Search Results - "Scott, Neil W. J"

A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticlesthe Case for Exploiting Pd Catalyst Speciation by Scott, Neil W. J, Ford, Mark J, Jeddi, Neda, Eyles, Anthony, Simon, Lauriane, Whitwood, Adrian C, Tanner, Theo, Willans, Charlotte E, Fairlamb, Ian J. S

“…Site-selective dihalogenated heteroarene cross-coupling with organometallic reagents usually occurs at the halogen proximal to the heteroatom, enabled by…”
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Reactivity of a Dinuclear PdI Complex [Pd2(μ-PPh2)(μ2‑OAc)(PPh3)2] with PPh3: Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)2/nPPh3 Catalyst System by Scott, Neil W. J, Ford, Mark J, Husbands, David R, Whitwood, Adrian C, Fairlamb, Ian J. S

“…[PdI 2(μ-PPh2)­(μ2-OAc)­(PPh3)2] is the reduction product of PdII(OAc)2(PPh3)2, generated by reaction of ‘Pd­(OAc)2’ with two equivalents of PPh3. Here, we…”
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Evidence for Suzuki-Miyaura cross-couplings catalyzed by ligated Pd 3 -clusters: from cradle to grave by Jeddi, Neda, Scott, Neil W J, Tanner, Theo, Beaumont, Simon K, Fairlamb, Ian J S

“…Pd clusters offer unique selectivity and exploitable reactivity in catalysis. Understanding the behavior of Pd clusters is thus critical for catalysis, applied…”
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Evidence for Suzuki–Miyaura cross-couplings catalyzed by ligated Pd3-clusters: from cradle to grave by Jeddi, Neda, Scott, Neil W J, Tanner, Theo, Beaumont, Simon K, Fairlamb, Ian J S

“…Pdn clusters offer unique selectivity and exploitable reactivity in catalysis. Understanding the behavior of Pdn clusters is thus critical for catalysis,…”
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Opening a Pandora’s Flask on a Prototype Catalytic Direct Arylation Reaction of Pentafluorobenzene: The Ag2CO3/Pd(OAc)2/PPh3 System by Platt, George M.H., Aguiar, Pedro M., Athavan, Gayathri, Bray, Joshua T.W., Scott, Neil W.J., Fairlamb, Ian J.S., Perutz, Robin N.

“…Direct C–H functionalization reactions have opened new avenues in catalysis, removing the need for prefunctionalization of at least one of the substrates…”
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Well-Defined Pd n Clusters for Cross-Coupling and Hydrogenation Catalysis: New Opportunities for Catalyst Design by Jeddi, Neda, Scott, Neil W. J., Fairlamb, Ian J. S.

“…In recent studies it has been demonstrated that the privileged reactivity of higher-order metal clusters can be exploited in widely applied catalytic…”
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Evidence for Suzuki-Miyaura cross-couplings catalyzed by ligated Pd-clusters: from cradle to grave by Jeddi, Neda, Scott, Neil W. J, Tanner, Theo, Beaumont, Simon K, Fairlamb, Ian J. S

“…Pd n clusters offer unique selectivity and exploitable reactivity in catalysis. Understanding the behavior of Pd n clusters is thus critical for catalysis,…”
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Reactivity of a Dinuclear Pd I Complex [Pd 2 (μ-PPh 2 )(μ 2 -OAc)(PPh 3 ) 2 ] with PPh 3 : Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc) 2 /nPPh 3 Catalyst System by Scott, Neil W. J., Ford, Mark J., Husbands, David R., Whitwood, Adrian C., Fairlamb, Ian J. S.

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Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalytic Species for Suzuki–Miyaura Couplings (X = P, As) by Appleby, Kate M, Dzotsi, Evans, Scott, Neil W. J, Dexin, Guan, Jeddi, Neda, Whitwood, Adrian C, Pridmore, Natalie E, Hart, Sam, Duckett, Simon B, Fairlamb, Ian J. S

“…Tripalladium clusters of the type [Pd3(PPh3)4]2+, wherein three linearly connected Pd atoms are stabilized by phosphine and arsine ligands, have been detected…”
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Bridging the Gap from Mononuclear Pd II Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd 3 (XPh 3 ) 4 ] 2+ Clusters as Catalytic Species for Suzuki–Miyaura Couplings (X = P, As) by Appleby, Kate M., Dzotsi, Evans, Scott, Neil W. J., Dexin, Guan, Jeddi, Neda, Whitwood, Adrian C., Pridmore, Natalie E., Hart, Sam, Duckett, Simon B., Fairlamb, Ian J. S.

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The ubiquitous cross-coupling catalyst system ‘Pd(OAc) 2 ’/2PPh 3 forms a unique dinuclear Pd I complex: an important entry point into catalytically competent cyclic Pd 3 clusters by Scott, Neil W. J., Ford, Mark J., Schotes, Christoph, Parker, Rachel R., Whitwood, Adrian C., Fairlamb, Ian J. S.

“…Palladium( ii ) acetate ‘Pd(OAc) 2 ’/ n PPh 3 is a ubiquitous precatalyst system for cross-coupling reactions. It is widely accepted that reduction of in situ…”
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The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd3 clusters by Scott, Neil W J, d, Mark J, Schotes, Christoph, Parker, Rachel R, Whitwood, Adrian C, Fairlamb, Ian J S

“…Palladium(ii) acetate ‘Pd(OAc)2’/nPPh3 is a ubiquitous precatalyst system for cross-coupling reactions. It is widely accepted that reduction of in situ…”
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The ubiquitous cross-coupling catalyst system 'Pd(OAc)'/2PPh forms a unique dinuclear Pd complex: an important entry point into catalytically competent cyclic Pd clusters by Scott, Neil W. J, Ford, Mark J, Schotes, Christoph, Parker, Rachel R, Whitwood, Adrian C, Fairlamb, Ian J. S

“…Palladium( ii ) acetate 'Pd(OAc) 2 '/ n PPh 3 is a ubiquitous precatalyst system for cross-coupling reactions. It is widely accepted that reduction of in situ…”
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