Search Results - "Schmidt, Johan A"
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A new mechanism for atmospheric mercury redox chemistry: implications for the global mercury budget
Published in Atmospheric chemistry and physics (29-05-2017)“…Mercury (Hg) is emitted to the atmosphere mainly as volatile elemental Hg0. Oxidation to water-soluble HgII plays a major role in Hg deposition to ecosystems…”
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Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem
Published in Atmospheric chemistry and physics (29-09-2016)“…We present a simulation of the global present-day composition of the troposphere which includes the chemistry of halogens (Cl, Br, I). Building on previous…”
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Carbon dioxide photolysis from 150 to 210 nm: Singlet and triplet channel dynamics, UV-spectrum, and isotope effects
Published in Proceedings of the National Academy of Sciences - PNAS (29-10-2013)“…We present a first principles study of the carbon dioxide (CO ₂) photodissociation process in the 150- to 210-nm wavelength range, with emphasis on photolysis…”
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Particulate air pollution in the Copenhagen metro part 2: Low-cost sensors and micro-environment classification
Published in Environment international (01-12-2022)“…[Display omitted] •Particulate matter (PM) levels on the CPH metro are measured with low-cost sensors.•Low-costs sensors perform well, due to stable conditions…”
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Active and widespread halogen chemistry in the tropical and subtropical free troposphere
Published in Proceedings of the National Academy of Sciences - PNAS (28-07-2015)“…Halogens in the troposphere are increasingly recognized as playing an important role for atmospheric chemistry, and possibly climate. Bromine and iodine react…”
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Clumped isotope perturbation in tropospheric nitrous oxide from stratospheric photolysis
Published in Geophysical research letters (16-05-2015)“…Nitrous oxide (N2O) is potent greenhouse gas and source of ozone depleting NO to the stratosphere. Recent advances in mass spectrometry allow accurate…”
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Isotopic constraints on the role of hypohalous acids in sulfate aerosol formation in the remote marine boundary layer
Published in Atmospheric chemistry and physics (14-09-2016)“…Sulfate is an important component of global atmospheric aerosol, and has partially compensated for greenhouse gas-induced warming during the industrial period…”
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SO₂ photoexcitation mechanism links mass-independent sulfur isotopic fractionation in cryospheric sulfate to climate impacting volcanism
Published in Proceedings of the National Academy of Sciences - PNAS (29-10-2013)“…Natural climate variation, such as that caused by volcanoes, is the basis for identifying anthropogenic climate change. However, knowledge of the history of…”
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Recoil Inversion in the Photodissociation of Carbonyl Sulfide near 234 nm
Published in Physical review letters (20-06-2017)“…We report the observation of recoil inversion of the CO (v=0, J_{CO}=66) state in the UV dissociation of lab-frame oriented carbonyl sulfide (OCS). This state…”
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Synthesis of 13C-depleted organic matter from CO in a reducing early Martian atmosphere
Published in Nature geoscience (09-05-2024)“…Organic matter found in early Martian sediment may yield clues to the planet’s environmental conditions, prebiotic chemistry and habitability, but its origin…”
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Halogen chemistry reduces tropospheric O3 radiative forcing
Published in Atmospheric chemistry and physics (15-01-2017)“…Tropospheric ozone (O3) is a global warming gas, but the lack of a firm observational record since the preindustrial period means that estimates of its…”
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Halogen chemistry reduces tropospheric O 3 radiative forcing
Published in Atmospheric chemistry and physics (31-01-2017)“…Tropospheric ozone (O3) is a global warming gas, but the lack of a firm observational record since the preindustrial period means that estimates of its…”
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Clumped isotope effects during OH and Cl oxidation of methane
Published in Geochimica et cosmochimica acta (01-01-2017)Get full text
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Hydrogen shift reactions in four methyl-buten-ol (MBO) peroxy radicals and their impact on the atmosphere
Published in Atmospheric environment (1994) (01-12-2016)“…We investigate the hydrogen shift (H-shift) reactions in the peroxy radicals derived from four different methyl-buten-ol (MBO) molecules; 2-methyl-3-buten-2-ol…”
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On the structure of Si(100) surface: importance of higher order correlations for buckled dimer
Published in The Journal of chemical physics (28-05-2013)“…We revisit a dangling theoretical question of whether the surface reconstruction of the Si(100) surface would energetically favor the symmetric or buckled…”
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Global modeling of tropospheric iodine aerosol
Published in Geophysical research letters (28-09-2016)“…Natural aerosols play a central role in the Earth system. The conversion of dimethyl sulfide to sulfuric acid is the dominant source of oceanic secondary…”
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Isotope Effect in the Carbonyl Sulfide Reaction with O(3 P)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-04-2012)“…The sulfur kinetic isotope effect (KIE) in the reaction of carbonyl sulfide (OCS) with O(3 P) was studied in relative rate experiments at 298 ± 2 K and 955 ±…”
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On the origin of the asymmetric shape of the HCl photodissociation cross section
Published in Chemical physics letters (08-10-2009)“…The photodissociation of HCl from 50 000 cm −1 to 75 000 cm −1. A wave packet evolving on two coupled potential energy curves. A first principles treatment of…”
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Urban vertical air pollution gradient and dynamics investigated with low-cost sensors and large-eddy simulations
Published in Atmospheric environment (1994) (01-01-2024)Get full text
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A three-dimensional model of the atmospheric chemistry of E and Z-CF3CH=CHCl (HCFO-1233(zd) (E/Z))
Published in Atmospheric environment (1994) (01-04-2018)“…Using a 3-dimensional global atmospheric chemistry and transport model we investigated the atmospheric degradation of HCFO-1233zd(E), E-CF3CH=CHCl, a…”
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