Search Results - "Seidler, Gerald T"
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Interface Engineering V2O5 Nanofibers for High‐Energy and Durable Supercapacitors
Published in Small (Weinheim an der Bergstrasse, Germany) (01-08-2019)“…A local electric field is induced to engineer the interface of vanadium pentoxide nanofibers (V2O5‐NF) to manipulate the charge transport behavior and obtain…”
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Conjugated Metal–Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity
Published in Journal of the American Chemical Society (16-03-2022)“…The dimensional reduction of solids into smaller fragments provides a route to achieve new physical properties and gain deeper insight into the extended parent…”
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Rapid evolution of the Photosystem II electronic structure during water splitting
Published in Physical review. X (01-10-2018)“…Photosynthetic water oxidation is a fundamental process that sustains the biosphere. A Mn Ca cluster embedded in the photosystem II protein environment is…”
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X‑ray Emission Spectroscopy of Mn Coordination Complexes Toward Interpreting the Electronic Structure of the Oxygen-Evolving Complex of Photosystem II
Published in Journal of physical chemistry. C (18-02-2016)“…X-ray emission (XES) spectroscopy is an attractive technique for analysis of the electronic structure of molecules, materials, and metalloproteins. However, a…”
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X‑ray Emission Spectroscopy of Biomimetic Mn Coordination Complexes
Published in The journal of physical chemistry letters (15-06-2017)“…Understanding the function of Mn ions in biological and chemical redox catalysis requires precise knowledge of their electronic structure. X-ray emission…”
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Direct Observation of 4f Intrashell Excitation in Luminescent Eu Complexes by Time-Resolved X‑ray Absorption Near Edge Spectroscopy
Published in Journal of the American Chemical Society (19-03-2014)“…We report time-resolved X-ray absorption near edge structure (TR-XANES) measurements at the Eu L 3 edge upon photoexcitation of several EuIII-based luminescent…”
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Competing Effects of Fluorination on the Orientation of Aromatic and Aliphatic Phosphonic Acid Monolayers on Indium Tin Oxide
Published in Journal of physical chemistry. C (25-07-2013)“…Transparent conductive oxides such as indium tin oxide (ITO) are common substrates for optoelectronic devices, including organic light-emitting diodes and…”
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Fast Detection Allowing Analysis of Metalloprotein Electronic Structure by X-ray Emission Spectroscopy at Room Temperature
Published in The journal of physical chemistry letters (19-07-2012)“…The paradigm of “detection-before-destruction” was tested for a metalloprotein complex exposed at room temperature to the high X-ray flux typical of…”
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Fast and reversible zinc ion intercalation in Al-ion modified hydrated vanadate
Published in Nano energy (01-04-2020)“…Aqueous Zn-ion batteries (ZIBs) are emerging candidates for safe and eco-friendly large-scale energy storage, but the critical challenge is to develop stable…”
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Probing Sulfur Chemical and Electronic Structure with Experimental Observation and Quantitative Theoretical Prediction of Kα and Valence-to-Core Kβ X‑ray Emission Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-07-2020)“…An extensive experimental and theoretical study of the Kα and Kβ high-resolution X-ray emission spectroscopy (XES) of sulfur-bearing systems is presented. This…”
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Informed Chemical Classification of Organophosphorus Compounds via Unsupervised Machine Learning of X‑ray Absorption Spectroscopy and X‑ray Emission Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (28-07-2022)“…We analyze an ensemble of organophosphorus compounds to form an unbiased characterization of the information encoded in their X-ray absorption near-edge…”
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New Insights into the High‐Performance Black Phosphorus Anode for Lithium‐Ion Batteries
Published in Advanced materials (Weinheim) (01-09-2021)“…Black phosphorus (BP) is a promising anode material in lithium‐ion batteries (LIBs) owing to its high electrical conductivity and capacity. However, the huge…”
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Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X‑ray Emission Spectroscopy
Published in Chemistry of materials (25-09-2018)“…Synthetic efforts to prepare indium phosphide (InP) quantum dots (QDs) have historically generated emissive materials with lower than unity quantum yields…”
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Sulfur Speciation in Biochars by Very High Resolution Benchtop Kα X‑ray Emission Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-06-2018)“…The analytical chemistry of sulfur-containing materials poses substantial technical challenges, especially due to the limitations of 33S NMR and the…”
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Aminophosphines as Versatile Precursors for the Synthesis of Metal Phosphide Nanocrystals
Published in Chemistry of materials (14-08-2018)“…We have broadened the scope of the aminophosphine precursor chemistry that has been developed for InP quantum dots to the synthesis of cadmium, zinc, cobalt,…”
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Determination of Hexavalent Chromium Fractions in Plastics Using Laboratory-Based, High-Resolution X‑ray Emission Spectroscopy
Published in Analytical chemistry (Washington) (05-06-2018)“…Cr(VI) is a well-known human carcinogen with many water-soluble moieties. Its presence in both natural and man-made substances poses a risk to public health,…”
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Energy-Degeneracy-Driven Covalency in Actinide Bonding
Published in Journal of the American Chemical Society (26-12-2018)“…Evaluating the nature of chemical bonding for actinide elements represents one of the most important and long-standing problems in actinide science. We…”
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Surface Functionalization of Black Phosphorus with Nitrenes: Identification of P=N Bonds by Using Isotopic Labeling
Published in Angewandte Chemie International Edition (12-04-2021)“…Surface functionalization of two‐dimensional crystals is a key path to tuning their intrinsic physical and chemical properties. However, synthetic protocols…”
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X-ray absorption spectroscopy of trivalent Eu, Gd, Tb, and Dy chlorides and oxychlorides
Published in Journal of alloys and compounds (15-03-2022)“…•Novel measurements of L3-edge XANES lanthanides using a laboratory scale spectrometer.•State-of-the-art DFT calculations of ground state structures, lattice…”
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Enhanced Lithium-Ion Intercalation Properties of V2O5 Xerogel Electrodes with Surface Defects
Published in Journal of physical chemistry. C (24-03-2011)“…V2O5 xerogel films were fabricated by casting V2O5 sols onto fluorine-doped tin oxide (FTO) glass substrates and annealing at 300 °C for 3 h in different…”
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