Search Results - "Santos Reboucas, Julio"
-
1
Manganese porphyrins immobilized on magnetic SBA-15 mesoporous silica as selective and efficient catalysts for cyclic and linear alkane oxidation
Published in Microporous and mesoporous materials (15-07-2018)“…This work describes the immobilization of neutral and cationic Mn porphyrins (MnP) on magnetic SBA-15 mesoporous silica. XRD patterns, TEM images and N2…”
Get full text
Journal Article -
2
Carbamazepine oxidation catalyzed by manganese porphyrins: Effects of the β-bromination of the macrocycle and the choice of oxidant
Published in Applied catalysis. A, General (28-11-2011)“…[Display omitted] ► Mn-porphyrins can be used as cytochrome P450 models for carbamazepine oxidation. ► Extension of porphyrin β-bromination affects the…”
Get full text
Journal Article -
3
High selectivity toward cyclohexanol in oxidation of cyclohexane using manganese aminophenylporphyrins as catalysts
Published in Applied catalysis. A, General (30-06-2011)“…[Display omitted] ► Mn(III) aminophenylporphyrins catalyze selectively the cyclohexane oxidation. ► There is an exclusive formation of Cy-ol in these…”
Get full text
Journal Article -
4
Metalloporphyrin/ZnO solids as selective catalysts for oxidation reaction assisted by light
Published in Applied catalysis. A, General (25-07-2023)“…Cationic manganese (MnP - [Mn(T4MPyP)]5+) and anionic iron (FeP - [Fe(TDFSPP)]3–) metalloporphyrins in conjunction with zinc oxide of different morphologies,…”
Get full text
Journal Article -
5
Cyclohexane hydroxylation by iodosylbenzene and iodobenzene diacetate catalyzed by a new β-octahalogenated Mn–porphyrin complex: The effect of meso-3-pyridyl substituents
Published in Journal of molecular catalysis. A, Chemical (02-04-2007)“…The Mn(II)Br 8T3PyP complex, a new β-octabrominated derivative of Mn(III)T3PyPCl, exhibits unexpected catalytic and electrochemical properties, which are in…”
Get full text
Journal Article -
6
Mn porphyrins immobilized on non-modified and chloropropyl-functionalized mesoporous silica SBA-15 as catalysts for cyclohexane oxidation
Published in Applied catalysis. A, General (25-09-2016)“…[Display omitted] •Immobilization of manganese(III) porphyrin on mesoporous silica via electrostatic or covalent bond.•Water as solvent to immobilization of…”
Get full text
Journal Article -
7
Hydrogen peroxide in seahorse aquaculture: Determining safe exposure levels using non-invasive biomarkers of stress
Published in Aquaculture (15-02-2023)“…Hydrogen peroxide (H2O2) is widely used in aquaculture to prevent and control fish mortality often associated with fungal, bacterial, and parasitic infections…”
Get full text
Journal Article -
8
Effect of imidazole on biomimetic cyclohexane oxidation by first-, second-, and third-generation manganese porphyrins using PhIO and PhI(OAc)2 as oxidants
Published in Applied catalysis. A, General (05-02-2015)“…•Study of the axial coordination equilibrium between imidazole and Mn-porphyrins.•Stability of the third-generation catalysts toward oxidative destruction by…”
Get full text
Journal Article -
9
Unexpected Products of Benzylamine Oxidation Catalyzed by Manganese Porphyrins: Some Factors that Play a Critical Role for Imine Formation
Published in ChemistrySelect (Weinheim) (29-03-2019)“…This work describes the oxidation of benzylamine by PhIO, catalyzed by a series of first‐row metal salts and the respective first‐, second‐, and…”
Get full text
Journal Article -
10
Magnetic HMS silica as a Support to Immobilization of Catalysts Based on Cationic Manganese Porphyrins
Published in ChemistrySelect (Weinheim) (02-05-2017)“…The immobilization of cationic manganese porphyrins (MnP) over the surface of a magnetic hexagonal HMS silica (HMS‐Mag) produced a solid with high surface area…”
Get full text
Journal Article -
11
Manganese porphyrin-based treatment improves fetal-placental development and protects against oxidative damage and NLRP3 inflammasome activation in a rat maternal hypothyroidism model
Published in Redox biology (01-08-2024)“…Oxidative stress (OS) and endoplasmic reticulum stress (ERS) are at the genesis of placental disorders observed in preeclampsia, intrauterine growth…”
Get full text
Journal Article -
12
Degradation of Dyes Catalyzed by Aminophenyl-Substituted Mn-Porphyrin Immobilized on Chloropropyl Silica Gel and Evaluation of Phytotoxicity
Published in ACS omega (09-07-2024)“…A heterogenized Mn(III) porphyrin-based catalyst was prepared for dye degradation. The new Mn(III) complex of…”
Get full text
Journal Article -
13
Interactions of porphyrins and single walled carbon nanotubes: A fine duet
Published in Synthetic metals (01-07-2014)“…•Covalent/non-covalent functionalization of carbon nanotubes with porphyrins.•Interactions of porphyrins and single walled carbon nanotubes: reciprocal…”
Get full text
Journal Article -
14
Panorama da Química Inorgânica no Brasil revisitado: Período de 2002 a 2006
Published in Química nova (03-07-2017)Get full text
Journal Article -
15
-
16
-
17
Effect of imidazole on biomimetic cyclohexane oxidation by first-, second-, and third-generation manganese porphyrins using PhIO and PhI(OAc) sub(2) as oxidants
Published in Applied catalysis. A, General (05-02-2015)“…In this work, spectrophotometric titrations of first- (Mn super(III)TPPCI), second- (Mn super(III)APTPPCl and Mn super(III)T4CMPPCI), and third- (Mn…”
Get full text
Journal Article -
18
Carbamazepine oxidation catalyzed by manganese porphyrins: Effects of the I super(2)-bromination of the macrocycle and the choice of oxidant
Published in Applied catalysis. A, General (28-11-2011)“…Carbamazepine (CBZ), which is one of the most commonly prescribed antiepileptic drugs and also used in the treatment of trigeminal neuralgia and psychiatric…”
Get full text
Journal Article -
19
Selective oxidation of lupeol by iodosylbenzene catalyzed by manganese porphyrins
Published in Catalysis communications (05-11-2016)“…Manganese porphyrin-catalyzed oxidation of lupeol by iodosylbenzene was achieved under mild conditions with low isolated yields but with remarkable…”
Get full text
Journal Article -
20
Spectral, electrochemical, and catalytic properties of a homologous series of manganese porphyrins as cytochrome P450 model: The effect of the degree of β-bromination
Published in Journal of inorganic biochemistry (01-10-2008)“…A homologous series of β-brominated porphyrins derived from meso-tetrakis(4-carbomethoxyphenyl)porphyrinatomanganese(III) chloride, i.e., Mn(III)(Br x TCMPP)Cl…”
Get full text
Journal Article