Search Results - "Schaller, R.F."
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Spatially resolved mapping of the relative concentration of dissolved hydrogen using the scanning electrochemical microscope
Published in Electrochemistry communications (01-02-2015)“…The scanning electrochemical microscope (SECM) was utilized to detect pre-dissolved hydrogen across an ultra-high strength stainless steel surface. A high…”
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Use of in situ Raman spectroelectrochemical technique to explore atmospheric corrosion in marine-relevant environments
Published in Electrochemistry communications (01-09-2020)“…[Display omitted] •In-situ Raman for simulated atmospheric environments.•Boundary layer control in Raman cell.•Solution regeneration needed to prevent oxygen…”
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A Review of the Governing Factors in Pit-to-Crack Transitions of Metallic Structures
Published in Corrosion (Houston, Tex.) (01-01-2023)“…Through a combination of mechanical stresses and corrosive environments, a material’s performance may be hindered by the complex evolution of damage due to…”
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Spatial determination of diffusible hydrogen concentrations proximate to pits in a Fe–Cr–Ni–Mo steel using the Scanning Kelvin Probe
Published in Electrochemistry communications (01-02-2016)“…The diffusible hydrogen concentration (CH,diff) was mapped spatially, proximate to acidic corrosion pits formed in MgCl2 droplets, on an ultra-high strength…”
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Insights from electrochemical crack tip modeling of atmospheric stress corrosion cracking
Published in Corrosion science (01-12-2022)“…Crack tip electrochemical conditions are explored utilizing a reactive transport Finite Element Method model for stainless steel 304 exposed to 3 M NaCl. Under…”
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Critical pitting temperature of selective laser melted 316L stainless steel: A mechanistic approach
Published in Corrosion science (01-06-2021)“…•The CPT of wrought and SLM 316 L stainless steel in 1.0 M NaCl was measured.•A higher CPT value (> 10 °C) was found for the SLM alloy compared to wrought…”
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Towards understanding stress corrosion cracking of austenitic stainless steels exposed to realistic sea salt brines
Published in Corrosion science (15-05-2024)“…Stress corrosion cracking behavior of stainless steel 304 L was investigated in full immersion, evaporated artificial sea salt brines (ASW) at 55 °C. It was…”
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Measurement of effective hydrogen diffusivity using the Scanning Kelvin Probe
Published in Electrochemistry communications (01-03-2014)“…Effective hydrogen diffusivity (DH,eff) was determined utilizing the Scanning Kelvin Probe (SKP) to measure the SKP voltage on cross-sectioned, hydrogen…”
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Physical and chemical properties of sea salt deliquescent brines as a function of temperature and relative humidity
Published in The Science of the total environment (10-06-2022)“…Thermodynamic modeling has been used to predict chemical compositions of brines formed by the deliquescence of sea salt aerosols. Representative brines have…”
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Quantitative assessment of environmental phenomena on maximum pit size predictions in marine environments
Published in Electrochimica acta (20-02-2021)“…•Atmospheric maximum pit size predictions for NaCl, MgCl2, and seawater solutions.•Max pit size decrease with cathode precipitation and dehydration…”
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Importance of the hydrogen evolution reaction in magnesium chloride solutions on stainless steel
Published in Corrosion science (01-12-2020)“…•Cathodic kinetics on platinum and stainless steel 304 L in magnesium chloride.•Oxygen reduction reaction suppression on stainless steel 304 L.•Hydrogen…”
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Correlation of Stainless Steel Pit Morphology to Humidity-Specific Sea Salt Brine Constituents
Published in Corrosion (Houston, Tex.) (01-03-2023)“…Immersion exposures of 304 stainless steel ground to a #4 finish were conducted in brines representative of the chemistry of sea salt aerosols at low (40%) and…”
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Considerations for realistic atmospheric environments: An application to corrosion testing
Published in The Science of the total environment (10-08-2023)“…Measured salt compositions in dust collected over roughly the last decade from surfaces of in-service stainless-steel alloys at four locations around the…”
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