Search Results - "Schwarz, Andrew D."

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene by Protchenko, Andrey V, Bates, Joshua I, Saleh, Liban M. A, Blake, Matthew P, Schwarz, Andrew D, Kolychev, Eugene L, Thompson, Amber L, Jones, Cameron, Mountford, Philip, Aldridge, Simon

“…By employing strongly σ-donating boryl ancillary ligands, the oxidative addition of H2 to a single site SnII system has been achieved for the first time,…”
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A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene by Protchenko, Andrey V., Schwarz, Andrew D., Blake, Matthew P., Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip, Aldridge, Simon

“…Si in sight: A one‐pot, single‐step synthesis of an acyclic silylsilylene, Si{Si(SiMe3)3}{N(SiMe3)Dipp} (Dipp=2,6‐iPr2C6H3), from a silicon(IV) starting…”
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Reactivity of Boryl- and Silyl-Substituted Carbenoids toward Alkynes: Insertion and Cycloaddition Chemistry by Protchenko, Andrey V, Blake, Matthew P, Schwarz, Andrew D, Jones, Cameron, Mountford, Philip, Aldridge, Simon

“…Three modes of reactivity of phenyl-substituted alkynes toward acyclic tetrelenes are reported, with reaction pathways found to be dependent not only on the…”
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Ring-Opening Polymerization of rac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study by Dyer, Hellen E, Huijser, Saskia, Susperregui, Nicolas, Bonnet, Fanny, Schwarz, Andrew D, Duchateau, Robbert, Maron, Laurent, Mountford, Philip

“…The synthesis and ring-opening polymerization (ROP) capability of bis(phenolate)amine-supported samarium borohydride and amide complexes are reported, together…”
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Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation by Huang, Yong, Wang, Wei, Lin, Chu-Chieh, Blake, Matthew P, Clark, Lawrence, Schwarz, Andrew D, Mountford, Philip

“…Reaction of the OOO-coordinating tridentate bis(phenolate) protio-ligand 2,2'-{oxybis(methylene)}bis{4,6-di(1-methyl-1-phenylethyl)phenol} (L(O3)-H2), with 1…”
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Ligand Variations in New Sulfonamide-Supported Group 4 Ring-Opening Polymerization Catalysts by Schwarz, Andrew D, Herbert, Katherine R, Paniagua, Cristina, Mountford, Philip

“…The synthesis, structures, and ring-opening polymerization (ROP) capability of a wide range of sulfonamide-supported group 4 amide, alkyl, and alkoxide…”
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A Remarkable Switch from a Diamination to a Hydrohydrazination Catalyst and Observation of an Unprecedented Catalyst Resting State by Schwarz, Andrew D., Onn, Chee S., Mountford, Philip

“…A small change with a big effect: Reaction of the titanium complex 1 with terminal alkynes gave the unusual acetylide–vinylhydrazide(1−) compounds 2 (R=4‐C6H4X…”
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Oxidative Bond Formation and Reductive Bond Cleavage at Main Group Metal Centers: Reactivity of Five-Valence-Electron MX2 Radicals by Protchenko, Andrey V., Dange, Deepak, Blake, Matthew P., Schwarz, Andrew D., Jones, Cameron, Mountford, Philip, Aldridge, Simon

“…Monomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M–C bond formation with 2,3-dimethylbutadiene, in a…”
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Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands by Unruangsri, Junjuda, Morgan, Hannah, Schwarz, Andrew D, Schofield, A. Daniel, Mountford, Philip

“…The synthesis and reactivity of titanium diphenyl hydrazido(2−) complexes supported by the diamido-ether ligands O(2-C6H4NSiMe3)2 (N2 ArO) and O(CH2CH2NSiMe3)2…”
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Synthesis, Structures and Reactivity of Group 4 Hydrazido Complexes Supported by Calix[4]arene Ligands by Clulow, Andrew J, Selby, Jonathan D, Cushion, Michael G, Schwarz, Andrew D, Mountford, Philip

“…Reaction of TiCl2(Me2Calix) with 2 equiv of LiNHNRR′ afforded the corresponding terminal hydrazido(2-) complexes Ti(NNRR′)(Me2Calix) (R = Ph, R′ = Ph (1) or…”
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New Sandwich and Half-Sandwich Titanium Hydrazido Compounds by Selby, Jonathan D, Feliz, Marta, Schwarz, Andrew D, Clot, Eric, Mountford, Philip

“…New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2−) compounds were prepared by tert-butyl imide/N,N-disubstituted hydrazine exchange reactions…”
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A Stable Two-Coordinate Acyclic Silylene by Protchenko, Andrey V., Birjkumar, Krishna Hassomal, Dange, Deepak, Schwarz, Andrew D., Vidovic, Dragoslav, Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip, Aldridge, Simon

“…Simple two-coordinate acyclic silylenes, SiR2, have hitherto been identified only as transient intermediates or thermally labile species. By making use of the…”
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Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization of rac-Lactide by Schwarz, Andrew D, Chu, Zengyong, Mountford, Philip

“…The synthesis, structures, and ring-opening polymerization (ROP) capability of a wide range of sulfonamide-supported aluminum alkyl and alkoxide complexes are…”
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A Reflection on Sustainable Anode Materials for Electrochemical Chloride Oxidation by Choi, Seungwoo, Choi, Won Il, Lee, Jun-Seo, Lee, Chang Hyun, Balamurugan, Mani, Schwarz, Andrew D, Choi, Zung Sun, Randriamahazaka, Hyacinthe, Nam, Ki Tae

“…Chloride oxidation is a key industrial electrochemical process in chlorine-based chemical production and water treatment. Over the past few decades,…”
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Sulfonamide-Supported Group 4 Catalysts for the Ring-Opening Polymerization of ε-Caprolactone and rac-Lactide by Schwarz, Andrew D, Thompson, Amber L, Mountford, Philip

“…Reaction of RCH2N(CH2CH2NHSO2Tol)2 (R = 2-NC5H4 (8, H2Lpy) or MeOCH2 (9, H2LOMe)) with Ti(NMe2)4 at room temperature afforded Ti(Lpy)(NMe2)2 (10) or…”
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Dicationic and zwitterionic catalysts for the amine-initiated, immortal ring-opening polymerisation of rac-lactide: facile synthesis of amine-terminated, highly heterotactic PLA by Clark, Lawrence, Cushion, Michael G, Dyer, Hellen E, Schwarz, Andrew D, Duchateau, Robbert, Mountford, Philip

“…Dicationic, zwitterionic and "conventional" yttrium compounds act as catalysts for the primary or secondary amine-initiated immortal ROP of rac-lactide;…”
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Surface forces and friction between Langmuir-Blodgett polymer layers in a nonpolar solvent by Taylor, Nicholas M., Pilkington, Georgia A., Snow, Tim, Dowding, Peter J., Cattoz, Beatrice N., Schwarz, Andrew D., Bikondoa, Oier, Vincent, Brian, Briscoe, Wuge H.

“…[Display omitted] Optimization of boundary lubrication by tuning the confined molecular structures formed by surface-active additives such as surfactants and…”
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Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium “Metalloid” Clusters by Protchenko, Andrey V., Urbano, Juan, Abdalla, Joseph A. B., Campos, Jesús, Vidovic, Dragoslav, Schwarz, Andrew D., Blake, Matthew P., Mountford, Philip, Jones, Cameron, Aldridge, Simon

“…Reduction of indium boryl precursors to give two‐ and three‐dimensional M−M bonded networks is influenced by the choice of supporting ligand. While the…”
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Stable GaX2, InX2 and TlX2 radicals by Protchenko, Andrey V., Dange, Deepak, Harmer, Jeffrey R., Tang, Christina Y., Schwarz, Andrew D., Kelly, Michael J., Phillips, Nicholas, Tirfoin, Remi, Birjkumar, Krishna Hassomal, Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip, Aldridge, Simon

“…The chemistry of the Group 13 metals is dominated by the +1 and +3 oxidation states, and simple monomeric M (II) species are typically short-lived, highly…”
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Group 3 and Lanthanide Boryl Compounds: Syntheses, Structures, and Bonding Analyses of Sc−B, Y−B, and Lu−B σ-Coordinated NHC Analogues by Saleh, Liban M. A, Birjkumar, Krishna Hassomal, Protchenko, Andrey V, Schwarz, Andrew D, Aldridge, Simon, Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip

“…Reaction of [Ln(CH2SiMe3)2(THF) n ][BPh4] (Ln = Sc, Y, Lu ; n = 3, 4) with Li{B(NArCH)2}(THF)2 (Ar = 2,6-C6H3 iPr2) formed the first group 3 and lanthanide…”
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