Search Results - "Sears, Trevor J."
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1
A theoretical study of the potential energy surface for the reaction OH + CO → H + CO2
Published in Chemical physics letters (07-12-2001)Get full text
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Photodissociation of Bromoform at 248 nm: Single and Multiphoton Processes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (04-03-2004)“…We have performed photodissociation experiments on CHBr3 at 248 nm using VUV ionization photofragment translational spectroscopy. Prompt C−Br bond fission is…”
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3
Kinetic study of the OH + ethylene reaction using frequency‐modulated laser absorption spectroscopy
Published in International journal of chemical kinetics (01-06-2019)“…The pressure dependence of the OH + C2H4 addition reaction has been investigated using frequency‐modulated laser absorption spectroscopy to monitor OH…”
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4
Doppler-Resolved Kinetics of Saturation Recovery
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-07-2015)“…Frequency-modulated laser transient absorption has been used to monitor the ground-state rotational energy-transfer rates of CN radicals in a double-resonance,…”
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5
Argon-Induced Pressure Broadening, Shifting, and Narrowing in the CN A2Π–X2Σ+ (1–0) Band
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-11-2013)“…Selected isolated rotational transitions in the 1–0 band of the red A2Π–X 2Σ+ system in CN have been recorded with transient frequency modulation spectroscopy…”
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What Is the Best DFT Functional for Vibronic Calculations? A Comparison of the Calculated Vibronic Structure of the S1–S0 Transition of Phenylacetylene with Cavity Ringdown Band Intensities
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (28-06-2012)“…The sensitivity of vibronic calculations to electronic structure methods and basis sets is explored and compared to accurate relative intensities of the…”
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Enhancement of Triplet Stability in Benzene by Substituents with Triple Bonds
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (22-08-2013)“…Excitation of phenylacetylene (PA) and benzonitrile to their lowest singlet states in a molecular beam has previously been shown to immediately (only during…”
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Temperature-Dependent, Nitrogen-Perturbed Line Shape Measurements in the ν1 + ν3 Band of Acetylene Using a Diode Laser Referenced to a Frequency Comb
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (19-12-2013)“…The P(11) line of the ν1 + ν3 combination band of C2H2 was studied using an extended cavity diode laser locked to a frequency comb. Line shapes were measured…”
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Vibronic Analysis of the S1−S0 Transition of Phenylacetylene Using Photoelectron Imaging and Spectral Intensities Derived from Electronic Structure Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (19-08-2010)“…The vibrational structure of the S1−S0 electronic band of phenylacetylene has been recorded by 1 + 1 resonance-enhanced multiphoton ionization, accompanied by…”
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State Mixing and Predissociation in the c̃ ← ã Band System of Singlet Methylene Studied by Optical−Optical Double Resonance
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-10-2008)“…In an attempt to characterize the state interactions near the dissociation energy of singlet methylene, the near ultraviolet band system of singlet methylene…”
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Sub-Doppler Stark Spectroscopy in the A−X (1,0) Band of CN
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (26-11-2009)“…The effect of external electric fields has been measured in hyperfine-resolved sub-Doppler transitions in the A 2Π−X 2Σ (1,0) band of the CN radical near 10…”
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12
Photoinduced Rydberg ionization spectroscopy of the B state of benzonitrile cation
Published in The Journal of chemical physics (28-10-2006)“…Photoinduced Rydberg ionization (PIRI) spectra of the second excited electronic state of benzonitrile cation were recorded via the origin and 6a1 and 6b1…”
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13
AC Stark detection of optical-optical double resonance in CH2
Published in Physical chemistry chemical physics : PCCP (28-06-2006)“…A new scheme for the detection of double resonance spectra of chemical intermediates involves negligible population transfer but the detection of electric…”
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14
Photoinduced Rydberg Ionization Spectroscopy of Phenylacetylene: Vibrational Assignments of the C̃ State of the Cation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (29-06-2006)“…The photoinduced Rydberg ionization spectrum of the third excited electronic state of phenylacetylene cation was recorded via the origin of the cation ground…”
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Pseudo-continuous resonance enhanced multiphoton ionisation: application to the determination of the hyperfine constants of 208Pb19F
Published in Molecular physics (10-04-2010)“…A highly efficient pseudo continuous resonance enhanced multiphoton ionisation detection scheme is presented that combines the sensitivity of resonance…”
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Doppler-Resolved Spectroscopy as an Assignment Tool in the Spectrum of Singlet Methylene
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (30-09-2004)“…New spectra of methylene, CH2, in the near-infrared have been obtained following 308 nm photolysis of ketene, CH2CO. Nascent photofragment Doppler spectra and…”
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Absorption Spectroscopy of Singlet CH2 near 9500 cm-1
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-11-2000)“…The b̃ 1B1−ã 1A1 spectrum of methylene between 9317 and 9610 cm-1 was recorded using frequency-modulated diode laser absorption spectroscopy. This is the…”
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Kinetics and Product Study of the Reaction of CH3 Radicals with O(3P) Atoms Using Time Resolved Time-of-Flight Spectrometry
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (22-07-1999)“…The kinetics and product distribution for the reaction of methyl radicals, CH3, with ground-state O(3P) oxygen atoms have been investigated. This reaction was…”
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Investigating the photodissociation of H2O2 using frequency modulation laser absorption spectroscopy to monitor radical products
Published in Chemical physics letters (01-11-2018)“…[Display omitted] •Detection of OH and HO2 has been demonstrated using FM laser absorption spectroscopy.•Room temperature photolysis of H2O2 at 193 nm in argon…”
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Frequency-comb referenced spectroscopy of v4- and v5-excited hot bands in the 1.5μm spectrum of C2H2
Published in Journal of molecular spectroscopy (01-10-2015)“…[Display omitted] •More than 130 v4 and v5 hot band lines in the v1+v3 band of C2H2 frequency measured with errors below 25kHz.•Perturbations in excited state…”
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