Search Results - "Schley, D."

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation by Schley, Nathan D, Fu, Gregory C

“…Although nickel-catalyzed stereoconvergent couplings of racemic alkyl electrophiles are emerging as a powerful tool in organic chemistry, to date there have…”
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Iridium-Catalyzed sp3 C–H Borylation in Hydrocarbon Solvent Enabled by 2,2′-Dipyridylarylmethane Ligands by Jones, Margaret R, Fast, Caleb D, Schley, Nathan D

“…Iridium-catalyzed alkane C–H borylation has long suffered from poor atom economy, resulting from both the inclusion of only 1 equiv of boron from the diboron…”
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Mechanochemically Driven Transformations in Organotin Chemistry: Stereochemical Rearrangement, Redox Behavior, and Dispersion-Stabilized Complexes by Koby, Ross F, Hanusa, Timothy P, Schley, Nathan D

“…Ball milling a mixture of the bulky allyl K­[A′] {[A′] = [1,3-(SiMe3)2C3H3]−} and SnCl2 in a 2:1 ratio for 5 min leads to the tris­(allyl) stannate [SnA′3K]∞,…”
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Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes by Deng, Min, Mukthar, Nishya F. M., Schley, Nathan D., Ung, Gaël

“…The synthesis of chiral C1‐symmetrical copper(I) complexes supported by chiral carbene ligands is described. These complexes are yellow emitters with modest…”
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Circularly Polarized Luminescence from Enantiopure C2-Symmetrical Tetrakis(2-pyridylmethyl)-1,2-diaminocyclohexane Lanthanide Complexes by Ayers, Kaitlynn M, Schley, Nathan D, Ung, Gaël

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Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes by Schley, Nathan D, Dobereiner, Graham E, Crabtree, Robert H

“…A series of ruthenium complexes can perform the acceptorless dehydrogenation of diols as well as the reaction of amines and alcohols to form ester, lactam, and…”
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Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis by Blakemore, James D, Schley, Nathan D, Balcells, David, Hull, Jonathan F, Olack, Gerard W, Incarvito, Christopher D, Eisenstein, Odile, Brudvig, Gary W, Crabtree, Robert H

“…Iridium half-sandwich complexes of the types Cp*Ir(N−C)X, [Cp*Ir(N−N)X]X, and [CpIr(N−N)X]X are catalyst precursors for the homogeneous oxidation of water to…”
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Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage by Fast, Caleb D, Schley, Nathan D

“…A catalytic, light-promoted hydrosilylative cleavage reaction of alkyl ethers is reported. Initial studies are consistent with a mechanism involving…”
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Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO2‑Capture: Discovery, Development, and Mechanism by Yousefi, Roozbeh, Struble, Thomas J, Payne, Jenna L, Vishe, Mahesh, Schley, Nathan D, Johnston, Jeffrey N

“…Cyclic carbamates are a common feature of small-molecule therapeutics, offering a constrained hydrogen bond acceptor that is both polar and sterically small…”
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Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer-Sphere Pathway by Dobereiner, Graham E, Nova, Ainara, Schley, Nathan D, Hazari, Nilay, Miller, Scott J, Eisenstein, Odile, Crabtree, Robert H

“…A new homogeneous iridium catalyst gives hydrogenation of quinolines under unprecedentedly mild conditionsas low as 1 atm of H2 and 25 °C. We report air- and…”
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Ultrafast photodriven intramolecular electron transfer from an iridium-based water-oxidation catalyst to perylene diimide derivatives by Vagnini, Michael T, Smeigh, Amanda L, Blakemore, James D, Eaton, Samuel W, Schley, Nathan D, D’Souza, Francis, Crabtree, Robert H, Brudvig, Gary W, Co, Dick T, Wasielewski, Michael R

“…Photodriving the activity of water-oxidation catalysts is a critical step toward generating fuel from sunlight. The design of a system with optimal energetics…”
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Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct by Huh, Daniel N, Koby, Ross F, Stuart, Zoe E, Dunscomb, Rachel J, Schley, Nathan D, Tonks, Ian A

“…The complex {(TMEDA) Li}{[Ti(N(TMS) ) ] (μ-η :η -N ) } (5-Li) is the only transition metal N complex ever reported with two side-on N adducts. In this report,…”
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Mechanisms to explain the reverse perivascular transport of solutes out of the brain by Schley, D., Carare-Nnadi, R., Please, C.P., Perry, V.H., Weller, R.O.

“…Experimental studies and observations in the human brain indicate that interstitial fluid and solutes, such as amyloid- β ( A β ) , are eliminated from grey…”
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Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors by Blakemore, James D, Schley, Nathan D, Kushner-Lenhoff, Maxwell N, Winter, Andrew M, D’Souza, Francis, Crabtree, Robert H, Brudvig, Gary W

“…Electrodeposition of iridium oxide layers from soluble precursors provides a route to active thin-layer electrocatalysts for use on water-oxidizing anodes…”
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Characterization of an Amorphous Iridium Water-Oxidation Catalyst Electrodeposited from Organometallic Precursors by Blakemore, James D, Mara, Michael W, Kushner-Lenhoff, Maxwell N, Schley, Nathan D, Konezny, Steven J, Rivalta, Ivan, Negre, Christian F. A, Snoeberger, Robert C, Kokhan, Oleksandr, Huang, Jier, Stickrath, Andrew, Tran, Lan Anh, Parr, Maria L, Chen, Lin X, Tiede, David M, Batista, Victor S, Crabtree, Robert H, Brudvig, Gary W

“…Upon electrochemical oxidation of the precursor complexes [Cp*Ir(H2O)3]SO4 (1) or [(Cp*Ir)2(OH)3]OH (2) (Cp* = pentamethylcyclopentadienyl), a blue layer of…”
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Nutrients and their role in host resistance to infection by Field, Catherine J., Johnson, Ian R., Schley, Patricia D.

“…Almost all nutrients in the diet play a crucial role in maintaining an “optimal” immune response, such that deficient and excessive intakes can have negative…”
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Structure–Activity Relationships for the N‑Me- Versus N‑H-Amide Modification to Macrocyclic ent-Verticilide Antiarrhythmics by Smith, Abigail N., Thorpe, Madelaine P., Blackwell, Daniel J., Batiste, Suzanne M., Hopkins, Corey R., Schley, Nathan D., Knollmann, Bjorn C., Johnston, Jeffrey N.

“…The synthesis of all N-Me and N-H analogues of ent-verticilide is described, enabling a structure–activity relationship study based on cardiac ryanodine…”
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The immune-enhancing effects of dietary fibres and prebiotics by Schley, P. D., Field, C. J.

“…The gastrointestinal tract is subjected to enormous and continual foreign antigenic stimuli from food and microbes. This organ must integrate complex…”
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Protective Measures, Personal Experience, and the Affective Psychology of Time by Peters, E., Kunreuther, H., Sagara, N., Slovic, P., Schley, D. R.

“…We examined the role of time and affect in intentions to purchase a risk‐protective measure (Studies 1 and 2) and explored participant abilities to factor time…”
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Mechanisms of omega-3 fatty acid-induced growth inhibition in MDA-MB-231 human breast cancer cells by SCHLEY, Patricia D, JIJON, Humberto B, ROBINSON, Lindsay E, FIELD, Catherine J

“…The omega-3 fatty acids, eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), inhibit the growth of human breast cancer cells in animal models and cell…”
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