Search Results - "Schalley, Christoph A"
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Multivalency as a Chemical Organization and Action Principle
Published in Angewandte Chemie International Edition (15-10-2012)“…Multivalent interactions can be applied universally for a targeted strengthening of an interaction between different interfaces or molecules. The binding…”
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Tetrathiafulvalene - a redox-switchable building block to control motion in mechanically interlocked molecules
Published in Beilstein journal of organic chemistry (20-08-2018)“…With the rise of artificial molecular machines, control of motion on the nanoscale has become a major contemporary research challenge. Tetrathiafulvalenes…”
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3
Gas-Phase Structural Analysis of Supramolecular Assemblies
Published in Accounts of chemical research (18-05-2021)“…Conspectus Ion mobility spectrometry and gas-phase IR action spectroscopy are two structure-sensitive mass-spectrometric methods becoming more popular…”
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Integrative self-sorting is a programming language for high level self-assembly
Published in Proceedings of the National Academy of Sciences - PNAS (30-06-2009)“…Starting from the basis of a simple 4-component self-sorting system of crown ethers and ammonium ions, we design 6 building blocks in which 2 identical or…”
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5
[N⋅⋅⋅I+⋅⋅⋅N] Halogen-Bonded Dimeric Capsules from Tetrakis(3-pyridyl)ethylene Cavitands
Published in Angewandte Chemie International Edition (02-11-2016)“…Two [N⋅⋅⋅I+⋅⋅⋅N] halogen‐bonded dimeric capsules using tetrakis(3‐pyridyl)ethylene cavitands with different lower rim alkyl chains are synthesized and analyzed…”
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Halogen‐Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase
Published in Angewandte Chemie International Edition (19-01-2017)“…Supramolecular capsules were assembled by neutral halogen bonding (XB) and studied in the solid state, in solution, and in the gas phase. The geometry of the…”
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Electrochemically switchable rotaxanes: recent strides in new directions
Published in Chemical science (Cambridge) (14-11-2019)“…Are they still electrifying? Electrochemically switchable rotaxanes are well known for their ability to efficiently undergo changes of (co-)conformation and…”
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Monitoring Self-Sorting by Electrospray Ionization Mass Spectrometry: Formation Intermediates and Error-Correction during the Self-Assembly of Multiply Threaded Pseudorotaxanes
Published in Journal of the American Chemical Society (24-02-2010)“…Three binary pseudorotaxanes, which are based on two different secondary ammonium/crown ether binding motifs, have been studied by 1H NMR and 1H,1H EXSY NMR…”
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Supramolecular Polymers as Surface Coatings: Rapid Fabrication of Healable Superhydrophobic and Slippery Surfaces
Published in Advanced materials (Weinheim) (19-11-2014)“…Supramolecular polymerization for non‐wetting surface coatings is described. The self‐assembly of low‐molecular‐weight gelators (LMWGs) with perfluorinated…”
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Supramolecular reactivity in the gas phase: investigating the intrinsic properties of non-covalent complexes
Published in Chemical Society reviews (21-03-2014)“…The high vacuum inside a mass spectrometer offers unique conditions to broaden our view on the reactivity of supramolecules. Because dynamic exchange processes…”
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Interfaces with Fluorinated Amphiphiles: Superstructures and Microfluidics
Published in Angewandte Chemie International Edition (13-03-2023)“…This Minireview discusses recent developments in research on the interfacial phenomena of fluorinated amphiphiles, with a focus on applications that exploit…”
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12
Chiroptical inversion of a planar chiral redox-switchable rotaxane
Published in Chemical science (Cambridge) (21-11-2019)“…A tetrathiafulvalene (TTF)-containing crown ether macrocycle with C s symmetry was designed to implement planar chirality into a redox-active [2]rotaxane. The…”
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13
Imine-based [2]catenanes in water
Published in Chemical science (Cambridge) (2018)“…We report the efficient condensation of imine-based macrocycles from dialdehyde and aliphatic diamines in pure water. Within the libraries, we identified a…”
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Integrative Self-Sorting: Construction of a Cascade-Stoppered Hetero[3]rotaxane
Published in Journal of the American Chemical Society (22-10-2008)“…In this Communication, a competing self-sorting system containing benzo-21-crown-7, dibenzo-24-crown-8 and two secondary ammonium salts is constructed, which…”
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The Interplay of Weakly Coordinating Anions and the Mechanical Bond: A Systematic Study of the Explicit Influence of Counterions on the Properties of (Pseudo)rotaxanes
Published in Molecules (Basel, Switzerland) (30-03-2023)“…Weakly coordinating anions (WCAs) have attracted much attention in recent years due to their ability to stabilise highly reactive cations. It may well be…”
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Accordion‐Like Motion in Electrochemically Switchable Crown Ether/Ammonium Oligorotaxanes
Published in Angewandte Chemie International Edition (11-03-2019)“…Reversible oxidation reactions in electrochemically switchable oligorotaxanes with tetrathiafulvalene (TTF) decorated 24‐crown‐8 ether wheels generate…”
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Multivalent Crown Ether Receptors Enable Allosteric Regulation of Anion Exchange in an Fe4L6 Tetrahedron
Published in Angewandte Chemie International Edition (22-10-2018)“…We report a strategy for regulating the rate of internally bound anion exchange within an Fe4L6 metal–organic tetrahedron through external coordination of…”
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Structural water as an essential comonomer in supramolecular polymerization
Published in Science advances (01-11-2017)“…Although the concept of structural water that is bound inside hydrophobic pockets and helps to stabilize protein structures is well established, water has…”
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Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions
Published in Journal of the American Chemical Society (22-11-2017)“…London dispersion forces are the weakest interactions between molecules. Because of this, their influence on chemical processes is often low, but can…”
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A Divalent Pentastable Redox‐Switchable Donor–Acceptor Rotaxane
Published in Chemistry : a European journal (24-02-2017)“…Donor–acceptor materials with small HOMO–LUMO gaps are important in molecular electronics, but are often difficult to synthesise. A simple and efficient way to…”
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