Determining the global activation energy of methane–air premixed flames

In this work, the determination of the apparent activation energy of a global chemical reaction mechanism of the methane–air flames is revisited. The one-step formulation allows to derive the theoretical background for the method to measure the activation energy within the burner stabilised flame se...

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Bibliographic Details
Published in:	Combustion theory and modelling Vol. 27; no. 7; pp. 909 - 924
Main Authors:	Moroshkina, Anastasia D., Ponomareva, Alina A., Mislavskii, Vladimir V., Sereshchenko, Evgeniy V., Gubernov, Vladimir V., Bykov, Viatcheslav V., Minaev, Sergey S.
Format:	Journal Article
Language:	English
Published:	Abingdon Taylor & Francis Ltd 10-11-2023
Subjects:	Activation energy Chemical reactions Critical phenomena Energy Mathematical models Methane Numerical prediction Premixed flames Pyrometry Reaction mechanisms Temperature distribution Thermal instability
Online Access:	Get full text
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Summary:	In this work, the determination of the apparent activation energy of a global chemical reaction mechanism of the methane–air flames is revisited. The one-step formulation allows to derive the theoretical background for the method to measure the activation energy within the burner stabilised flame setup. The validity of this approach is demonstrated by using the numerical simulations with the detailed reaction model and direct thin filament pyrometry measurements of the temperature distribution in flame. The combination of numerical and experimental approaches allows us to find the activation energy for various mixture compositions. The prediction of numerical simulations and measured values of the activation energy is found to be in good agreement with each other and the data known from the literature. It is demonstrated that two critical phenomena need to be taken into account to obtain a reliable estimate of the activation energy: the flame blow-off and the onset of the diffusive-thermal instabilities. The effect of these critical events on the accuracy of the measurements is discussed as well as prospects of further investigation.
ISSN:	1364-7830 1741-3559
DOI:	10.1080/13647830.2023.2245380