Search Results - "Sebastián, Rosa María"
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Mechanistic Studies on Ring-Opening Polymerization of Benzoxazines: A Mechanistically Based Catalyst Design
Published in Macromolecules (28-06-2011)“…Ring-opening polymerization behavior of a model p-cresol–aniline-based benzoxazine under various conditions was investigated in detail by 1H NMR analysis in…”
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Photochemical Polymerization of N‑Phenyl Mono-1,3-benzoxazines in Aqueous Media
Published in Macromolecules (22-05-2018)“…Some N-phenyl monosubstituted mono-1,3-benzoxazines can be polymerized under appropriate UV irradiation in aqueous solutions at room temperature. Photoinduced…”
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3
Triarylmethane Dyes for Artificial Repellent Cotton Fibers
Published in Chemistry : a European journal (17-03-2017)“…Families of new hydrophobic and/or oleophobic triarylmethane dyes possessing long hydrocarbon or polyfluorinated chains have been prepared. When covalently…”
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Photochemical Activation of Extremely Weak Nucleophiles: Highly Fluorinated Urethanes and Polyurethanes from Polyfluoro Alcohols
Published in Journal of organic chemistry (06-06-2014)“…An efficient and environmentally friendly photoreaction between phenyl isocyanate or pentafluorophenyl isocyanate and polyfluorinated alcohols and diols is…”
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Strategies for the Preparation of Phosphorus Janus Dendrimers and Their Properties
Published in Molecules (Basel, Switzerland) (21-07-2023)“…Dendrimers, being highly branched monodispersed macromolecules, predominantly exhibit identical terminal functionalities within their structural framework…”
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Triazine mediated covalent antibiotic grafting on cotton fabrics as a modular approach for developing antimicrobial barriers
Published in Cellulose (London) (01-08-2019)“…New antimicrobial textiles were prepared through direct chemical linkage of bioactive molecules eugenol and fluoroquinolone derivatives, onto the surface of…”
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Recoverable silica-gel supported binam-prolinamides as organocatalysts for the enantioselective solvent-free intra- and intermolecular aldol reaction
Published in Tetrahedron (28-01-2013)“…Silica-gel supported binam-derived prolinamides are efficient organocatalysts for the direct intramolecular and intermolecular aldol reaction under…”
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Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support
Published in Catalysts (01-01-2023)“…Two new unsymmetrical N-heterocyclic carbene ligand (uNHC)-based ruthenium complexes featuring phenolic OH function were obtained and fully characterised. The…”
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An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)
Published in Angewandte Chemie International Edition (13-10-2014)“…The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl…”
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Electroinduced crosslinking of triphenylamine-based polybenzoxazines
Published in Microchemical journal (01-11-2022)“…[Display omitted] •Synthesis, characterization and spectroelectrochemical properties of new triphenylamine-benzoxazine systems.•Determination of the…”
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Mechanistic Insights into Copper-Catalyzed Michael Reactions
Published in European Journal of Inorganic Chemistry (01-03-2010)“…The mechanism of the Michael reaction between 2‐(ethoxycarbonyl)cyclopentanone (2) and methyl vinyl ketone (3) catalyzed by the copper(II) salt…”
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Antibiotic protected silver nanoparticles for microbicidal cotton
Published in Tetrahedron (03-01-2019)“…Surface coating of metal nanoparticles is one of the major aspects to be optimized in the design of antimicrobial nanoparticles. The novelty of this work is…”
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Radical Dendrimers: A Family of Five Generations of Phosphorus Dendrimers Functionalized with TEMPO Radicals
Published in Macromolecules (25-11-2014)“…Five novel generations of phosphorus dendrimers based on a cyclotriphosphazene core with stable TEMPO radicals end groups have been synthesized and studied by…”
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Synthesis and Photochemical Behavior of Phosphorus Dendrimers Containing Azobenzene Units within the Branches and/or on the Surface
Published in Chemistry : a European journal (03-05-2002)“…We describe the synthesis of three series of phosphorus‐containing dendrimers having azobenzene derivatives specifically placed at some generations in the…”
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15
Heck–Matsuda reaction of arenediazonium salts in water
Published in Tetrahedron (25-03-2013)“…The palladium-catalyzed arylation of alkenes with aryldiazonium salts can be carried out through an environmentally friendly protocol using neat water low…”
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Specific Bifunctionalization on the Surface of Phosphorus Dendrimers Syntheses and Properties
Published in Organics (Basel) (01-09-2022)“…Dendrimers are highly branched macromolecules possessing, in most cases, identical terminal functions. However, it is sometimes desirable to have two types of…”
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Synthesis and Core and Surface Reactivity of Phosphorus-Based Dendrons
Published in European journal of inorganic chemistry (01-06-2004)“…A series of phosphorus‐containing dendrons is synthesized starting from a unique precursor (EtO)2P(O)CH=CHC6H4PPh2 (3‐G0), whose X‐ray crystal structure shows…”
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Dendritic structures within dendritic structures: dendrimer-induced formation and self-assembly of nanoparticle networks
Published in Nanoscale (01-11-2009)“…15-Membered tri-olefinic azamacrocycles as end-groups of phosphorus-containing dendrimers from generation 1 to 4 are used for obtaining Pt nanoparticles in…”
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Synthesis and Characterization of Phosphorus Dendrimers Containing Long, Conjugated Branches
Published in European Journal of Organic Chemistry (01-04-2005)“…The synthesis of a new family of phosphorus dendrimers is described up to the fifth generation (96 end‐groups). The reaction is based on the nucleophilic…”
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20
Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
Published in ARKIVOC (01-01-2007)Get full text
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