Search Results - "Schürmann, Markus"
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Highly enantioselective synthesis and cellular evaluation of spirooxindoles inspired by natural products
Published in Nature chemistry (01-09-2010)“…In biology-oriented synthesis the underlying scaffold classes of natural products selected in evolution are used to define biologically relevant starting…”
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2
Branching Cascades: A Concise Synthetic Strategy Targeting Diverse and Complex Molecular Frameworks
Published in Angewandte Chemie International Edition (18-07-2011)“…Touch 'n' transform: A synthetic strategy based on cascade or domino reaction sequences enabled the simultaneous incorporation of skeletal diversity and…”
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3
Natural product–inspired cascade synthesis yields modulators of centrosome integrity
Published in Nature chemical biology (25-12-2011)“…Natural product–inspired compounds are primed to interact with and manipulate biological processes, but obtaining these complex molecules poses synthetic…”
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4
Stereoselective Cascade Double-Annulations Provide Diversely Ring-Fused Tetracyclic Benzopyrones
Published in Organic letters (07-12-2012)“…A cascade double-annulation strategy employing diverse pairs of zwitterions with 3-formylchromones is presented that provides stereoselective access to complex…”
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5
Chromium Pentacarbonyl-Substituted Organotin(II) Cation Stabilized by p‑Dimethylaminopyridine or Triphenylphosphane Oxide
Published in Organometallics (22-04-2013)“…The syntheses of the heteroleptic organostannylene chromium pentacarbonyl complexes [4-t-Bu-2,6-{P(O)(Oi-Pr)2}2C6H2(X)SnCr(CO)5] (2, X = ClO4; 3, X = OTf) and…”
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6
Enantioselective synthesis of the spirotryprostatin A scaffold
Published in Tetrahedron (30-12-2011)“…The pentacyclic spirotryprostatin scaffold embodies an oxindole with an all-carbon quaternary stereocenter. The scaffold can efficiently be accessed in a…”
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7
Bismuth−Arene π-Interaction: A Combined Experimental and Theoretical Approach
Published in Organometallics (28-09-2009)“…The triorgano bismuth compound [Bi(CH2C6H4Cl-2)3]2 (2) was characterized by an X-ray single-crystal structure analysis, which reveals the formation of a…”
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8
Biology-oriented synthesis of a natural-product inspired oxepane collection yields a small-molecule activator of the Wnt-pathway
Published in Proceedings of the National Academy of Sciences - PNAS (26-04-2011)“…In Biology Oriented Synthesis the scaffolds of biologically relevant compound classes inspire the synthesis of focused compound collections enriched in…”
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9
From Pseudo-octahedral to Pseudo-trigonal Bipyramidal Configuration: Syntheses and Molecular Structures of 4-t-Bu-2,6-[(EtO)2P(O)]2C6H2BiCl2 and [1(Bi),3(P)-Bi(Cl)OP(O)(OEt)-5-t-Bu-7-P(O)(OEt)2]C6H2
Published in Organometallics (10-10-2011)“…The syntheses and molecular structures in solution and in the solid state of the intramolecularly coordinated organobismuth derivatives…”
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Syntheses and Molecular Structures of [RSn{W(CO)3Cp}2][W(CO)3Cp], [RSn{W(CO)3Cp}Cl2], and [RSn{W(CO)3Cp}Cr(CO)5] (R = [4‑t‑Bu-2,6-{P(O)(OR′)2}2C6H2], R′ = Et, i‑Pr). Autoionization Induced by Intramolecular PO→Sn Coordination
Published in Organometallics (08-09-2014)“…The syntheses of the intramolecularly coordinated organotin-substituted transition metal complexes [RSn{W(CO)3Cp}2][W(CO)3Cp] (2, R =…”
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Organotin-Substituted [13]-Crown-4 Ethers: Ditopic Receptors for Lithium and Cesium Halides
Published in Organometallics (08-11-2010)“…The synthesis of the organotin- and the bis(organostannyl)methane-substituted crown ethers Ph(3−n)X n SnCH2-[13]-crown-4 (1, n = 0; 2, n = 1, X = I; 3, n = 1,…”
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12
Synthesis of the B-seco limonoid scaffold
Published in Chemical communications (Cambridge, England) (21-06-2011)“…The underlying stereochemically complex and densely functionalized scaffold of the B-seco limonoids was synthesized employing an Ireland-Claisen rearrangement…”
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13
Regioselective De Novo Synthesis of Cyanohydroxypyridines with a Concerted Cycloaddition Mechanism
Published in Journal of the American Chemical Society (08-10-2008)“…An efficient cycloaddition reaction of 1-alkoxy-1-azadienes with α,α-dicyanoalkenes is described, which gives facile access to highly substituted…”
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14
Palladium and Molybdenum Complexes of the Heteroleptic Organostannylene [2,6-(Me2NCH2)2C6H3]SnCl
Published in Organometallics (24-08-2009)“…The synthesis and molecular structures are reported for the transition metal heteroleptic organostannylene complexes {[2,6-(Me2NCH2)2C6H3]SnCl}(C5H5)(CO)2MoCl…”
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15
Synthesis and Complexation Properties of Allenic Bipyridines, a New Class of Axially Chiral Ligands for Transition Metal Catalysis
Published in European Journal of Inorganic Chemistry (01-02-2008)“…The allenic bipyridines 3, which represent a new class of axially chiral ligands for transition metal catalysis, were synthesized and their complexation…”
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16
tert-Butylphosphonic Acid: From the Bulk to the Gas Phase
Published in Chemistry : a European journal (17-02-2003)“…The structure of tert‐butylphosphonic acid in the solid, in solution, and in the gas phase was studied by single‐crystal X‐ray diffraction, 1H and 31P NMR…”
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17
The First Examples of a Crown Ether Intramolecularly Encapsulating Mono- and Diorganotin Dications: Synthesis and Structures of [PhSnCH2([16]crown-5)][ClO4]2 and [HOSnCH2([16]crown-5)][Y]2 (Y=ClO4, CF3SO3)
Published in Chemistry : a European journal (19-07-2010)“…The reaction of silver perchlorate with [PhI2SnCH2([16]crown‐5)] (1) and [I3SnCH2([16]crown‐5)] (2) gave the organotin(IV)‐substituted crown ether complexes…”
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18
Arylphosphonic acid esters as bridging ligands in coordination polymers of bismuth
Published in Main group metal chemistry (01-12-2013)“…The reaction of the arylphosphonic acid esters 4,4′-[(i-PrO)2P(O)]C6H4C6H4[P(O)(Oi-Pr)2] (L1), 1,3,5-[(i-PrO)2P(O)]3C6H3 (L2), and…”
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19
Synthesis, Structure, and Reactivity of Novel Intramolecularly Coordinated Organolead(II) Compounds
Published in European journal of inorganic chemistry (01-10-2003)“…The intramolecularly coordinated heteroleptic organolead(II) compounds {4‐tBu‐2,6‐[P(O)(OEt)2]2C6H2}PbX (2, X = Cl; 3, X = SPh) have been synthesized…”
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Synthesis and Structure of 1,3,5-Tris(diorganohydroxysilyl)benzenes. Novel Building Blocks in Supramolecular Silanol Chemistry
Published in Organometallics (27-09-2004)“…The 1,3,5-tris(diorganohydroxysilyl)benzenes 1,3,5-(HOR2Si)3C6H3 (TMSB, R = Me; TPSB, R = Ph) have been prepared and fully characterized by X-ray…”
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