Search Results - "Sercel, Zachary P"

Surprising Route to a Monoazaporphyrin and Full Characterization of Its Complexes with Five Different 3d Metals by Raslin, Arik, Sercel, Zachary P., Fridman, Natalia, Saltsman, Irena, Gross, Zeev

“…In the search for mild agents for the oxidative cyclization of tetrapyrromethane to the corresponding corrole, we discovered a route that leads to a…”
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Synthesis of Enantioenriched gem-Disubstituted 4‑Imidazolidinones by Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation by Sercel, Zachary P, Sun, Alexander W, Stoltz, Brian M

“…A variety of enantioenriched gem-disubstituted 4-imidazolidinones were prepared in up to >99% yield and 95% ee by the Pd-catalyzed decarboxylative asymmetric…”
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Total Synthesis of Aleutianamine by Yu, Hao, Sercel, Zachary P, Rezgui, Samir P, Farhi, Jonathan, Virgil, Scott C, Stoltz, Brian M

“…Aleutianamine is a recently isolated pyrroloiminoquinone natural product that displays potent and selective biological activity toward human pancreatic cancer…”
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Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers by Moghadam, Farbod A., Hicks, Elliot F., Sercel, Zachary P., Cusumano, Alexander Q., Bartberger, Michael D., Stoltz, Brian M.

“…An enantioselective iridium-catalyzed allylic alkylation of malonates with trisubstituted allylic electrophiles to form all-carbon quaternary stereocenters is…”
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Divergent total syntheses of pyrroloiminoquinone alkaloids enabled by the development of a Larock/Buchwald-Hartwig annulation/cyclization by Rezgui, Samir P, Farhi, Jonathan, Yu, Hao, Sercel, Zachary P, Virgil, Scott C, Stoltz, Brian M

“…Pyrroloiminoquinone alkaloids are a large class of natural products that display a wide range of biological activities. Synthetic approaches to these natural…”
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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones by Sercel, Zachary P, Sun, Alexander W, Stoltz, Brian M

“…We report the palladium-catalyzed asymmetric allylic alkylation of 1,4-diazepan-5-ones. This reaction proceeds smoothly to give gem-disubstituted diazepanone…”
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Part-per-Trillion Trace Selective Gas Detection Using Frequency Locked Whispering-Gallery Mode Microtoroids by Li, Cheng, Lohrey, Trevor, Nguyen, Phuong-Diem, Min, Zhouyang, Tang, Yisha, Ge, Chang, Sercel, Zachary P., McLeod, Euan, Stoltz, Brian M., Su, Judith

“…Rapid detection of toxic and hazardous gases at trace concentrations plays a vital role in industrial, battlefield, and laboratory scenarios. Of interest are…”
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Some unusual transformations of a highly reactive α-bromocaranone by Samkian, Adrian E., Sercel, Zachary P., Virgil, Scott C., Stoltz, Brian M.

“…[Display omitted] The facile synthesis of a highly reactive α-bromocaranone from (+)-carene is reported. This intermediate was found to generate diverse chiral…”
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