Search Results - "Schlick, Shulamith"
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Scavenging of Hydroxyl Radicals by Ceria Nanoparticles: Effect of Particle Size and Concentration
Published in Journal of physical chemistry. C (31-03-2016)“…The most commonly used proton exchange membranes (PEMs) for hydrogen and direct methanol fuel cells are the perfluorosulfonic acid ionomers (PFSA) such as…”
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Cerium(III) as a Stabilizer of Perfluorinated Membranes Used in Fuel Cells: In Situ Detection of Early Events in the ESR Resonator
Published in Macromolecules (24-11-2009)“…We present experiments in an in situ fuel cell (FC) inserted in the resonator of the ESR spectrometer that allowed separate monitoring of radical formation at…”
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Spin Trapping by 5,5-Dimethylpyrroline-N-oxide in Fenton Media in the Presence of Nafion Perfluorinated Membranes: Limitations and Potential
Published in The journal of physical chemistry. B (08-06-2006)“…Spin trapping by 5,5-dimethylpyrroline-N-oxide (DMPO) was used for the detection of radicals in Fenton media in the presence and absence of Nafion…”
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Using Cyclodextrins to Encapsulate Oxygen-Centered and Carbon-Centered Radical Adducts: The Case of DMPO, PBN, and MNP Spin Traps
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (03-06-2010)“…We present electron spin resonance (ESR) experiments that describe the interaction of β-cyclodextrin (β-CD) with spin adducts of three spin traps:…”
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Understanding the fingerprint region in the infra-red spectra of perfluorinated ionomer membranes and corresponding model compounds: Experiments and theoretical calculations
Published in Journal of power sources (15-10-2011)“…[Display omitted] ► We present an ATR-FTIR study of three major perfluorinated ionomers, Nafion, Aquivion and 3M, with focus on the C–O–C band absorptions. ►…”
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In-Depth Profiling of Degradation Processes in a Fuel Cell: 2D Spectral-Spatial FTIR Spectra of Nafion Membranes
Published in ACS macro letters (21-02-2012)“…We present in-depth profiling by micro FTIR of cross sections for Nafion 115 membranes in membrane-electrode assemblies (MEAs) degraded during 52 or 180 h at…”
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Spatial effects in the photodegradation of poly(acrylonitrile-butadiene-styrene): a study by ATR-FTIR
Published in Polymer (Guilford) (01-05-2002)“…Spatial effects in the degradation of polyacrylonitrile-butadiene-styrene (ABS) exposed to ultraviolet radiation and oxygen in a weathering chamber at 318K…”
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Stabilization and Early Degradation of UV-Irradiated Heterophasic Propylene−Ethylene Copolymers Based on ESR, ESR Imaging, UV−Vis, and DSC: Effect of Ethylene Content and UV Wavelength
Published in Macromolecules (09-08-2005)“…Heterophasic propylene−ethylene copolymers (HPEC) containing 1 wt % bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate (Tinuvin 770) as a hindered amine…”
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Hydration in the Various Phases of the Triblock Copolymers EO13PO30EO13 (Pluronic L64) and EO6PO34EO6 (Pluronic L62), Based on Electron Spin Resonance Spectra of Cationic Spin Probes
Published in Macromolecules (03-11-1998)“…Aqueous solutions of the triblock copolymers poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) EO13PO30EO13 (Pluronic L64) and EO6PO34EO6…”
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Nafion Perfluorinated Membranes Treated in Fenton Media: Radical Species Detected by ESR Spectroscopy
Published in The journal of physical chemistry. B (08-04-2004)“…ESR spectroscopy was used to detect and identify radicals in Nafion perfluorinated membranes exposed to the Fenton reagent based on Ti3+ (TiCl3 + H2O2). This…”
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Phase Separation in Sulfonated Poly(ether ether ketone) (SPEEK) Ionomers by Spin Probe ESR: Effect of the Degree of Sulfonation and Water Content
Published in Macromolecules (10-02-2015)“…We present the effect of the degree of sulfonation (DS) and water content on the phase separation in sulfonated poly(ether ether ketone) (SPEEK) ionomers,…”
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Direct ESR detection and spin trapping of radicals generated by reaction of oxygen radicals with sulfonated poly(ether ether ketone) (SPEEK) membranes
Published in Polymer degradation and stability (01-10-2009)“…The stability of membranes under the strong oxidizing conditions in fuel cells is one of the major challenges in the development of fuel cells based on proton…”
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Fragmentation of Perfluorinated Membranes Used in Fuel Cells: Detecting Very Early Events by Selective Encapsulation of Short-Lived Fragments in β-Cyclodextrin
Published in The journal of physical chemistry. B (03-11-2011)“…The fragmentation of perfluorinated ionomeric membranes during fuel cell (FC) operation is studied in our laboratory by direct electron spin resonance (ESR)…”
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Visualizing Chemical Reactions and Crossover Processes in a Fuel Cell Inserted in the ESR Resonator: Detection by Spin Trapping of Oxygen Radicals, Nafion-Derived Fragments, and Hydrogen and Deuterium Atoms
Published in The journal of physical chemistry. B (11-06-2009)“…We present experiments in an in situ fuel cell (FC) inserted in the resonator of the ESR spectrometer that offered the ability to observe separately processes…”
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Measuring Diffusion Coefficients of Nitroxide Radicals in Heterophasic Propylene−Ethylene Copolymers by Electron Spin Resonance Imaging
Published in Macromolecules (25-01-2011)“…Heterophasic propylene-ethylene copolymers (HPECs), also known as impact-modified polypropylene copolymers (IPC), are an important class of materials because…”
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Ranking the Stability of Perfluorinated Membranes Used in Fuel Cells to Attack by Hydroxyl Radicals and the Effect of Ce(III): A Competitive Kinetics Approach Based on Spin Trapping ESR
Published in Macromolecules (13-04-2010)“…The stability of Nafion, stabilized Nafion (StNafion), and 3M and Aquivion membranes to attack by the hydroxyl radical, HO•, was compared in their aqueous…”
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Spatially resolved degradation in heterophasic polymers by ESR imaging and FTIR: The case of propylene-ethylene copolymers
Published in JCT research (2005)“…Heterophasic propylene-ethylene copolymers (HPEC) containing bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate (Tinuvin 770) as a hindered amine stabilizer (HAS)…”
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Electron spin resonance study of chemical reactions and crossover processes in a fuel cell: Effect of membrane thickness
Published in Journal of power sources (01-07-2013)“…Spin trapping ESR experiments were performed in a fuel cell inserted in the resonator of the ESR spectrometer, and allow visualization of crossover processes…”
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