Search Results - "Schuh, Walter"

Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodiphosphorane iridium intermediate: substitution of one phosphine moiety of a carbodiphosphorane by an organic azide by Partl, Gabriel Julian, Nussbaumer, Felix, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The structure of [Ir{(4-Cl-C 6 H 4 N 3 )C(dppm)-κ 3 P , C , N }(dppm-κ 2 P , P ′)]Cl·1.5CH 2 Cl 2 ·0.5C 7 H 8 (C 57 H 48 Cl 2 IrN 3 P 4 ·1.5CH 2 Cl 2 ·0.5C 7 H…”
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Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand by Partl, Gabriel Julian, Nussbaumer, Felix, Schlapp-Hackl, Inge, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…Compound [Ir(C 8 H 12 )(C 51 H 45 P 4 )]Cl 2 or [Ir(cod)(CH(dppm) 2 -κ 3 P , C , P )]Cl 2 ( 1a ), was obtained from [IrCl(cod)] 2 and the carbodiphosphorane…”
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Crystal structures of the [Ir III {C(C 4 H 6 O 2 )(dppm)-κ 3 P , C , O }(dppm)H](CF 3 O 3 S) 2 and [Ir III {C(C 4 H 6 O 2 )(dppm)-κ 2 P , C }(CO)(dppm)H](CF 3 O 3 S) 2 phosphorus ylide complexes, generated by a Wittig-type carbon–carbon coupling reaction of a carbodiphosphorane PCP ligand system by Schlapp-Hackl, Inge, Pauer, Bettina, Falschlunger, Christoph, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The reaction of [Ir III {C(dppm) 2 -κ 3 P , C , P ′}ClH(NH 3 C 2 )]Cl with ethyl diazoacetate, a well known C=C coupling reagent, leads to the formation of a…”
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Syntheses and crystal structures of [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}ClH]Cl·2.75CH2Cl2 and its derivatives, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}(CH2CO2Et)Cl]Cl·CH3OH·0.5H2O, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}Cl2]Cl·CH3OH·2H2O and [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C',P'}(CH2CO2Et)(CO)]Cl2·2CH2Cl2·1.5H2O by Schlapp-Hackl, Inge, Falschlunger, Christoph, Zauner, Kathrin, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The common feature of the four iridium(III) salt complexes,…”
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Crystal structures of [IrCl2(NHCHPh)((dppm)(C(N2dppm))-κ3 P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N2))-κ2 P,C)(dppm-κ2 P,P′)]I(I3)·0.5I2·MeOH·0.5CH2Cl2: triazene fragmentation in a PCN pincer iridium complex by Pauer, Bettina, Partl, Gabriel Julian, Oberparleiter, Stefan, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…In this communication, two compounds and their respective crystal structures, obtained via fragmentation of the triazene moiety in a PCN pincer iridium…”
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Crystal structure of an iridium(III) complex of the [C(dppm) 2 ] PCP pincer ligand system and its conjugate CH acid form by Reitsamer, Christian, Schlapp-Hackl, Inge, Partl, Gabriel, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…After the successful creation of the newly designed PCP carbodi-phospho-rane (CDP) ligand [Reitsamer (2012 ▸). , 3503-3514; Stallinger (2007 ▸). pp. 510-512],…”
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Metal “Capture” by a Heterotrimetalloligand, Heterometallic d10−d10 Interactions, and Unexpected Iron-to-Platinum Silyl Ligand Migration:  a Combined Experimental and Theoretical Study by Schuh, Walter, Braunstein, Pierre, Bénard, Marc, Rohmer, Marie-Madeleine, Welter, Richard

“…The heterotrinuclear chain complex Hg[Fe{Si(OMe)3}(CO)3(dppm-P)]2 (dppm = Ph2PCH2PPh2) 1 which has a transoid arrangement of the phosphine donors was used as a…”
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Homochiral Self Recognition in Gold-Phosphane-Helicates by Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…Treatment of Au(SMe2)Cl with a mixture of (R*,S*)‐ and (R*,R*)‐(±)‐p4 (p4 = 1,1,4,7,10,10‐hexaphenyl‐1,4,7,10‐tetraphosphadecane) and TlOTf produces…”
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Gold(I) and Gold(III) complexes of the [CH(dppm)2]+ and C(dppm)2 PCP pincer ligand systems by Reitsamer, Christian, Hackl, Inge, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…Gold(III) complexes of the PCP pincer carbodiphosphorane (CDP) ligand C(dppm)2 and gold(I) complexes of the conjugate CH acid [CH(dppm)2]+ were synthesized and…”
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Crystal structures of [IrCl 2 (NHCHPh)((dppm)(C(N 2 dppm))-κ 3 P , C , P ')]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N 2 ))-κ 2 P , C )(dppm-κ 2 P , P ')]I(I 3 )·0.5I 2 ·MeOH·0.5CH 2 Cl 2 : triazene fragmentation in a PCN pincer iridium complex by Pauer, Bettina, Partl, Gabriel Julian, Oberparleiter, Stefan, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The structure of [IrCl (C H N P )]Cl·5.5CH CN or [IrCl (NHCHPh)(((dppm)C(N dppm)) κ )]Cl·5.5CH CN [ , dppm = bis-(di-phenyl-phos-phino)methane; systematic…”
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The First Carbodiphosphorane Complex with Two Palladium Centers Attached to the CDP Carbon: Assembly of a Single-Stranded di-Pd Helicate by the PCP Pincer ligand C(dppm)2 by Reitsamer, Christian, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Ellmerer, Ernst P, Peringer, Paul

“…The reaction of the protonated PCP pincer carbodiphosphorane (CDP) complex [PdCl(CH(dppm)2)]Cl2 (1) with [PdCl2(MeCN)2] results in the opening of one ring of…”
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Crystal structures of IrCl2(NHCHPh)((dppm)(C(N2dppm))-κ3 P,C,P')Cl·5.5MeCN and IrI(NHCHPh)(((dppm)C(N2))-κ2 P,C)(dppm-κ2 P,P')I(I3)·0.5I2·MeOH·0.5CH2Cl2: triazene fragmentation in a PCN pincer iridium complex by Pauer, Bettina, Partl, Gabriel Julian, Oberparleiter, Stefan, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The structure of [IrCl2(C58H51N3P4)]Cl·5.5CH3CN or [IrCl2(NHCHPh)(((dppm)C(N2dppm))-κ 3P,C,P)]Cl·5.5CH3CN [3, dppm = bis-(di-phenyl-phos-phino)methane;…”
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Syntheses and crystal structures of [Ir III {C(CHCO 2 Et)(dppm) 2 -κ 4 P , C , C ', P '}ClH]Cl·2.75CH 2 Cl 2 and its derivatives, [Ir III {C(CHCO 2 Et)(dppm) 2 -κ 4 P , C , C ', P '}(CH 2 CO 2 Et)Cl]Cl·CH 3 OH·0.5H 2 O, [Ir III {C(CHCO 2 Et)(dppm) 2 -κ 4 P , C , C ', P '}Cl 2 ]Cl·CH 3 OH·2H 2 O and [Ir III {C(CHCO 2 Et)(dppm) 2 -κ 4 P , C , C ', P '}(CH 2 CO 2 Et)(CO)]Cl 2 ·2CH 2 Cl 2 ·1.5H 2 O by Schlapp-Hackl, Inge, Falschlunger, Christoph, Zauner, Kathrin, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The common feature of the four iridium(III) salt complexes,…”
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Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodi-phospho-rane iridium inter-mediate: substitution of one phosphine moiety of a carbodi-phospho-rane by an organic azide by Partl, Gabriel Julian, Nussbaumer, Felix, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The structure of [Ir{(4-Cl-C H N )C(dppm)-κ , , }(dppm-κ , ')]Cl·1.5CH Cl ·0.5C H (C H Cl IrN P ·1.5CH Cl ·0.5C H ) ( ), dppm =…”
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Crystal structures of the [Ir III {C(C 4 H 6 O 2 )(dppm)-κ 3 P , C , O }(dppm)H](CF 3 O 3 S) 2 and [Ir III {C(C 4 H 6 O 2 )(dppm)-κ 2 P , C }(CO)(dppm)H](CF 3 O 3 S) 2 phosphorus ylide complexes, generated by a Wittig-type carbon-carbon coupling reaction of a carbodiphospho-rane PCP ligand system by Schlapp-Hackl, Inge, Pauer, Bettina, Falschlunger, Christoph, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The reaction of [Ir {C(dppm) -κ , , '}ClH(NH C )]Cl with ethyl diazo-acetate, a well known C=C coupling reagent, leads to the formation of a C=C unit,…”
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Crystal structures of four new iridium complexes, each containing a highly flexible carbodi-phos-phorane PCP pincer ligand by Partl, Gabriel Julian, Nussbaumer, Felix, Schlapp-Hackl, Inge, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…Compound [Ir(C H )(C H P )]Cl or [Ir(cod)(CH(dppm) -κ , , )]Cl ( ), was obtained from [IrCl(cod)] and the carbodi-phospho-rane (CDP) salt [CH(dppm) ]Cl [where…”
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Synthesis and Structure of the First Heterodinuclear PCP−Pincer−CDP Complex with a Pd−Au d 8 −d 10 Pseudo-Closed-Shell Interaction by Reitsamer, Christian, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

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Syn−Anti Isomerization by Intramolecular Alkene Rotation: Study of the Dynamics of the Bicyclo[2.2.1]hept-2-ene Ligands in a Diplatinum(I) Complex and Its Lewis Acid Adducts by Wachtler, Helmuth, Schuh, Walter, Augner, Sven, Hägele, Gerhard, Wurst, Klaus, Peringer, Paul

“…Intramolecular exchange by alkene rotation observed for the first time in a dinuclear d9-Pt(I) olefin complex was evidenced for…”
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[Hg 2] 2+ coordinated by eight nitrogen donor atoms: Synthesis and structure of [Hg 2(phen) 4](OTf) 2, phen = 1,10-phenanthroline by Malleier, Richard, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul

“…The mercury(I) complex [Hg 2(phen) 4](OTf) 2 exhibits a Hg 2N 8 kernel, which involves the highest number of N-donor atoms coordinated to Hg 2 2 + reported so…”
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Metal "capture" by a heterotrimetalloligand, heterometallic d(10)-d(10) interactions, and unexpected iron-to-platinum silyl ligand migration: a combined experimental and theoretical study by Schuh, Walter, Braunstein, Pierre, Bénard, Marc, Rohmer, Marie-Madeleine, Welter, Richard

“…The heterotrinuclear chain complex Hg[Fe{Si(OMe)(3)}(CO)(3)(dppm-P)](2) (dppm = Ph(2)PCH(2)PPh(2)) 1 which has a transoid arrangement of the phosphine donors…”
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