior and Formation of Metal–Organic Frameworks
Published in Langmuir (07-06-2022)“…Isothermal titration calorimetry (ITC) is a technique which directly measures the thermodynamic parameters of binding events. Although historically it has been…”
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Effective Strategy toward Obtaining Reliable Breakthrough Curves of Solid Adsorbents
Published in ACS applied materials & interfaces (31-01-2024)“…Metal–organic frameworks (MOFs) have demonstrated their versatility in a wide range of applications, including chemical separation, gas capture, and storage…”
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Leveraging Ligand Desymmetrization to Enrich Structural Diversity of Zirconium Metal–Organic Frameworks for Toxic Chemical Adsorption
Published in Angewandte Chemie International Edition (11-11-2024)“…The discovery of metal–organic frameworks (MOFs) with novel structures provides significant opportunities for developing porous solids with new properties and…”
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Programmable Water Sorption through Linker Installation into a Zirconium Metal–Organic Framework
Published in Journal of the American Chemical Society (09-04-2024)“…Hydrolytically stable materials exhibiting a wide range of programmable water sorption behaviors are crucial for on-demand water sorption systems. While…”
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Leveraging Isothermal Titration Calorimetry to Explore Structure–Property Relationships of Protein Immobilization in Metal–Organic Frameworks
Published in Angewandte Chemie International Edition (12-09-2022)“…Proteins immobilized in metal–organic frameworks (MOFs) often show extraordinary stability. However, most efforts to immobilize proteins in MOFs have only been…”
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13
Constraining Flexibility in the MIL-88 Topology through Integration of 3‑Dimensional Linkers
Published in Crystal growth & design (01-05-2024)“…Metal–organic frameworks (MOFs) make up a class of crystalline, nanoporous materials that are recognized for their tunability. While some MOFs demonstrate…”
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14
Rationally Tailored Mesoporous Hosts for Optimal Protein Encapsulation
Published in Journal of the American Chemical Society (02-08-2023)“…Proteins play important roles in the therapeutic, medical diagnostic, and chemical catalysis industries. However, their potential is often limited by their…”
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Robust Carborane-Based Metal–Organic Frameworks for Hexane Separation
Published in Journal of the American Chemical Society (01-11-2023)“…Hexane isomers play a vital role as feedstocks and fuel additives in the petrochemical industry. However, their similar physical and chemical properties lead…”
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Biomimetic Mineralization of Large Enzymes Utilizing a Stable Zirconium-Based Metal-Organic Frameworks
Published in Journal of the American Chemical Society (28-02-2024)“…Enzymes are natural catalysts for a wide range of metabolic chemical transformations, including selective hydrolysis, oxidation, and phosphorylation. Herein,…”
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Role of Metal–Organic Framework Topology on Thermodynamics of Polyoxometalate Encapsulation
Published in ACS applied materials & interfaces (12-06-2024)“…Polyoxometalates (POMs) are discrete anionic clusters whose rich redox properties, strong Bro̷nsted acidity, and high availability of active sites make them…”
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Cationic Metal–Organic Framework with Amino-Functionalized Isonicotinic Acid for Chromium(VI) Removal
Published in Crystal growth & design (09-05-2024)“…The removal of hexavalent chromium, Cr(VI), from wastewater remains a significant environmental challenge. In this study, we explored the effectiveness of a…”
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Thermodynamic Insights into Phosphonate Binding in Metal–Azolate Frameworks
Published in Journal of the American Chemical Society (28-02-2024)“…Organophosphorus chemicals, including chemical warfare agents (CWAs) and insecticides, are acutely toxic materials that warrant capture and degradation…”
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A Catalytically Accessible Polyoxometalate in a Porous Fiber for Degradation of a Mustard Gas Simulant
Published in ACS applied materials & interfaces (13-04-2022)“…Polyoxometalates (POMs) are versatile materials for chemical catalysis due to their tunable acidity and rich redox properties. While POMs have attracted…”
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