Search Results - "Schoenitz, Mirko"
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Mechanochemically prepared reactive and energetic materials: a review
Published in Journal of materials science (01-10-2017)“…Reactive and energetic materials are typically metastable and are expected to transform into thermodynamically favorable reaction products with substantial…”
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2
Fluorine-containing oxidizers for metal fuels in energetic formulations
Published in Defence technology (01-02-2019)“…Fluorine containing oxidizers, primarily polymers, are extensively used in pyrotechnic compositions. Fluorinated oxidizers are less explored for metalized…”
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3
Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate, in presence of metal oxides
Published in Defence technology (01-08-2021)“…Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly…”
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4
Oxidation of Magnesium: Implication for Aging and Ignition
Published in Journal of physical chemistry. C (21-01-2016)“…Magnesium is widely used in pyrotechnic formulations; it is also a component of reactive alloys, e.g., AlMg and BMg, which are potential fuels for explosives…”
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5
Rapid destruction of sarin surrogates by gas phase reactions with focus on diisopropyl methylphosphonate (DIMP)
Published in Defence technology (01-06-2021)“…Rapid destruction of stockpiles of sarin and other chemical weapon agents (CWA) requires understanding and quantitative description of the relevant chemical…”
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6
Reaction interface between aluminum and water
Published in International journal of hydrogen energy (01-08-2013)“…Reaction of aluminum with water is of interest for hydrogen generation for a wide range of applications, from in-situ operated fuel cells to propulsion of…”
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7
Effect of polymorphic phase transformations in Al2O3 film on oxidation kinetics of aluminum powders
Published in Combustion and flame (01-03-2005)“…Thermogravimetry was used to study the oxidation of aluminum powders at elevated temperatures. Aluminum powders of various particle sizes and surface…”
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8
Preparation and Characterization of Silicon-Metal Fluoride Reactive Composites
Published in Nanomaterials (Basel, Switzerland) (28-11-2020)“…Fuel-rich composite powders combining elemental Si with the metal fluoride oxidizers BiF and CoF were prepared by arrested reactive milling. Reactivity of the…”
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9
Accelerated intermetallic phase amorphization in a Mg-based high-entropy alloy powder
Published in Journal of magnesium and alloys (01-05-2024)“…•The presence of multiple elements, each with distinct mixing affinities, promotes an accelerated amorphization. The energetic state and atomic size…”
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10
The effect of surface modification of aluminum powder on its flowability, combustion and reactivity
Published in Powder technology (01-12-2010)“…Surface modification of aluminum powders for the purpose of flow improvement was performed and several samples were prepared. Correlations between the…”
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11
Mechanical alloying and reactive milling in a high energy planetary mill
Published in Journal of alloys and compounds (01-06-2009)“…Powder refinement in a planetary mill (Retsch PM 400-MA) is investigated experimentally and analyzed using discrete element modeling (DEM). Refinement is…”
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12
Structure and properties of Al–Mg mechanical alloys
Published in Journal of materials research (01-08-2003)“…Mechanically alloys in the Al–Mg binary system in the range of 5–50 at.% Mg were produced for prospective use as metallic additives for propellants and…”
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13
A study of mechanical alloying processes using reactive milling and discrete element modeling
Published in Acta materialia (01-06-2005)“…The milling progress of mechanical alloying in SPEX shaker mills was investigated using different ball sizes and ball to powder mass ratios (charge ratios)…”
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14
Correlating ignition mechanisms of aluminum-based reactive materials with thermoanalytical measurements
Published in Progress in energy and combustion science (01-10-2015)“…A class of non-detonating materials capable of highly exothermic reactions, referred to as reactive materials (RMs), has been subjected to extensive recent…”
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15
Effect of particle morphology on reactivity, ignition and combustion of boron powders
Published in Fuel (Guildford) (15-09-2022)“…•Spherical boron particles prepared by milling oxidize faster than commercial boron.•Spherical boron particles ignite at a lower temperature than irregularly…”
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16
Method for Studying Survival of Airborne Viable Microorganisms in Combustion Environments: Development and Evaluation
Published in Aerosol and Air Quality Research (01-10-2010)“…Inactivation of airborne microorganisms due to thermal or chemical air treatment has gained considerable attention. Destruction of aerosolized biothreat agents…”
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17
Bismuth fluoride-coated boron powders as enhanced fuels
Published in Combustion and flame (01-11-2020)“…By double displacement reaction in aqueous media, bismuth fluoride, BiF3, was coated onto micron-sized boron particles to target two compositions with 5 and…”
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18
Aluminum in magnesium silicate perovskite: Formation, structure, and energetics of magnesium-rich defect solid solutions
Published in Journal of Geophysical Research - Solid Earth (01-07-2003)“…MgSiO3‐rich perovskite is expected to dominate Earth's lower mantle (pressures >25 GPa) with iron and aluminum as significant substituents. The incorporation…”
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19
Parameters affecting mechanochemical nitration of aromatic precursors
Published in Chemical engineering science (31-12-2021)“…•Mechanochemical nitration extended to a range of aromatic compounds.•Nitration rate depends on combination of physical and chemical properties.•Prominent…”
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20
Effect of reactive B–Ti powder morphology on its removal from a surface and ignition by electro-static discharge
Published in Journal of electrostatics (01-11-2022)“…Blast-powder interaction forms an aerosol, which could ignite, affecting production and distribution of fallout products. Full-scale experiments are…”
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