Search Results - "Sciarone, Timo J. J."

Methacrylic Stereoblock Copolymers via the Combination of Catalytic Chain Transfer and Anionic Polymerization by Sanders, Gemma C., Sciarone, Timo J. J., Lambermont-Thijs, Hanneke M. L., Duchateau, Robbert, Heuts, Johan P. A.

“…A novel synthetic pathway toward stereoblock copolymers by combining catalytic chain transfer polymerization with anionic polymerization is described…”
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Strategies for the Synthesis of Lanthanum Dialkyl Complexes with Monoanionic Ancillary Ligands by Bambirra, Sergio, Perazzolo, Francesca, Boot, Steven J, Sciarone, Timo J. J, Meetsma, Auke, Hessen, Bart

“…The synthesis of lanthanum dialkyl complexes with monoanionic ancillary ligands [L]− is pursued by three different strategies: (a) in situ peralkylation of…”
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Isobutene Polymerization Using Chelating Diboranes: Polymerization in Aqueous Suspension and Hydrocarbon Solution by Lewis, Stewart P, Chai, Jianfang, Collins, Scott, Sciarone, Timo J. J, Henderson, Lee D, Fan, Cheng, Parvez, Masood, Piers, Warren E

“…The use of the chelating diboranes o-C6F4[B(C6F5)2]2 (1) and o-C6F4(9-BC12F8)2 (2: 9-BC12F8 = 1,2,3,4,5,6,7,8-octafluoro-9-borafluorene) for the polymerization…”
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Formation of Chelated Counteranions Using Lewis Acidic Diboranes:  Relevance to Isobutene Polymerization by Chai, Jianfang, Lewis, Stewart P, Collins, Scott, Sciarone, Timo J. J, Henderson, Lee D, Chase, Preston A, Irvine, Geoffrey J, Piers, Warren E, Elsegood, Mark R. J, Clegg, William

“…The reactions of chelating diboranes with PhCMe2Cl and related initiators were studied by variable-temperature NMR spectroscopy. Although thermally stable…”
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effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate by Smeets, Niels M.B, Jansen, Tom G.T, Sciarone, Timo J.J, Heuts, Johan P.A, Meuldijk, Jan, Van Herk, Alex M

“…The effect a Co(II) based catalytic chain transfer agent (CCTA) has on the course of the polymerization and the product properties of an emulsion…”
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Neutral and Cationic Paramagnetic Amino-amidinate Iron(II) Complexes: 19F NMR Evidence for Interactions with Weakly Coordinating Anions by Sciarone, Timo J. J, Nijhuis, Christian A, Meetsma, Auke, Hessen, Bart

“…Two alkylamino-benzamidinates, [RNC(Ph)NCH2CH2NMe2]− (ArL, R = 2,6-iPr2C6H3; SiL, R = SiMe3), have been employed as ligands for Fe(II). The ligands adopt…”
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Reactivity of Paramagnetic Fe II –Bis(amidinate) Complexes by Jellema, Erica, Sciarone, Timo J. J., Navarrete, Noa M., Hettinga, Marten J., Meetsma, Auke, Hessen, Bart

“…Synthesis and characterisation of ether adducts of bis(amidinate) Fe II complexes are described [amidinate = 2,6‐ i Pr 2 C 6 H 3 –NC(Ph)N–Ph]. The isolation of…”
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First‐Row Transition Metal Bis(amidinate) Complexes; Planar Four‐Coordination of Fe II Enforced by Sterically Demanding Aryl Substituents by Nijhuis, Christian A., Jellema, Erica, Sciarone, Timo J. J., Meetsma, Auke, Budzelaar, Peter H. M., Hessen, Bart

“…The sterically hindered benzamidinate ligand [PhC(NAr) 2 ] – (Ar = 2,6‐ i Pr 2 C 6 H 3 ) has been employed to prepare bis(amidinate) complexes [{PhC(NAr) 2 } 2…”
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Neutral and Cationic Paramagnetic Amino-amidinate Iron(II) Complexes: 19 F NMR Evidence for Interactions with Weakly Coordinating Anions by Sciarone, Timo J. J., Nijhuis, Christian A., Meetsma, Auke, Hessen, Bart

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3-Metalla-1,2-dioxolanes and Their Reactivity by Krom, Monique, Peters, Theo P. J., Coumans, Ruud G. E., Sciarone, Timo J. J., Hoogboom, Johan, ter Beek, Sandra I., Schlebos, Paul P. J., Smits, Jan M. M., de Gelder, René, Gal, Anton W.

“…The ethene complexes [MI(CH2CH2)]+ (M = Ir, Rh) can be oxygenated by molecular oxygen or air in the solid state, to form isolable unsubstituted…”
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Reactivity of Paramagnetic FeII-Bis(amidinate) Complexes by Jellema, Erica, Sciarone, Timo J. J., Navarrete, Noa M., Hettinga, Marten J., Meetsma, Auke, Hessen, Bart

“…Synthesis and characterisation of ether adducts of bis(amidinate) FeII complexes are described [amidinate = 2,6‐iPr2C6H3–NC(Ph)N–Ph]. The isolation of these…”
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First-Row Transition Metal Bis(amidinate) Complexes; Planar Four-Coordination of FeII Enforced by Sterically Demanding Aryl Substituents by Nijhuis, Christian A., Jellema, Erica, Sciarone, Timo J. J., Meetsma, Auke, Budzelaar, Peter H. M., Hessen, Bart

“…The sterically hindered benzamidinate ligand [PhC(NAr)2]– (Ar = 2,6‐iPr2C6H3) has been employed to prepare bis(amidinate) complexes [{PhC(NAr)2}2M] of the…”
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