Search Results - "Setser, D. W"

Infrared Chemiluminescence Study of the Reaction of Hydroxyl Radical with Formamide and the Secondary Unimolecular Reaction of Chemically Activated Carbamic Acid by Butkovskaya, N. I, Setser, D. W

“…Reactions of OH and OD radicals with NH2CHO and ND2CHO were studied by Fourier transform infrared emission spectroscopy of the product molecules from a…”
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Branching Ratios and Vibrational Distributions in Water-Forming Reactions of OH and OD Radicals with Methylamines by Butkovskaya, N. I, Setser, D. W

“…Reactions of OH and OD radicals with (CH3)3N, (CH3)2NH, and CH3NH2 were studied by Fourier transform infrared emission spectroscopy (FTIR) of the water product…”
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The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2‑H Atom Transfer, 1,1-HF and 1,2-HF Elimination Reactions, and the Dependence of Threshold Energies on the Number of F‑Atom Substituents in the Fluoroethane Molecules by Smith, Caleb A, Gillespie, Blanton R, Heard, George L, Setser, D. W, Holmes, Bert E

“…The recombination of CF3 and CHF2 radicals in a room-temperature bath gas was used to prepare vibrationally excited CF3CHF2* molecules with 101 kcal mol–1 of…”
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Reinvestigation of the Unimolecular Reactions of CHF2CHF2: Identification of the 1,1-HF Elimination Component from Addition of :CFCHF2 to trans-2-Butene by Smith, Caleb A, Heard, George L, Setser, D. W, Holmes, Bert E

“…The recombination of ·CHF2 radicals in a room-temperature bath gas was used to generate CHF2CHF2* (where * indicates vibrational excitation) molecules with 96…”
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Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination by Brown, Timothy M, Gillespie, Blanton R, Smith, Caleb A, Nestler, Matthew J, Heard, George L, Setser, D. W, Holmes, Bert E

“…The five unimolecular HX and DX (X = F, Cl) elimination pathways of CD2ClCHFCl* were examined using a chemical activation technique; the molecules were…”
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Chemical Activation Study of the Unimolecular Reactions of CD3CD2CHCl2 and CHCl2CHCl2 with Analysis of the 1,1-HCl Elimination Pathway by Larkin, Allie C, Nestler, Matthew J, Smith, Caleb A, Heard, George L, Setser, D. W, Holmes, Bert E

“…Chemically activated C2D5CHCl2 molecules were generated with 88 kcal mol–1 of vibrational energy by the recombination of C2D5 and CHCl2 radicals in a room…”
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Characterization of the 1,1-HCl Elimination Reaction of Vibrationally Excited CD3CHFCl Molecules and Assignment of Threshold Energies for 1,1-HCl and 1,2-DCl plus 1,1-HF and 1,2-DF Elimination Reactions by Brown, Timothy M, Nestler, Matthew J, Rossabi, Samuel M, Heard, George L, Setser, D. W, Holmes, Bert E

“…Vibrationally excited CD3CHFCl molecules with 96 kcal mol–1 of energy were generated by the recombination of CD3 and CHFCl radicals in a room-temperature bath…”
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Characterization of the 1,1-HF Elimination Reaction from the Competition between the 1,1-HF and 1,2-DF Unimolecular Elimination Reactions of CD3CD2CHF2 by Wormack, Leah N, McGreal, Meghan E, McClintock, Corey E, Heard, George L, Setser, D. W, Holmes, Bert E

“…The recombination of CHF2 and C2D5 radicals was used to produce CD3CD2CHF2* molecules with 96 kcal mol–1 of vibrational energy in a room temperature bath gas…”
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Unimolecular Reactions of 1,1,1-Trichloroethane, 1,1,1-Trichloropropane, and 3,3,3-Trifluoro-1,1,1-trichloropropane: Determination of Threshold Energies by Chemical Activation by Turpin, Martha A, Smith, Kylie C, Heard, George L, Setser, D. W, Holmes, Bert E

“…The recombination of CCl3 radicals with CH3, CH3CH2, and CF3CH2 radicals was used to generate CH3CCl3, CH3CH2CCl3, and CF3CH2CCl3 molecules with approximately…”
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Unimolecular Reactions in the CF3CH2Cl ↔ CF2ClCH2F System: Isomerization by Interchange of Cl and F Atoms by Enstice, Erin C, Duncan, Juliana R, Setser, D. W, Holmes, Bert E

“…The recombination of CF2Cl and CH2F radicals was used to prepare CF2ClCH2F* molecules with 93 ± 2 kcal mol−1 of vibrational energy in a room temperature bath…”
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Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement by Tucker, Mary K, Rossabi, Samuel M, McClintock, Corey E, Heard, George L, Setser, D. W, Holmes, Bert E

“…The room-temperature gas-phase recombination of CH2F and CD2Cl radicals was used to prepare CH2FCD2Cl molecules with 91 kcal mol–1 of vibrational energy. Three…”
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Unimolecular HCl and HF Elimination Reactions of 1,2-Dichloroethane, 1,2-Difluoroethane, and 1,2-Chlorofluoroethane: Assignment of Threshold Energies by Duncan, Juliana R, Solaka, Sarah A, Setser, D. W, Holmes, Bert E

“…The recombination of CH2Cl and CH2F radicals generates vibrationally excited CH2ClCH2Cl, CH2FCH2F, and CH2ClCH2F molecules with about 90 kcal mol−1 of energy…”
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Isomerization of Neopentyl Chloride and Neopentyl Bromide by a 1,2-Interchange of a Halogen Atom and a Methyl Group by Lisowski, Carmen E, Duncan, Juliana R, Ranieri, Anthony J, Heard, George L, Setser, D. W, Holmes, Bert E

“…The recombination of chloromethyl and t-butyl radicals at room temperature was used to generate neopentyl chloride molecules with 89 kcal mol−1 of internal…”
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Unimolecular Elimination of HF and HCl from Chemically Activated CF3CFClCH2Cl by Zaluzhna, Oksana, Simmons, Jay G, Heard, George L, Setser, D. W, Holmes, Bert E

“…The unimolecular reactions of CF3CFClCH2Cl molecules formed with 87 kcal mol−1 of vibrational energy by recombination of CF3CFCl and CH2Cl radicals at room…”
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Unimolecular Reactions Including ClF Interchange of Vibrationally Excited CF2ClCHFCH2CH3 and CF2ClCHFCD2CD3 by Beaver, Melinda R, Simmons, J. G, Heard, George L, Setser, D. W, Holmes, Bert E

“…Vibrationally excited CF2ClCHFC2H5(CF2ClCHFC2D5) molecules were prepared in the gas phase at 300 K with ≈93 kcal mol-1 of energy by recombination of CF2ClCHF…”
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Unimolecular Reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl: Observation of ClF Interchange by Zaluzhna, Oksana, Simmons, Jay G, Setser, D. W, Holmes, Bert E

“…The unimolecular reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl molecules formed with 87 and 91 kcal mol−1, respectively, of vibrational energy from the…”
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Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl:  Threshold Energies for HF and HCl Elimination by Ferguson, J. D, Johnson, N. L, Kekenes-Huskey, P. M, Everett, W. C, Heard, G. L, Setser, D. W, Holmes, B. E

“…Vibrationally activated CF3CH2CH2Cl molecules were prepared with 94 kcal mol-1 of vibrational energy by the combination of CF3CH2 and CH2Cl radicals and with…”
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Rate constants and vibrational distributions for water‐forming reactions of OH and OD radicals with thioacetic acid, 1,2‐ethanedithiol and tert‐butanethiol by Butkovskaya, N. I., Setser, D. W.

“…Reactions of OH and OD radicals with CH3C(O)SH, HSCH2CH2SH, and (CH3)3CSH were studied at 298 K in a fast‐flow reactor by infrared emission spectroscopy of the…”
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Unimolecular Reactions of Vibrationally Excited CF2ClCHFCH3 and CF2ClCHFCD3:  Evidence for the 1,2-FCl Interchange Pathway by Burgin, M. O, Simmons, J. G, Heard, G. L, Setser, D. W, Holmes, B. E

“…Chemically activated CF2ClCHFCH3 and CF2ClCHFCD3 molecules were prepared with 94 kcal mol-1 of vibrational energy by the recombination of CF2ClCHF and CH3(CD3)…”
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Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of C2D5CHFCl: Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl2 Reactions by Gillespie, Blanton R, Patel, Chaitanya A, Rothrock, Mallory M, Heard, George L, Setser, D. W, Holmes, Bert E

“…The gas-phase unimolecular reactions of C2D5CHFCl molecules with 94 kcal mol–1 of vibrational energy have been studied by the chemical-activation experimental…”
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