Search Results - "Schlegel, M.L."
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Crystal chemistry of trace elements in natural and synthetic goethite
Published in Geochimica et cosmochimica acta (01-11-2000)“…The crystal chemistry of Cr (0.73%), Mn (0.88%), Co (0.166%), Ni (0.898%), Cu (0.263%), and Zn (0.026%) in natural goethite (αFeOOH) from an earthy saprolite…”
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Mobility of selenium oxyanions in clay-rich media: A combined batch and diffusion experiments and synchrotron-based spectroscopic investigation
Published in Applied geochemistry (01-05-2021)“…Selenium-79 is considered as a critical radionuclide in safety assessment of high-level radioactive waste deep geological repository in clay-rich formations,…”
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Anticorrosion performance of a Zr-based architectured substrate/coating system
Published in Corrosion science (01-08-2023)“…After Zr+ HiPIMS etching, four Zr-based substrate/coating systems were synthesized on 304L stainless steel by hybrid pulsed DCMS/HiPIMS. SEM-BSE images showed…”
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Structural and optical changes in silica-based optical fibers exposed to high neutron and gamma fluences
Published in Journal of non-crystalline solids (15-12-2021)“…•Raman spectroscopy on compacted optical fiber induced by high neutron fluence.•The densification process is uniform along the whole fiber transverse…”
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Corrosion of carbon steel in clay compact environments at 90 °C: Effect of confined conditions
Published in Corrosion science (15-05-2021)“…•Carbon steel anoxic corrosion in simulated crevice hindered by confined conditions.•Heterogeneous corrosion in microcontainer due to gradual…”
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On the role of Fe(III) ions on the reduction mechanisms of concentrated nitric acid
Published in Electrochimica acta (01-03-2020)“…The reduction mechanism of concentrated HNO3 (4 mol L−1) was investigated on a gold electrode at 40 °C by coupling electrochemical methods (cyclic voltammetry,…”
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Uptake of uranium and trace elements in pyrite (FeS 2) suspensions
Published in Geochimica et cosmochimica acta (01-03-2010)“…Pyrite dissolution and interaction with Fe (II), Co (II), Eu (III) and U (VI) have been studied under anoxic conditions by solution chemistry and spectroscopic…”
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Corrosion at the carbon steel-clay compact interface at 90°C: Insight into short- and long-term corrosion aspects
Published in Corrosion science (15-05-2019)“…•Carbon steel was corroded in contact with anoxic clay at 90 °C.•Corrosion damage equaled 8.5 and 29.5 μm at 7 and 76 months, respectively.•Heterogeneous…”
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Cation sorption on the muscovite (0 0 1) surface in chloride solutions using high-resolution X-ray reflectivity
Published in Geochimica et cosmochimica acta (15-07-2006)“…The structure and mechanism of cation sorption at the (0 0 1) muscovite-water interface were investigated in 0.01 and 0.5 m KCl, CsCl, and CaCl 2 and 0.01 m…”
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Carbon steel corrosion in clay-rich environment
Published in Corrosion science (01-11-2014)“…•We studied the steel corrosion under CO2 in clay-rich environment.•The steel corrosion under CO2 leads to a complex mineralogical paragenesis.•Under CO2, the…”
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Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones (Meuse/Haute–Marne, France)
Published in Applied geochemistry (01-04-2008)“…Diffusive parameters of tritiated water (HTO) and several anionic tracers ( 36Cl −, 125I −, 35 SO 4 2 - and 75 SeO 3 2 - ) were determined in the…”
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Corrosion of iron and low alloyed steel within a water saturated brick of clay under anaerobic deep geological disposal conditions: An integrated experiment
Published in Journal of nuclear materials (30-09-2008)“…The aim of this study was to determine the corrosion behaviour of iron and low alloyed steels under simulated geological disposal conditions, related to…”
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In situ grazing-incidence X-ray diffraction during electrodeposition of birnessite thin films: Identification of solid precursors
Published in Electrochemistry communications (01-05-2011)“…A special electrochemical flow-cell allowing in situ grazing-incidence X-ray diffraction during electrodeposition of thin films has been successfully…”
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Behavior of Heptavalent Technetium in Sulfuric Acid under a-Irradiation: Structural Determination of Technetium Sulfate Complexes by X-ray Absorption Spectroscopy and First Principles Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (2014)Get full text
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Mechanism of Europium Retention by Calcium Silicate Hydrates: An EXAFS Study
Published in Environmental science & technology (15-08-2004)“…The uptake of Eu by calcium silicate hydrate (C−S−H) phases as a function of Eu/sorbate ratio (from 37 to 450 μmol g-1 C−S−H), C−S−H Ca/Si mole ratio (1.3,…”
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Chlorine speciation in nuclear graphite studied by X-ray Absorption Near Edge Structure
Published in Journal of nuclear materials (01-11-2011)“…► A first XANES study of chlorine speciation in virgin nuclear graphite. ► Chlorine is covalently bound to carbon atom, with a valence equal to (−I). ►…”
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Sorption of metal ions on clay minerals. 2: Mechanism of Co sorption on hectorite at high and low ionic strength and impact on the sorbent stability
Published in Journal of colloid and interface science (15-12-1999)“…The mechanism of Co uptake from aqueous solution onto hectorite (a magnesian smectite) and its impact on the stability of this clay mineral were investigated…”
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Natural speciation of Mn, Ni and Zn at the micrometer scale in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction
Published in Geochimica et cosmochimica acta (15-01-2007)“…The natural speciation of Mn (0.19 g/kg), Ni (46 mg/kg), and Zn (42 mg/kg) in the argillic horizon (120 cm depth, pH = 5.6) of an Ultisol from a paddy soil in…”
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Suppressive effects of dehydroepiandrosterone and 3-beta-methylandrost-5-en-17-one on attack towards lactating female intruders by castrated male mice
Published in Physiology & behavior (01-12-1989)“…Three experiments were performed. In Experiment I, triads of adult castrated male mice were chronically administered with either oil-vehicle or 80…”
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