Search Results - "Segalman, Rachel"
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Tuning the Double Gyroid Phase Window in Block Copolymers via Polymer Chain Conformation Near the Interface
Published in Macromolecules (22-06-2021)“…Block copolymer network morphologies have been proven interesting for applications ranging from mechanical to transport and optical properties. The shape of…”
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Thermal Conductivity of High-Modulus Polymer Fibers
Published in Macromolecules (25-06-2013)“…Polymers have many desirable properties for engineering systems–e.g., low mass density, chemical stability, and high strength-to-mass ratio–but applications of…”
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3
Organic thermoelectric materials for energy harvesting and temperature control
Published in Nature reviews. Materials (02-08-2016)“…Conjugated polymers and related processing techniques have been developed for organic electronic devices ranging from lightweight photovoltaics to flexible…”
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4
Patterning with block copolymer thin films
Published in Materials science & engineering. R, Reports : a review journal (28-02-2005)“…The nanometer-scale architectures in thin films of self-assembling block copolymers have inspired a variety of new applications. For example, the uniformly…”
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5
Thermal Conductivity and Elastic Constants of PEDOT:PSS with High Electrical Conductivity
Published in Macromolecules (10-02-2015)“…Mixtures of poly(3,4-ethylenedioxythiophene) and polystyrenesulfonate (PEDOT:PSS) have high electrical conductivity when cast from aqueous suspensions in…”
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6
Block Copolymers for Organic Optoelectronics
Published in Macromolecules (08-12-2009)“…While polymers hold significant potential as low cost, mechanically flexible, lightweight large area photovoltaics and light emitting devices (OLEDs), their…”
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7
Thermoelectricity in Molecular Junctions
Published in Science (American Association for the Advancement of Science) (16-03-2007)“…By trapping molecules between two gold electrodes with a temperature difference across them, the junction Seebeck coefficients of 1,4-benzenedithiol (BDT),…”
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8
Can Self-Assembly Address the Permeability/Selectivity Trade-Offs in Polymer Membranes?
Published in Macromolecules (28-07-2020)“…In 1999, Freeman published a visionary article that proposed a molecular basis for the trade-off between permeability and selectivity for polymeric gas…”
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Controlling the Doping Mechanism in Poly(3-hexylthiophene) Thin-Film Transistors with Polymeric Ionic Liquid Dielectrics
Published in Chemistry of materials (12-11-2019)“…Two disparate modes of operation can occur in an electrolyte-gated transistors (EGTs) depending on the permeability of the semiconductor to ions that are…”
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10
Polymer Chain Shape of Poly(3-alkylthiophenes) in Solution Using Small-Angle Neutron Scattering
Published in Macromolecules (12-03-2013)“…The chain shape of polymers affects many aspects of their behavior and is governed by their intramolecular interactions. Delocalization of electrons along the…”
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11
X‐Ray Scattering Reveals Ion‐Induced Microstructural Changes During Electrochemical Gating of Poly(3‐Hexylthiophene)
Published in Advanced functional materials (31-10-2018)“…The heterogeneous microstructure of semicrystalline polymers complicates the relationship between their electrical conductivity and carrier concentration…”
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12
Role of Disorder Induced by Doping on the Thermoelectric Properties of Semiconducting Polymers
Published in Chemistry of materials (08-05-2018)“…A fundamental understanding of charge transport in polymeric semiconductors requires knowledge of how the electrical conductivity varies with carrier density…”
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13
Water-Processable Polymer−Nanocrystal Hybrids for Thermoelectrics
Published in Nano letters (10-11-2010)“…We report the synthesis and thermoelectric characterization of composite nanocrystals composed of a tellurium core functionalized with the conducting polymer…”
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14
Surface Structure and Hydration of Sequence-Specific Amphiphilic Polypeptoids for Antifouling/Fouling Release Applications
Published in Langmuir (01-09-2015)“…Amphiphilic polypeptoids can be designed with specific sequences of hydrophilic and hydrophobic units, which determine their surface properties for…”
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15
Effect of Interfacial Properties on Polymer-Nanocrystal Thermoelectric Transport
Published in Advanced materials (Weinheim) (20-03-2013)“…The electrical behavior of a conducting‐polymer/inorganic‐nanowire composite is explained with a model in which carrier transport occurs predominantly through…”
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Light‐Controllable Ionic Conductivity in a Polymeric Ionic Liquid
Published in Angewandte Chemie International Edition (23-03-2020)“…Polymeric ionic liquids (PILs) have attracted considerable attention as electrolytes with high stability and mechanical durability. Light‐responsive materials…”
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Where Biology and Traditional Polymers Meet: The Potential of Associating Sequence-Defined Polymers for Materials Science
Published in JACS Au (25-10-2021)“…Polymers with precisely defined monomeric sequences present an exquisite tool for controlling material properties by harnessing both the robustness of…”
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18
Controlling inelastic light scattering quantum pathways in graphene
Published in Nature (London) (31-03-2011)“…Controlling scattered light Inelastic light scattering spectroscopy is a powerful tool used in materials science to probe elementary excitations. In the…”
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Thermoelectricity in Fullerene–Metal Heterojunctions
Published in Nano letters (12-10-2011)“…Thermoelectricty in heterojunctions, where a single-molecule is trapped between metal electrodes, has been used to understand transport properties at…”
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Chain Stiffness of Donor–Acceptor Conjugated Polymers in Solution
Published in Macromolecules (25-01-2022)“…The optoelectronic properties of conjugated polymers are dictated by their chain conformations, which depend on the interplay of delocalization of electrons…”
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