Search Results - "Schelter, Eric J."

Rare earth elements: Mendeleev's bane, modern marvels by Cheisson, Thibault, Schelter, Eric J

“…The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical similarities as a group, while individually expressing distinctive and…”
Get full text

Photoinduced Miyaura Borylation by a Rare‐Earth‐Metal Photoreductant: The Hexachlorocerate(III) Anion by Qiao, Yusen, Yang, Qiaomu, Schelter, Eric J.

“…The first photoinduced carbon(sp2)–heteroatom bond forming reaction by a rare‐earth‐metal photoreductant, a Miyaura borylation, has been achieved. This simple,…”
Get full text

Photocatalytic C-H activation and the subtle role of chlorine radical complexation in reactivity by Yang, Qiaomu, Wang, Yu-Heng, Qiao, Yusen, Gau, Michael, Carroll, Patrick J, Walsh, Patrick J, Schelter, Eric J

“…The functionalization of methane, ethane, and other alkanes derived from fossil fuels is a central goal in the chemical enterprise. Recently, a photocatalytic…”
Get full text

Sustainable Inorganic Chemistry: Metal Separations for Recycling by Nelson, Joshua J. M, Schelter, Eric J

“…Inorganic materials are critical components of clean energy technology. For example, rare earths are key for the function of electric car batteries and in…”
Get full text

Cerium Photosensitizers: Structure–Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions by Yin, Haolin, Carroll, Patrick J, Manor, Brian C, Anna, Jessica M, Schelter, Eric J

“…Two complete mixed-ligand series of luminescent CeIII complexes with the general formulas [(Me3Si)2NC­(N i Pr)2] x CeIII[N­(SiMe3)2]3–x (x = 0, 1-N; x = 1,…”
Get full text

Functional Synthetic Model for the Lanthanide-Dependent Quinoid Alcohol Dehydrogenase Active Site by McSkimming, Alex, Cheisson, Thibault, Carroll, Patrick J., Schelter, Eric J.

“…The oxidation of methanol by dehydrogenase enzymes is an essential part of the bacterial methane metabolism cycle. The recent discovery of a lanthanide (Ln)…”
Get full text

Uranyl Functionalization Mediated by Redox-Active Ligands: Generation of O–C Bonds via Acylation by Coughlin, Ezra J, Qiao, Yusen, Lapsheva, Ekaterina, Zeller, Matthias, Schelter, Eric J, Bart, Suzanne C

“…A series of uranyl compounds with the redox-active iminoquinone ligand have been synthesized, and their electronic structures elucidated using multinuclear…”
Get full text

An Operationally Simple Method for Separating the Rare-Earth Elements Neodymium and Dysprosium by Bogart, Justin A., Lippincott, Connor A., Carroll, Patrick J., Schelter, Eric J.

“…Rare‐earth metals are critical components of electronic materials and permanent magnets. Recycling of consumer materials is a promising new source of rare…”
Get full text

The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides by Yin, Haolin, Jin, Yi, Hertzog, Jerald E, Mullane, Kimberly C, Carroll, Patrick J, Manor, Brian C, Anna, Jessica M, Schelter, Eric J

“…The hexachlorocerate­(III) anion, [CeIIICl6]3–, was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction…”
Get full text

DFT Study of the Active Site of the XoxF-Type Natural, Cerium-Dependent Methanol Dehydrogenase Enzyme by Bogart, Justin A., Lewis, Andrew J., Schelter, Eric J.

“…Rare‐earth metal cations have recently been demonstrated to be essential co‐factors for the growth of the methanotrophic bacterium Methylacidiphilum…”
Get full text

A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination by Hirscher, Nathanael A, Ohri, Nidhi, Yang, Qiaomu, Zhou, Jiawang, Anna, Jessica M, Schelter, Eric J, Goldberg, Karen I

“…Halogenation is an important alkane functionalization strategy, but O is widely considered the most desirable terminal oxidant. Here, the aerobic iodination of…”
Get full text

Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift by Panetti, Grace B., Sergentu, Dumitru-Claudiu, Gau, Michael R., Carroll, Patrick J., Autschbach, Jochen, Walsh, Patrick J., Schelter, Eric J.

“…The synthesis of bona fide organometallic Ce IV complexes is a formidable challenge given the typically oxidizing properties of the Ce IV cation and reducing…”
Get full text

NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides by Zhang, Jiadi, Bellomo, Ana, Trongsiriwat, Nisalak, Jia, Tiezheng, Carroll, Patrick J, Dreher, Spencer D, Tudge, Matthew T, Yin, Haolin, Robinson, Jerome R, Schelter, Eric J, Walsh, Patrick J

“…Although the past 15 years have witnessed the development of sterically bulky and electron-rich alkylphosphine ligands for palladium-catalyzed cross-couplings…”
Get full text

Understanding and Controlling the Emission Brightness and Color of Molecular Cerium Luminophores by Qiao, Yusen, Sergentu, Dumitru-Claudiu, Yin, Haolin, Zabula, Alexander V, Cheisson, Thibault, McSkimming, Alex, Manor, Brian C, Carroll, Patrick J, Anna, Jessica M, Autschbach, Jochen, Schelter, Eric J

“…Molecular cerium complexes are a new class of tunable and energy-efficient visible- and UV-luminophores. Understanding and controlling the emission brightness…”
Get full text

Harnessing redox activity for the formation of uranium tris(imido) compounds by Anderson, Nickolas H., Odoh, Samuel O., Yao, Yiyi, Williams, Ursula J., Schaefer, Brian A., Kiernicki, John J., Lewis, Andrew J., Goshert, Mitchell D., Fanwick, Phillip E., Schelter, Eric J., Walensky, Justin R., Gagliardi, Laura, Bart, Suzanne C.

“…Classically, late transition-metal organometallic compounds promote multielectron processes solely through the change in oxidation state of the metal centre…”
Get full text

Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions by Panetti, Grace B, Carroll, Patrick J, Gau, Michael R, Manor, Brian C, Schelter, Eric J, Walsh, Patrick J

“…The super electron donor (SED) ability of 2-azaallyl anions has recently been discovered and applied to diverse reactivity, including transition metal-free…”
Get full text

The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry by Robinson, Jerome R., Carroll, Patrick J., Walsh, Patrick J., Schelter, Eric J.

“…Let's get cerium: The role of ligand organization in the redox chemistry of CeIII was investigated with a series of cerium(III)/alkali metal/1,1′‐binolate…”
Get full text

Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework by Bogart, Justin A., Lippincott, Connor A., Carroll, Patrick J., Booth, Corwin H., Schelter, Eric J.

“…Ligand reorganization has been shown to have a profound effect on the outcome of cerium redox chemistry. Through the use of a tethered, tripodal, trianionic…”
Get full text

Mediating Photochemical Reaction Rates at Lewis Acidic Rare Earths by Selective Energy Loss to 4f-Electron States by Ruoff, Kevin P., Gish, Melissa K., Song, Ellen, Douair, Iskander, Pandey, Pragati, Steger, Mark, Johnson, Justin C., Carroll, Patrick J., Gau, Michael, Chang, Christopher H., Larsen, Ross E., Ferguson, Andrew J., Schelter, Eric J.

“…Manifesting chemical differences in individual rare earth (RE) element complexes is challenging due to the similar sizes of the tripositive cations and the…”
Get full text

Lanthanide Photocatalysis by Qiao, Yusen, Schelter, Eric J

“…Conspectus The use of earth-abundant, cheap, potent, and readily available lanthanide photocatalysts provides an opportunity to complement or even replace rare…”
Get full text