Search Results - "Schulze, Bärbel"
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Oxidation of 3,4-dialkyl substituted isothiazolium salts to 1,1-dioxides
Published in ARKIVOC (01-01-2011)Get full text
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Thermochemiluminescence as a fast method to detect and characterize hydroperoxide moieties in novel 3-hydroperoxyisothiazole 1,1-dioxides
Published in Tetrahedron (19-08-2012)“…Hydroperoxy compounds are important for selective oxidation of organic precursors in the chemical industry. Moreover, novel 3-hydroperoxyisothiazole…”
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[π4+π2] Cycloadditions of Isothiazole Derivatives
Published in Heterocycles (31-12-2003)Get full text
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Fluorinated Diazo Diketones in Rhodium(II)-Catalyzed Reactions with Sultams: Chemoselective O-Functionalization of Amide Carbonyl Groups
Published in Helvetica chimica acta (01-07-2005)“…Rhodium(II)‐catalyzed decomposition of fluorinated diazo diketones in the presence of isothiazole‐3(2H)‐one 1,1‐dioxides offers a chemoselective and useful…”
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Spirocyclic and Fused Derivatives of Maleimide Based on Intra- and Intermolecular Reactions of Carbonyl Ylides from Diazocarbonyl Compounds
Published in Heterocycles (01-12-2007)Get full text
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N, N′-Linked 1,2-benzisothiazol-3( 2H)-one 1,1-dioxides: synthesis, biological activity, and derived radicals
Published in Tetrahedron (02-01-2010)“…A number of N, N′-linked benzoannelated isothiazol-3( 2H)-one 1,1-dioxides, not available via oxidation of isothiazolium salts, were obtained with good yields…”
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Vanadium diboride catalyzed oxidation of cyclooctene by molecular oxygen: Kinetic study
Published in Journal of molecular catalysis. A, Chemical (01-04-2009)“…The kinetics of initial stages of the liquid-phase oxidation of cyclooctene by molecular oxygen catalyzed by VB 2 has been reported for the first time. The…”
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Chemoselective Electrophilic Oxidation of Heteroatoms by Hydroperoxy Sultams
Published in Journal of organic chemistry (29-11-2002)“…The synthesis of novel hydroperoxy sultams 1b−d and their potential as renewable chemoselective electrophilic oxidants for a wide range of nitrogen, sulfur,…”
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Synthesis of Stable Isothiazole Carbenes
Published in Angewandte Chemie International Edition (01-01-2007)“…Through deprotonation of isothiazolium salts, stable substituted singlet carbenes of isothiazol‐3‐ylidenes (see scheme) could be synthesized for the first…”
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Synthesis and elastase-inhibiting activity of 2-pyridinyl-isothiazol-3(2 H)-one 1,1-dioxides
Published in Bioorganic & medicinal chemistry (01-09-2008)“…The synthesis of a series of new isothiazol-3(2 H)-one 1,1-dioxides with halogenated (mostly fluorinated) pyridinyl and pentafluorophenyl substituents at…”
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Reply to "Recently Reported Crystalline Isothiazole Carbenes: Myth or Reality"
Published in Angewandte Chemie International Edition (10-09-2007)“…In light of the results of Bertrand and co‐workers, the isothiazole carbenes previously reported by us cannot be considered to be stable. Evidently they are…”
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3,3,6,6-Tetramethyl-1,2,4,5-tetroxane: a twinned crystal structure
Published in Acta crystallographica. Section C, Crystal structure communications (01-03-2004)“…The title compound, C6H12O4, also known as dimeric acetone peroxide, Me2(C2O4)Me2, has crystallographically imposed inversion symmetry and adopts a chair…”
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Aniline Exchange of 2-Aryl-4,5-diphenyl-substituted Isothiazolium Salts
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-04-2008)“…4,5-Diphenyl-substituted N-(R -aryl)-isothiazolium salts 4 react with anilines 2 (R ) to form 4,5- disubstituted N-(R -aryl)-isothiazolium salts 4. The…”
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2,4,5-Triphenylisothiazol-3 (2H)-one 1,1-dioxides as inhibitors of human leukocyte elastase
Published in Journal of enzyme inhibition and medicinal chemistry (01-08-2005)“…A series of substituted 2,4,5-triphenylisothiazol-3(2H)-one 1,1-dioxides 9 was synthesized and investigated as inhibitors of human leukocyte elastase (HLE)…”
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N,N'-Linked 1,2-benzisothiazol-3(2H)-one 1,1-dioxides: synthesis, biological activity, and derived radicals
Published in Tetrahedron (2010)Get full text
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Synthesis of 4-(Isothiazol-3-yl)morpholines and 1-(Isothiazol-3-yl)piperazines, and Their Inhibitory Activity towards Acetylcholinesterase
Published in Helvetica chimica acta (01-01-2008)“…The synthesis of novel triaryl‐substituted 4‐(isothiazol‐3‐yl)morpholines 7 and 8, and 1‐(isothiazol‐3‐yl)piperazines 9–13 by reaction of the corresponding…”
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3,3,6,6-Tetramethyl-1,2,4,5-tetroxane: a twinned crystal structure
Published in Acta crystallographica. Section C, Crystal structure communications (01-03-2004)“…The title compound, C6H12O4, also known as dimeric acetone peroxide, Me2(C2O4)Me2, has crystallographically imposed inversion symmetry and adopts a chair…”
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Synthesis of N,N’-Linked Isothiazolium Salts via Intramolecular Cyclocondensation of Hydrazonium Salts
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-04-2006)“…Interaction of β -thiocyanatovinyl aldehydes with N-amino heterocycles leads to formation of α, β - unsaturated hydrazonium salts dependent on the functional…”
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Novel Synthesis of 2-Aryl-4,5,6,7-tetrahydro-1,2-benzisothiazol-3(2H)-ones and Their S-Oxides
Published in Helvetica chimica acta (01-02-2004)“…2‐Aryl‐4,5,6,7‐tetrahydro‐1,2‐benzisothiazol‐3(2H)‐ones 1a–e were synthesized by cyclocondensation of 2‐(thiocyanato)cyclohexene‐1‐carboxanilides 9 as a…”
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